Preparation and characterization of HMX/NH2-GO composite with enhanced thermal safety and desensitization

To improve the safety of HMX, HMX/NH₂-GO composite was prepared with aqueous ammonia functionalized graphene oxide (NH₂-GO). The composite was characterized by SEM, Zeta potential, XPS, Raman spectrum, XRD, HPLC, DSC and BAM sensitivity test. The results indicated that the functionalization with aqueous ammonia can enhance the interaction between GO and HMX, and more efficiently desensitize the explosive. The optimal impact sensitivity of the HMX/NH₂-GO composite can be not less than 40 J, which is also the most insensitivity compared to the previous reports prepared by coating desensitization with non-energetic desensitized material. Moreover, the potential reason for the different impact and friction sensitivity was also discussed, which may bring a novel perspective to achieve the desensitization of energetic material.     

火炮发射药装药自动识别方法

发射装药号是影响火炮身管寿命的重要因素,为自动识别火炮发射药的装药号,避免人工记录失误和完善火炮射弹履历,分析了装药号自动识别原理,运用火炮动力学分析理论和ADAMS虚拟样机技术,建立火炮发射动力学虚拟样机.通过仿真试验获取样本数据,应用BP神经网络进行学习和训练,从而建立装药号和测试数据之间的非线性映射关系,实现对火炮发射装药号的精确预测.     

Damage analysis of POZD coated square reinforced concrete slab under contact blast

High efficiency, environmental protection and sustainability have become the main theme of the development of the protection engineering, requiring that the components not only meet the basic functions, but also have chemical properties such as acid and alkali corrosion resistance and aging resistance. Polyisocyanate-oxazodone (POZD) polymer has the above characteristics, it also has the advantages of strong toughness, high strength and high elongation. The concrete slab sprayed with POZD material has excellent anti-blast performance. In order to explore the damage characteristics of POZD sprayed concrete slabs under the action of contact explosion thoroughly, the contact explosion test of POZD concrete slabs with different charges were carried out. On the basis of experimental verification, numerical simulation were used to study the influence of the thickness of the POZD on the blast resistance of the concrete slab. According to the test and numerical simulation results that as the thickness of the coating increases, the anti-blast performance of the concrete slab gradually increases, and the TNT equivalent required for critical failure is larger. Based on the above analysis, empirical expressions on normalized crater diameter, the normalized spall diameter and normalized spall diameter are obtained.     

一种新型CVD铁涂层吸波纤维

利用Fe(CO)5受热分解,以CVD方法在SiC纤维表面涂覆单质铁的涂层。研究表明,涂层的引入对SiC纤维力学性能基本没有损伤;纤维依靠涂层导电,其电阻率显著降低;改变工艺条件,可以在较大范围内调节涂层纤维的介电常数,同时也引入了磁损耗机制;采用较低的沉积温度和较高的载气流速,可以提高介电常数和磁导率,同时有好的频散效应。     

Effect of metal powders on explosion of fuel-air explosives with delayed secondary igniters

In order to improve the energy level of fuel air explosive(FAE) with delayed secondary igniters, high energetic metal powders were added to liquid fuels mainly composed of ether and isopropyl nitrate. Metal powders' explosive properties and reaction mechanisms in FAE were studied by high-speed video, pressure test system, and infrared thermal imager. The results show that compared with pure liquid fuels, the shock wave overpressure, maximum surface fireball temperature and high temperature duration of the mixture were significantly increased after adding high energetic metal powder. The overpressure values of the liquid-solid mixture at all measuring points were higher than that of the pure liquid fuels. And the maximum temperature of the fireball was up to 1700 ℃, which was higher than that of the pure liquid fuels. After replacing 30％of aluminum powder with boron or magnesium hydride, the shock wave pressure of the mixture was further increased. The high heat of combustion of boron and the hydrogen released by magnesium hydride could effectively increase the blast effect of the mixture. The improvement of the explosion performance of boron was better than magnesium hydride. It shows that adding high energetic metal powder to liquid fuels can effectively improve the explosion performance of FAE.     

PIP工艺制备的C/SiC复合材料的氧化行为

PIP工艺制备的C/SiC复合材料中SiC基体富碳,因此增强体和基体均容易氧化。碳纤维和无涂层保护C/SiC复合材料试样在400~1300℃的氧化速率随温度升高而加快,低温为反应控制,高温为扩散控制。CVD-SiC涂层保护C/SiC复合材料和由CVD-SiC层、自愈合层、CVD-SiC层三层涂层保护C/SiC复合材料在400~1300℃的氧化先随温度升高而加快,然后减慢。三层涂层在800~1300℃有非常好的保护效果。扫描电镜照片显示自愈合层的玻璃态物质进入涂层裂纹中,填充裂纹且阻挡氧的通过,从而有良好的抗氧化保护效果。     

一种新型内孔热喷涂技术及涂层性能研究

介绍了一种新型的内孔热喷涂技术———离心雾化等离子喷涂技术,并阐述了该技术的工作原理和工作过程。通过试验制取了3Cr13涂层和铝涂层,使用扫描电镜、能谱仪和光学显微镜等仪器设备对2种涂层的表面和截面进行观察分析,结果表明,通过该技术制取的涂层具有和传统电弧喷涂层类似的组织结构,并具有氧化物含量低,喷涂粒子大等特点。     

添加SiC微粉对硅树脂先驱体转化3D Cf/Si-O-C材料性能的影响

以三维碳纤维织物和廉价的硅树脂为原料,采用先驱体转化工艺制备3D G/Si-O-C材料,考察了浸渍液中添加SiC填料对材料微观结构、力学性能和抗氧化性能影响.结果表明:添加适量的SiC填料有助于减少基体孔隙,改善界面结合,从而提高材料的力学性能;而SiC含量过高时,容易在材料内部形成闭孔,从而导致材料力学性能下降.当SiC微粉含量为18.2%时,材料具有最好的力学性能,弯曲强度和断裂韧度分别为421.3MPa和13.0 MPa·m1/2;而材料的抗氧化性能随着SiC微粉含量的增加而增加,当SiC微粉含量为25.0%时,材料的弯曲强度保留率最高,达到了89.5%.     

拉伸载荷作用下基体表层激光离散预处理对铬镀层／45钢基开裂行为的影响

采用激光离散预处理钢基体再电镀铬层技术得到了一种新型复合结构,研究了这种新型复合结构在拉伸载荷作用下的开裂行为特征,并与无激光处理钢基体的试样在同样试验条件下的开裂特征进行了对比分析。结果表明：有激光离散预处理钢基体试样的承载能力要高于无激光预处理钢基体试样的承载能力,且有激光处理的试样开裂区域在两个激光带之间（无激光处理区）,主裂纹呈现明显的周期性特征。本研究结果可归结为激光预处理钢基体不仅改善了基体表层的应力状态和力学性能,而且还改善了后续铬镀层的力学性能。     

湿热环境中油罐防腐设计

湿热环境中油罐的腐蚀主要体现为电化学腐蚀的特征,适宜的防腐措施对提高油罐的建设质量,减缓油罐的腐蚀速度,延长油罐的使用寿命,减小维护费用等具有积极的意义。从分析湿热环境中油罐腐蚀规律出发,介绍了油罐内外壁防腐涂层的选用原则,对3000m^3地面立式油罐的牺牲阳极电法保护进行了设计计算,提出了施工方法,对湿热环境中油罐防腐具有指导意义。