Theoretical study of an energetic material di-1H-1,3,4-triazole derivatives

Computations by density functional theory (DFT) method are performed on a series of di-1H-1,3,4-triazole derivatives with different substituents and linkages. The heat of formation (HOF) is predicted by the designed isodesmic reactions. The predicted results reveal that –N₃ and –NN– groups are effective structural units for increasing the HOF values of the di-1H-1,3,4-triazole derivatives. The HOMO–LUMO gap is affected by the substituents and linkage groups. Detonation performance is evaluated using the Kamlet–Jacobs approach based on the calculated density and HOF. The results indicate that –NO₂, –NF₂, –NH–, –NH–NH– and –NN– groups are helpful for enhancing the detonation properties of di-1H-1,3,4-triazole derivatives. The bond dissociation energy and bond order of the weakest bonds are analyzed to investigate their stability. It is observed that the –CH₂–, –CH₂–CH₂– and –CHCH– groups are effective structural units for improving the stabilities of these derivatives. Considering the detonation performance and the stability, five compounds are screened as the potential candidates for high energy density materials.     

Scale-up synthesis and characterization of 2,6-diamino-3,5-dinitropyrazine-1-oxide

2,6-diamino-3,5-dinitropyrazine-1-oxide (ANPZO), as an insensitive high explosive, with a high yield and excellent purity has been prepared at pilot plant scale by an improved method. The synthesized ANPZO is characterized by IR, laser granularity measurement, SEM and HPLC. The particle analysis revealed that the improved method could offer desired product with average particle size of 40 μm and high purity (>98.45%). The experimental parameters exhibited that the detonation velocity of the formulation based on ANPZO was higher than that of the corresponding TATB formulation. The DSC curve showed that the exothermic decomposition of the product occurred at the temperature between 300.5 °C and 360.4 °C. Furthermore, the sensitivity test suggests its safe nature towards mechanical stimulus.     

Analysis on the resistive force in penetration of a rigid projectile

According to the dimensionless formulae of DOP (depth of penetration) of a rigid projectile into different targets, the resistive force which a target exerts on the projectile during the penetration of rigid projectile is theoretically analyzed. In particular, the threshold V_c of impact velocity applicable for the assumption of constant resistive force is formulated through impulse analysis. The various values of V_c corresponding to different pairs of projectile-target are calculated, and the consistency of the relative test data and numerical results is observed.     

动态弹道补偿

通常意义下的弹道补偿没有考虑火炮摆动对射击的影响,因而在坦克运动或目标运动时,命中概率将大大降低.分析了由火炮摆动带来的射击误差,给出了相应的补偿算法及电路的实现方法.     

模糊-专家控制在智能消磁中的应用研究

综合消磁是处理舰船固定磁性的重要手段.长期以来,由于综合消磁工艺的复杂性,使得这项工作在很大程度上依赖人工.实现消磁自动化,就是要将工作人员从繁重的脑体劳动中解放出来,提高工作效率.目前的新型消磁站已经实现了数据采集、统计自动化,不仅基本免除了工作人员的体力劳动,也从一定程度上减轻了消磁技师的脑力劳动.然而由于需要人工参与决策,综合消磁的效果和效率仍然十分依赖于人的因素.所以,实现综合消磁工作的完全自动化,补偿电流值组合的智能化决策是关键问题.本文在分析以前所做工作的基础上,运用模糊控制理论构造模糊-专家控制器,替代人工决策过程以实现自动化消磁.     

紫外光语音通信系统参数补偿技术及Matlab仿真

利用线谱对参数建立了针对紫外光通信的语音参数补偿模型,采用基于LSF参数奇偶采样插值方法和丢失能量线性补偿法,对样本的丢包补偿前后相关系数和音质进行了对比.仿真结果表明,前后帧的中值补偿替代丢失帧的参数效果最好;该方法简单有效,对语音质量有较大改善.     

舰载光电跟踪的船摇扰动复合补偿控制

针对船摇扰动引起的机械谐振和视轴不稳定的问题,舰载条件下通过安装多个陀螺来实现船摇扰动的复合补偿,在原有等效闭环系统中串入高通滤波器,消除谐振环节带来的影响。从仿真结果看,复合补偿控制具有良好船摇隔离效果,有利于高精度跟踪系统的实现。     

圆柱形装药驱动轴向预制破片飞散特性

为了增强柱形战斗部轴向威力,在无壳柱形战斗部底面布置单层离散的预制破片.开展圆柱形TNT装药驱动轴向预制破片飞散试验,获得预制破片的最大初速、飞散角等特征参数;运用LS-DYNA软件对装药驱动预制破片过程进行数值模拟,阐述预制破片群飞散过程;对装药驱动整体平板理论计算公式进行改进,获得预制破片的最大初速.结果表明:破片...     

动力翼伞风扰补偿高度控制方法

外界风场是影响翼伞高度跟踪精度的最主要扰动因素。针对该问题,建立了动力翼伞的八自由度模型,并在传统自抗扰控制的基础上,设计一种基于风场前馈补偿的改进抗扰控制器,对外界的风场干扰进行针对性补偿,实现翼伞系统的高度跟踪控制。在通过仿真实验对控制器进行初步验证的基础上,进行了翼伞系统的实际飞行实验。在实际飞行环境下,仿真中所调节的控制器参数可直接应用于实际飞行实验,翼伞系统的平均高度跟踪误差在2.5 m以内,证明所设计的控制器存在一定的实际应用价值。     

稀薄气体动理论中介观尺度数值模拟的加速方法

针对滑移流、早期过渡流区域采用离散速度法(discrete velocity method, DVM)求解Boltzmann方程收敛速度极慢、计算资源消耗大的难题,提出全流场耦合介观/宏观方程加速方法。在介观层面基于有限差分的DVM求解Boltzmann方程,在宏观层面基于有限体积的压力耦合方程组半隐式方法求解矩方程,充分利用纳维-斯托克斯-傅里叶/R26矩方程在低克努森数下的快速收敛特性,对介观方程进行加速。基于高阶Hermite多项式重构分布函数,完成宏观方程与介观方程之间的数据传输。仿真结果表明:全流场耦合介观/宏观方程的加速方法在滑移流、早期过渡流区域具有显著加速性能,最大降低了95.28%的计算时长;但对中、大克努森数流域,加速性能大幅度下降。