燃烧型焊条焊接A3钢的研究

基于燃烧合成技术的燃烧机理,结合焊接母材的材质,制备可用于手工施焊的燃烧型焊条焊接A3钢。对焊接试件进行力学性能测试和金相分析,结果表明:焊接试件的结合方式为冶金结合,焊缝合金在细晶强化和弥散强化的作用下,试件的抗拉强度(σb)达到370 MPa,抗弯强度(σf)达到1 100 MPa,成功实现了燃烧型焊条对A3钢的焊接。     

一类多分子化学反应系统的极限环

本文研究由低浓度三分子反应模型改进而建立的一类多分子化学反应模型,应用微分方程定性理论,完整地解决了该模型极限环的存在性、不存在性和唯一性问题,从而给出了化学浓度阀。     

导弹初始大角度转弯复合控制研究

基于直接力/气动力复合控制方法,研究了导弹初始快速大角度转弯问题。给出了直/气复合控制回路稳定性分析方法,并应用极点配置求得系统控制参数。最后对直/气复合控制回路稳定性进行了分析,对其时域跟踪进行了数学仿真。仿真结果表明,提出的控制方法可以提高系统转弯快速性,验证了复合控制方法的可行性。     

一类化学反应动力系统的极限环

本文研究具有饱和输出的Prigogine三分子反应动力学模型,应用微分方程定性理论,完整地解决了系统极限环的存在性和唯一性问题。     

非均匀形核法制备Cu包覆纳米SiO2复合粉体

采用非均匀形核法制备了Cu包覆纳米SiO2复合颗粒,利用X射线衍射仪、扫描电镜、能谱仪及透射电镜等分析手段对复合颗粒进行了表征,并探讨了包覆结构的形成机制。结果表明:复合颗粒分散均匀,无团聚,单颗粒内包含多个分布均匀的纳米SiO2颗粒,且均被Cu包覆层隔离,纳米SiO2颗粒的分散性得到了显著改善;新制备的复合颗粒不存在氧化,在存放或者制样过程中会部分氧化为Cu2O;纳米SiO2颗粒表面Cu包覆层的形成机制主要是非均匀形核作用,包覆的结构取决于 Cu晶粒在纳米SiO2颗粒表面的沉积以及对复合颗粒的团聚控制。     

一类可逆生化反应动力系统的定性分析

研究生化反应中一类可逆饱和反应的数学模型：应用微分方程定性理论,比较完整地解决了该系统极限环的存在性、唯一性和不存在性等问题。     

A melt-cast Duan-Zhang-Kim mesoscopic reaction rate model and experiment for shock initiation of melt-cast explosives

A melt-cast Duan-Zhang-Kim (DZK) mesoscopic reaction rate model is developed for the shock initiation of melt-cast explosives based on the pore collapse hot-spot ignition mechanism. A series of shock initiation experiments was performed for the Comp B melt-cast explosive to estimate effects of the loading pressure and the particle size of granular explosive component, and the mesoscopic model is validated against the experimental data. Further numerical simulations indicate that the initial density and formula proportion greatly affect the hot-spot ignition of melt-cast explosives.     

药物爆燃产生强红外辐射的分析研究

定向红外脉冲强光辐射是定向红外对抗技术中的关键技术,用来破坏敌方精确制导武器或C4I系统中的红外传感器。本文主要研究了药物爆燃产生近红外辐射的特性,通过计算化学反应热分析了药物爆燃产生的总能量,并且详细介绍了几种不同的实验方法和实验结果。     

一类生化反应动力系统的极限环

研究生化反应中一类饱和反应的数学模型dxdt =a1 -xy a2 y2dydt=a3 xy-a2 y2 - vyy b应用微分方程定性理论 ,完整地解决了该系统极限环的存在性、唯一性和不存在性等问题。     

Effect of microstructure on short pulse duration shock initiation of TATB and initial response mechanism

Micro-TATB particles with different sizes and 3D nanoporous TATB architectures with different specific surface areas were prepared through recrystallization to study short pulse duration shock initiation properties by electric gun technology. For micro-TATB, the initiation threshold significantly decreases with TATB average size ranging from 79.7 μm to 0.5 μm. For 3D nanoporous TATB architecture, the initiation threshold decreases and then increases with specific surface areas increased from 9.6 m²/g to 36.2 m²/g. The lowest initiation thresholds are obtained for the micro-TATB with average sizes of 1.3 μm and 0.5 μm, and 3D nanoporous TATB architecture with specific surface area of 22.4 m²/g. The shock initiation thresholds of micro-TATB and 3D nanoporous TATB architectures show significantly decreases with the porosity increased. The decomposition reaction and thermal conductivity properties were further investigated to understand the initial response mechanism. High porosity provides more collapse sites to generate high temperature for formation of hot spots. The low thermal conductivity and decomposition temperature could enhance the formation and ignition of the hot spots, and initial decomposition reaction of TATB. The effect of the decomposition temperature is higher than that of the thermal conductivity on the shock initiation properties. The enhanced decomposition reaction could promote energy release and transfer process from the ignition to the combustion. This work offers a new insight to understand the effects of microstructure on the shock initiation properties and the initial response mechanism of TATB.