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681.
Composite solid propellants (CSPs) have widely been used as main energy source for propelling the rockets in both space and military applications. Internal ballistic parameters of rockets like characteristic exhaust velocity, specific impulse, thrust, burning rate etc., are measured to assess and control the performance of rocket motors. The burn rate of solid propellants has been considered as most vital parameter for design of solid rocket motors to meet specific mission requirements. The burning rate of solid propellants can be tailored by using different constituents, extent of oxidizer loading and its particle size and more commonly by incorporating suitable combustion catalysts. Various metal oxides (MOs), complexes, metal powders and metal alloys have shown positive catalytic behaviour during the com-bustion of CSPs. These are usually solid-state catalysts that play multiple roles in combustion of CSPs such as reduction in activation energy, enhancement of rate of reaction, modification of sequences in reaction-phase, influence on condensed-phase combustion and participation in combustion process in gas-phase reactions. The application of nanoscale catalysts in CSPs has increased considerably in recent past due to their superior catalytic properties as compared to their bulk-sized counterparts. A large surface-to-volume ratio and quantum size effect of nanocatalysts are considered to be plausible reasons for improving the combustion characteristics of propellants. Several efforts have been made to produce nanoscale combustion catalysts for advanced propellant formulations to improve their energetics. The work done so far is largely scattered. In this review, an effort has been made to introduce various combustion catalysts having at least a metallic entity. Recent developments of nanoscale combustion catalysts with their specific merits are discussed. The combustion chemistry of a typical CSP is briefly discussed for providing a better understanding on role of combustion catalysts in burning rate enhancement. Available information on different types of combustion nanocatalysts is also presented with critical comments. 相似文献
682.
Inwook Kim 《Contemporary Security Policy》2019,40(2):165-192
The 2016 decision to deploy Terminal High Altitude Area Defense (THAAD) to South Korea has generated multitude of intensely politicized issues and has proved highly controversial. This has made it challenging to alleviate, let alone clarify, points of analytical and policy tensions. We instead disaggregate and revisit two fundamental questions. One is whether THAAD could really defend South Korea from North Korean missiles. We challenge the conventional “qualified optimism” by giving analytical primacy to three countermeasures available to defeat THAAD–use of decoys, tumbling and spiral motion, and outnumbering. These countermeasures are relatively inexpensive to create but exceedingly difficult to offset. Second, we assess the optimal way to ensure South Korean national security against North Korean missiles. By examining the balance of capability and issues of credibility/commitment, we show that the U.S. extended deterrence by punishment remains plentiful and sufficiently credible even without enhancing the current defense capability. 相似文献
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紧贴装备保障转型的需求,引进物理-事理-人理(WuLi-ShiLi-RenLi,WSR)系统方法论与精益六西格玛(Lean Six Sigma,LSS)管理理论,提出一种装甲装备维修质量全系统综合管理模式。从WSR与LSS管理的角度,阐述了这种管理模式的基本思想,详细分析了其基本特点;依据LSS管理模式,从整体上详细论述了装甲装备维修质量管理包含的内容;结合WSR与LSS的逻辑过程,论述了其基本管理方式。 相似文献
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提出将人工免疫系统(Artificial Immunity System,AIS)中的反面选择原理应用到炮射导弹故障诊断中,依据免疫算法实现故障诊断的基本原理,构建了基于反面选择算法的故障诊断数学模型,解决了在故障先验知识和故障特征信息缺乏等情况下的故障诊断问题,并通过对炮射导弹制导仪系统中的故障进行实例分析,验证了该方法的有效性和优越性。 相似文献
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射频 /红外双模复合制导技术的不断发展引发了对射频 /红外双模复合制导仿真工具的迫切需求。国外从 20世纪 80年代末就开始了射频 /红外半实物仿真系统的研究。分析了美国海军空战中心等 4个单位的射频 /红外半实物仿真系统及其发展过程、技术特点。 相似文献