反应法制备SiC涂层组成与结构

采用反应法在C/SiC复合材料表面制备SiC致密涂层,利用XRD分析涂层的组分及晶体结构,利用扫描电镜及金相显微镜观察涂层的断口及表面形貌,并对涂层形成过程进行了分析。结果显示:涂层主要由SiC及少量的游离Si组成,致密不开裂的SiC涂层与C/SiC复合坯体之间有很好的梯度过渡结构;相反,涂层与坯体之间如果没有形成过渡层,涂层会因热残余应力过大而开裂;反应法制备不开裂SiC涂层与CVDSiC涂层有很好的热匹配性,同时在其表面制备的CVDSiC涂层无点缺陷。     

消防应急救援过度应激反应及对策研究

重大灾害应急救援已经成为消防部队重要的作战任务之一,通过应激反应分类、危害性等情况研究,分析消防部队进行重大灾害救援时产生的心理影响,提出了事前、事中及事后三个不同阶段应采取的不同干预措施,对保证消防部队有效完成重大灾害救援作战任务,提高消防部队灭火救援能力具有重要意义。     

Study on energy release characteristics of reactive material casings under explosive loading

Reactive Materials (RMs), a new material with structural and energy release characteristics under shock-induced chemical reactions, are promising in extensive applications in national defense and military fields. They can increase the lethality of warheads due to their dual functionality. This paper focuses on the energy release characteristics of RM casings prepared by alloy melting and casting process under explosive loading. Explosion experiments of RM and conventional 2A12 aluminum alloy casings were conducted in free field to capture the explosive fireballs, temperature distribution, peak overpressure of the air shock wave and the fracture morphology of fragments of reactive material (RM) warhead casings by using high-speed camera, infrared thermal imager temperature and peak overpressure testing and scanning electron microscope. Results showed that an increase of both the fireball temperature and air shock wave were observed in all RM casings compared to conventional 2A12 aluminum ally casings. The RM casings can improve the peak overpressure of the air shock wave under explosion loading, though the results are different with different charge ratios. According to the energy release characteristics of the RM, increasing the thickness of RM casings will increase the peak overpressure of the near-field air shock wave, while reducing the thickness will increase the peak overpressure of the far-field air shock wave.     

Si3 N4基复相陶瓷天线罩材料的制备及性能

基于高马赫数导弹天线罩为应用背景,以Si粉、BN粉、SiO2粉为主要原料,采用反应烧结法制备Si3N4基复相陶瓷材料,探讨了原料组成、成型工艺及坯体密度对材料性能的影响。试验结果表明:当原料中Si、BN和SiO2分别为55%、30%和10%时,材料强度可达96.7MPa,断裂韧性可达1.80MPa.m1/2。同时材料具有良好的介电性能及热物理性能。     

Investigation of the shock compression behaviors of Al/PTFE composites with experimental and a 3D mesoscale-model

The responses of AI/PTFE reactive materials (RMs) under shock compression were investigated by a single-stage gas gun.A 3D mesoscale-model was established based on micro-computed tomography(micro-CT) slice images and confirmed with experimental results.In the high-pressure stage,the com-posites reacted partially,whereas there were no deviations between the partially reacted Hugoniot and the inert simulation results.The simulation reveals that the Teflon matrix melting on the high shock pressure.Melts and decomposition of the PTFE accelerated the diffusion of the atoms.Thus,the reactions of the Al/PrFE composites are more like a combustion rather than a detonation.     

高速核在高温热平衡等离子体中的非平衡弛豫过程对热核反应率参数的影响

高速核入射到高温热平衡等离子体背景中,由于入射核动能远大于背景等离体中带电粒子之平均动能,入射核在与背景等离子体达到热平衡之前,会存在一段逐渐损失能量的非平衡弛豫过程。本文以高速氘核入射到高温氘化锂等离子体为例,在计及氘核的这种非平衡弛豫过程时,给出了一种计算热核反应D(t,n)~4He之反应率参数的方法。氘核在弛豫过程中的能量损失考虑了氘核与各种带电粒子的库仑散射过程,其能量损失率采用快速带电粒子的慢化理论来计算;氘与背景等离子体中的原子核发生的核反应过程,考虑了非平衡状态下束靶机制的D(t,n)~4He反应和热平衡状态下的D(t.n)~4He反应。在暂未考虑核散射的情况下,计算结果表明,当等离子体温度在7.5KeV～20KeV范围内变化时,氘核的非平衡弛豫过程对热平衡状态下D(t,n)~4He反应率参数的修正因子大致在1.0062～1.0943范围内变动,且温度越高,修正因子越小。计算还表明,当温度一定时,修正因子随等离子体中粒子的数密度变化不明显。     

一类三分子饱和反应动力系统的定性分析

研究化学反应中一类多分子一级饱和反应的数学模型应用微分方程定性理论,研究了该系统极限环的存在性、不存在性和唯一性问题。     

渗碳气氛的热力学及动力学分析

本文对渗碳气氛进行热力学及动力学分析,给出炉气各组分间反应速率的测试方法及测试数据。结果表明,渗碳气氛的独立反应数为4,自由度为3,甲烷的渗碳作用不可忽略,控制甲烷这一碳源有利于提高碳势控制精度.     

Si(Al)C纤维先驱体聚铝碳硅烷的合成

采用低分子量固态聚碳硅烷和乙酰丙酮铝为原料,利用Si-H与乙酰丙酮铝之间的交联反应合成适于熔融纺丝的聚铝碳硅烷。研究了反应条件对产物数均分子量、软化点和组成结构的影响及交联反应程度与可纺性之间的关系。实验结果表明:随着反应温度的升高和反应时间的延长,反应程度提高,残余乙酰丙酮基减少,Si-O-Al交联支化结构增多,分子量和软化点增大,可纺性随之下降。当乙酰丙酮铝投料比为8%时,在370℃下反应4~6 h,可得到软化点为206~221℃,Al wt%=0.68%,具有良好可纺性的聚铝碳硅烷。     

舰炮火控系统反应时间与精度关系的仿真

对舰炮火控系统中反应时间和系统精度之间的关系做了简要的介绍,并论述了舰炮火控系统中时间和精度之间复杂的关系,通过分析采样点数和误差之间的关系,结合采样点数和系统反应时间之间的联系以及误差与系统精度之间的联系,引出反应时间与精度之间的某种关系,最后对从接收目标指示到给出射击诸元这个过程的各个时间段与其相对应的精度之间的关系进行计算机仿真。