Effect of silicon carbide and wire-mesh reinforcements in dissimilar grade aluminium explosive clad composites

Aluminium composites are inevitable in the manufacture of aircraft structural elements owing to less weight, superior corrosion resistance and higher specific properties. These composites reduce the weight of the aircraft, improve the fuel efficiency and enhance the maintenance duration. This study proposes the development of dissimilar grade aluminium (aluminium 1100-aluminium 5052) composites with different reinforcement’s viz., stainless steel wire-mesh, silicon carbide (SiC) powders and SiC powder interspersed wire-mesh, by explosive cladding technique. Wire-mesh enhances the friction and restricts the movement of flyer plate to craft a defect free clad, while SiC particles form a band on the interface. Highest strength is obtained when SiC powder interspersed wire mesh is employed as reinforcement. The dissimilar aluminium explosive clad with SiC particle reinforcement results in lower strength, which is higher than that of the weaker parent alloy and that of the conventional dissimilar aluminium explosive clads without any reinforcement.     

石墨烯作为水基半合成切削液添加剂的硬质合金-钢材料摩擦学特性分析

改善加工过程润滑条件是延缓刀具磨损的重要途径。将石墨烯作为3034水基半合成切削液的添加剂,研究石墨烯悬浮切削液的硬质合金-钢材料摩擦学性能,研究对象是由硬质合金YG8制备的金属球和由45#钢制备的圆盘形试件;采用球-盘摩擦副接触方式在摩擦磨损试验机上进行试验,测定了质量分数为0. 1%~0. 9%的石墨烯悬浮切削液的平均摩擦特性和摩擦系数;采用激光共聚焦显微镜对磨痕轮廓进行提取,并得出磨损定量评价指数,并用扫描电镜和拉曼光谱仪对磨痕进行磨损机理分析;进行切削实验来分析石墨烯悬浮切削液对切削性能指标的改善情况。实验分析结果表明:石墨烯悬浮切削液能明显改善硬质合金-45#钢之间的润滑条件,摩擦系数和磨损率显著下降,采用不同质量分数石墨烯悬浮切削液的平均摩擦系数较原半合成切削液下降12. 9%~57. 3%,磨损率下降33. 82%,同时切削合力较原半合成切削液下降18. 58%,加工后工件表面粗糙度下降7. 5%。     

飞秒激光烧蚀硅的瞬态演化特性仿真

为深入揭示飞秒激光烧蚀硅的瞬态演化特性,建立了飞秒激光烧蚀硅材料理论模型,并进行了仿真研究。研究表明:飞秒激光可在脉宽时间内激发大量的电子,使其浓度超过损伤阈值,而此时晶格仍保持在较"冷"状态,直到1 ns量级才达到熔点温度;电子温度也会在脉宽时间内急剧拉升至104K量级,随后将能量缓慢地释放给晶格,直到10 ns量级才与晶格达到热平衡。电子存在两次急剧升温的过程:第一次起于自由电子吸收,止于电子与晶格的能量耦合;第二次起于单光子和双光子吸收,止于脉冲结束。脉冲能量越大,电子密度和温度越高;脉宽越短,电子温度越高。     

溶胶凝胶法制备碳化硅陶瓷的影响因素

采用溶胶凝胶法 ,以正硅酸乙酯和酚醛树脂为原料 ,在草酸催化作用下 ,制备出了不含硫和氯的均相碳化硅先驱体 ,并在一定的升温制度下制备出SiC陶瓷。考察了温度对预水解过程的影响以及水用量、催化剂和镍盐用量等因素对凝胶时间的影响。结果表明 ,在预水解温度控制在 4 0℃左右 ,时间为 2 4h时效果最佳 ;而当水与正硅酸乙酯的摩尔比达到 0 2 8左右、草酸与正硅酸乙酯的摩尔比为 0 0 1左右时 ,可以使凝胶时间达到最短。进一步的研究表明 ,镍盐的加入对凝胶烧成过程中 β -SiC的生成有催化作用。     

NICALON(SiC)纤维增强铝预制丝透射电镜样品的研制

文中研究了用离子减薄法制备NICALON(SiC)/A1预制丝的透射电镜(TEM)样品。结果表明:用离子减薄法制备含有性质非常不同的组元(如碳化硅-铝复合材料)TEM样品是一种方便、有效的方法。运用TEM初步分析了所制出的预制丝样品。     

不同裂解温度对制备SiCf/Si-O-C复合材料性能研究

以聚硅氧烷为先驱体,研究先驱体转化过程中在不同的裂解温度下对制备SiCf/Si-O-C复合材料性能影响.结果表明,当裂解温度在700℃、800℃时,陶瓷基复合材料的弯曲强度分别为255.2 MPa、309.0 MPa;当裂解温度在1000℃时,陶瓷基复合材料的弯曲强度为45.3 MPa.对SiCf/Si-O-C复合材料的微观结构及载荷-位移曲线进行分析,发现界面结构是影响SiCf/Si-O-C复合材料性能的主要因素.     

Combustion of B4C/KNO3 binary pyrotechnic system

Presented herein is an experimental study on the combustion of B4C/KNO3 binary pyrotechnic system.Combustion products were tested using X-ray diffraction(XRD),scanning electron microscopy(SEM),and energy dispersive spectrometer(EDS).According to the results of tests and CEA calculation,the combustion reaction equation was established.The flames and burning rates were recorded by a high speed camera and a spectrophotometer.The effect of B4C particle size on the thermal sensitivity of B4C/KNO3 was investigated by differential scanning calorimetry(DSC)techniques.In addition,a reliable method for calculating the flame temperature was proposed.Based on the results of experiments,the combustion reaction mechanism was briefly analyzed.The burning rate,flame temperature and thermal sensitivity of B4C/KNC3 increase with the decrease of B4C particle size.The mass ratio of B4C/KNO3 has a great effect on combustion properties.Oxidizer-rich compositions have low flame temperatures,low burning rates,and provide green light emission.The combustion reactions of fuel-rich compositions are vigorous,and the B4C/KNO3 with mass ratio of 25:75 has the highest burning rate and the highest flame temperature.     

碳化硼表面金属化初步研究

为了降低碳化硼(B,C)与金属钎焊连接的温度,采用真空熔结Al基钎料的方法,在1000℃时对其进行了表面金属化处理,SEM和EDAX观察分析B4C与钎料结合断面的形貌和元素面分布,发现B4C与钎料界面发生了互扩散,界面结合致密,形成冶金结合.     

先驱体转化致密碳化硅纳米复合材料的制备及其热电性能

以聚碳硅烷和锑改性聚硅烷为先驱体,利用先驱体转化Si C材料的富余自由碳高温石墨化的微观结构演变特点,采用热压烧结、先驱体浸渍-裂解法以及退火工艺制备出先驱体转化Si C纳米复合材料。采用SEM、TEM、XRD和Raman等测试手段表征和分析了相组成和微观结构,讨论了样品的热导率、电导率和塞贝克系数等热电参数随温度变化关系。研究表明,所得致密Si C纳米复合材料为n型热电材料。由于纳米石墨的作用,材料热导率抑制在4~8W/(m·K)范围。1600℃退火处理能够降低热导率,同时提高电导率和塞贝克系数绝对值,使先驱体转化法得到的Si C纳米复合材料无量纲热电优值ZT达到0.0028(650℃),高于其他已报道的致密Si C/C复合材料和纳米复合材料体系。