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《防务技术》2014,10(4):384-392
Computations by density functional theory (DFT) method are performed on a series of di-1H-1,3,4-triazole derivatives with different substituents and linkages. The heat of formation (HOF) is predicted by the designed isodesmic reactions. The predicted results reveal that –N3 and –NN– groups are effective structural units for increasing the HOF values of the di-1H-1,3,4-triazole derivatives. The HOMO–LUMO gap is affected by the substituents and linkage groups. Detonation performance is evaluated using the Kamlet–Jacobs approach based on the calculated density and HOF. The results indicate that –NO2, –NF2, –NH–, –NH–NH– and –NN– groups are helpful for enhancing the detonation properties of di-1H-1,3,4-triazole derivatives. The bond dissociation energy and bond order of the weakest bonds are analyzed to investigate their stability. It is observed that the –CH2–, –CH2–CH2– and –CHCH– groups are effective structural units for improving the stabilities of these derivatives. Considering the detonation performance and the stability, five compounds are screened as the potential candidates for high energy density materials. 相似文献
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《防务技术》2014,10(4):321-327
Parameter estimation is analyzed using two kinds of common sampling-type DFRFT (discrete fractional Fourier transform) algorithm. A model of parameter estimation is established. The factors which influence estimation accuracy are analyzed. And the simulation is made to verify the conclusions. From the theoretic analysis and simulation verification, it can be drawn that, for the estimation of chirp-rate and initial frequency, Pei's method [10] is more suitable if the absolute value of chirp-rate is small relatively; Ozaktas' method [9] is more suitable if the absolute value of chirp-rate is large relatively; and the two methods are both workable if the absolute value of chirp-rate is moderate. The scope of moderate chirp-rate can be approximately determined as [40 Hz/s, 110 Hz/s]. 相似文献
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《防务技术》2014,10(1):60-65
A new guidance law, called biased retro proportional navigation (BRPN), is proposed. The guidance law is designed to intercept high-speed targets with angular constraint, which can be used for ballistic target interception. BRPN guidance law is defined, and the exact time-varying bias for a required impact angle is derived. Furthermore, the simulation results (trajectory, variation of navigation ratio, capture region, etc) are compared with those of biased proportional navigation (BPN), proportional navigation and retro-proportional navigation. The results show that, at the cost of a higher intercept time, BRPN demands lower terminal lateral acceleration and has larger capture region compared to BPN. 相似文献
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对自由曲面的立体现觉测量与加工一体化技术中的图像匹配、曲面造型以及接口设计等问题进行了分析与讨论,并提出了切实可行的解决办法。 相似文献
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针对遥感异源图像匹配中非线性灰度畸变和强噪声干扰问题,提出一种基于主成分分析(Principal Components Analysis,PCA)和方向梯度直方图(Histogram of Oriented Gradients,HOG)的遥感异源图像匹配算法.该算法利用HOG提取图像间的几何结构共性特征,能有效克服异源... 相似文献
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