溴酸盐体系中的化学波

本文对溴酸盐体系中的化学波进行了实验研究,得到了反应物的初始浓度与波速的关系,随 ＫＢｒＯ３和 Ｈ２ＳＯ４初始浓度的增加,波速具有增加的趋势,而随 ＭＡ的初始浓度的增加而变化不大。并给出了其反应机理的分析及数学模型。     

Fe~(3+)与S~(2-)反应的研究

Fe3+ 与S2 - 反应是一个典型的竞争反应 ,反应的生成物与反应条件有着非常密切的关系。通过理论研究和实验验证 ,确认在酸性介质中反应的生成物为Fe3+ 和单质S↓ ;在碱性介质中反应的生成物为黑色Fe2 S3↓。     

中学化学继续教育应强化实验研究

通过Ｚｎ与Ｃｕ（ＮＯ_３）_２溶液反应的实验分析,提出了研究和全面认识置换反应的思路。对中学化学教师继续教育中实验教学应解决的问题进行了讨论。     

储运过程反应失控型火灾爆炸事故的预测与防范

储运化学活泼性物质时易发生反应失控型火灾爆炸事故,其危险性随着容器的增大和储运时间的增长而增加.介绍一种储运容器中反应失控火灾爆炸事故危险性预测的方法,预测结果与实际情况具有良好的一致性,并对预防事故的冷却方法进行了实验研究.     

自润滑材料工作机理验证与材料再生

在研究含油量低(HDV6)、中(HDV12)、高(HDV20)3种材料的滑动摩擦特性基础上,通过实验验证了自润滑材料工作机理;并发现自润滑材料失去自润滑特性后,通过对其重新浸油,可以使材料的自润滑性能再生.     

摩擦电喷镀Ni-Co-MoS2复合镀层摩擦学性能研究

采用摩擦电喷镀技术制备Ni-Co-MoS2复合镀层,系统试验研究了复合镀层的摩擦学性能。结果表明,Ni-Co-MoS2复合镀层在滑动摩擦条件下,摩擦因数主要取决于镀层中MoS2微粒的含量、滑动速度和载荷;MoS2微粒的减磨作用,可有效改善镀层的耐磨性;在滑动摩擦条件下,Ni-Co-MoS2复合镀层的耐磨性能将随MoS2含量的提高而提高。     

起步过程中离合器半接合点的试验研究

离合器接合过程半接合点的确定和控制参数的选取是提高自动变速车辆起步品质的关键。在试验的基础上 ,得出了离合器半接合点的变化特点 ,选择以离合器主、被动轴转速差Δnec作为控制参数使车辆的起步过程具有一定的自适应性。     

建筑材料燃烧性能分级新变革

介绍我国建筑材料燃烧性能分级的现状和未来的发展方向,提出引进欧盟的分级体系形成新的分级方法,并进行分析比较。     

渗碳气氛的热力学及动力学分析

本文对渗碳气氛进行热力学及动力学分析,给出炉气各组分间反应速率的测试方法及测试数据。结果表明,渗碳气氛的独立反应数为4,自由度为3,甲烷的渗碳作用不可忽略,控制甲烷这一碳源有利于提高碳势控制精度.     

Effects of nano-sized aluminum on detonation characteristics and metal acceleration for RDX-based aluminized explosive

Nano-sized aluminum(Nano-Al)powders hold promise in enhancing the total energy of explosives and the metal acceleration ability at the same time.However,the near-detonation zone effects of reaction between Nano-Al with detonation products remain unclear.In this study,the overall reaction process of 170 nm Al with RDX explosive and its effect on detonation characteristics,detonation reaction zone,and the metal acceleration ability were comprehensively investigated through a variety of experiments such as the detonation velocity test,detonation pressure test,explosive/window interface velocity test and confined plate push test using high-resolution laser interferometry.Lithium fluoride(LiF),which has an inert behavior during the explosion,was used as a control to compare the contribution of the reaction of aluminum.A thermochemical approach that took into account the reactivity of aluminum and ensuing detonation products was adopted to calculate the additional energy release by afterburn.Combining the numerical simulations based on the calculated afterburn energy and experimental results,the param-eters in the detonation equation of state describing the Nano-Al reaction characteristics were calibrated.This study found that when the 170 nm Al content is from 0％to 15％,every 5％increase of aluminum resulted in about a 1.3％decrease in detonation velocity.Manganin pressure gauge measurement showed no significant enhancement in detonation pressure.The detonation reaction time and reaction zone length of RDX/Al/wax/80/15/5 explosive is 64 ns and 0.47 mm,which is respectively 14％and 8％higher than that of RDX/wax/95/5 explosive(57 ns and 0.39 mm).Explosive/window interface velocity curves show that 170 nm Al mainly reacted with the RDX detonation products after the detonation front.For the recording time of about 10 μs throughout the plate push test duration,the maximum plate velocity and plate acceleration time accelerated by RDX/Al/wax/80/15/5 explosive is 12％and 2.9 μs higher than that of RDX/LiF/wax/80/15/5,respectively,indicating that the aluminum reaction energy significantly increased the metal acceleration time and ability of the explosive.Numerical simulations with JWLM explosive equation of state show that when the detonation products expanded to 2 times the initial volume,over 80％of the aluminum had reacted,implying very high reactivity.These results are significant in attaining a clear understanding of the reaction mechanism of Nano-Al in the development of aluminized explosives.