微波辐射Fenton反应降解罗丹明B研究

Fenton试剂在降解有机污染物方面具有无二次污染等优势,但由于存在降解速率较慢的缺陷,在工程实践中尚未得以推广应用。考虑到微波具有促进有机化学反应速率的功能,采用微波和Fenton试剂联合作用氧化降解罗丹明B,对降解罗丹明B的优化实验条件进行了研究。首先研究了单一因素对降解效果的影响,然后对各种因素的综合作用效果进行了分析,得出了降解的优化实验条件。研究表明,微波能有效促进罗丹明B的降解脱色,而且能大大缩短反应时间,降低反应成本,增强Fenton氧化反应的活性,提高降解效果。     

一类可逆生化反应动力系统的定性分析

研究生化反应中一类可逆饱和反应的数学模型：应用微分方程定性理论,比较完整地解决了该系统极限环的存在性、唯一性和不存在性等问题。     

二价钴、镍氯化物的四齿N4大环席夫碱配合物的合成及表征

以Cocl_2·6H_2O和NiCl_2·6H_2O为模板剂,邻苯二胺和邻苯二醛为原料,在无水乙醇中模板合成了两种新型的大环席夫碱配合物。通过元素分析、摩尔电导和磁化率的测定,红外光谱、紫外可见光谱等项表征,确定了配合物的组成和结构,进而观察和研究了它们的电致变色现象,并对其电致变色机理进行了初步探讨。     

A melt-cast Duan-Zhang-Kim mesoscopic reaction rate model and experiment for shock initiation of melt-cast explosives

A melt-cast Duan-Zhang-Kim (DZK) mesoscopic reaction rate model is developed for the shock initiation of melt-cast explosives based on the pore collapse hot-spot ignition mechanism. A series of shock initiation experiments was performed for the Comp B melt-cast explosive to estimate effects of the loading pressure and the particle size of granular explosive component, and the mesoscopic model is validated against the experimental data. Further numerical simulations indicate that the initial density and formula proportion greatly affect the hot-spot ignition of melt-cast explosives.     

Numerical research on adverse effect of muzzle flow formed by muzzle brake considering secondary combustion

The simulation of the artillery interior and intermediate ballistics problem is performed to investigate the influence of a gas dynamics device, muzzle brake, on the muzzle hazard phenomena, such as flash and blast waves. The correlation of the chemical reactions with the characteristics of the muzzle flow field is analyzed by the simulation for a further understanding of the secondary combustion phenom-enon of the muzzle flow. The novel structure of muzzle flow caused by the muzzle brake is presented by the simultaneous solution of the interior ballistics model and multi-species Navier-Stokes equations in order to analyze the influence of the muzzle brake structure on the chemical reactions. The secondary combustion of the muzzle flow due to the oxygen-supplement chemical reactions is obtained by the chemical reaction kinetic model. The interaction of the blast waves released from the muzzle brake is illustrated in detail and the mechanism of the formation of muzzle flash is analyzed. This research provides a reference for the studies on the suppression of the muzzle flash.     

反作用轮低速特性观测补偿方法

反作用轮在现代高精度卫星姿态控制中占据着重要的地位。但由于反作用轮工作于低速状态,其转速过零时摩擦力矩的非线性特征将会对姿态控制精度产生较大的影响,并影响卫星运行寿命。基于Dahl摩擦模型建立了直流电机驱动的反作用轮系统数学模型,在此基础上设计了用于改善反作用轮低速性能的补偿观测器,并将其应用于三正交结构姿态控制系统。数字仿真说明此方法可以有效地抑制反作用轮低速摩擦产生的扰动,从而大幅度改善卫星姿态控制精度及其姿态稳定性。最后探讨了该观测器方法同变结构控制方法的综合应用前景。     

防空导弹行进间发射技术初探

行进间发射技术是防空导弹技术的重要发展趋势之一,它能为机械化部队提供不间断的伴随防空,大幅增强武器系统的快速反应能力,提高了系统的生存能力,在综述各国行进间发射防空导弹型号基础上,对该技术的使用意义、装备特点和关键技术进行了总结。     

基于动力学和扩散分段控制的Mg/H2O反应模型及数值分析

为了数值研究宽广温度范围内Mg/H2O的反应特性,分别建立了考虑部分MgO在液滴表面凝聚的Mg/H2O扩散燃烧模型和基于Arrhenius公式的Mg/H2O反应动力学模型.数值研究了Mg/H2O反应速率在扩散控制和化学动力学控制下随反应条件变化的规律.研究结果表明,Mg液滴扩散燃烧时间计算结果与文献值相符;提高温度和水...