层裂问题的数值研究

本文对Carrol、Holt 和Johnson提出的延性材料损伤断裂进行了改进。在模型中考虑了材料的硬化效应和空穴成核的影响。用数值方法模拟了高速碰撞中OFCH 铜和铝的层裂过程,其结果与实验吻合得相当好。     

协同仿真环境的设计与实现

本文从计算机技术和仿真技术的发展和应用需求出发，提出了协同仿真的基本概念和关键技术，包括建模方法、仿真算法、仿真数据库等几个方面。讨论了协同仿真环境的一般体系结构，最后，介绍了一种协同仿真环境的设计和实现方法。     

Vapor-phase decomposition of dimethyl methylphosphonate (DMMP), a sarin surrogate,in presence of metal oxides

Chemical warfare agents (CWA) are stockpiled in large quantities across the globe. Agents stored in inaccessible facilities need to be destroyed rapidly without dispersing the compounds to surrounding areas. Metal-based energetic formulations are used in such prompt defeat applications to rapidly decompose the CWA by generating a high temperature environment. An alternate, and possibly a more effective decomposition pathway could be provided by chemicidal action of aerosolized condensed combustion products, which typically consist of metal oxides. Toxic fumes that escape the high tem-perature blast zone can be neutralized by smoke generated during combustion, depending on the par-ticle size, surface characteristics, chemical properties, and concentration of this smoke. This review considers relevant experimental and modeling studies quantifying decomposition of CWA comprising organophosphorus compounds and their surrogates on the surface of various metal oxides. Dimethyl methylphosphonate (DMMP), a sarine surrogate, was used most commonly for such experiments. Many reported efforts focused on the mechanisms of adsorption of DMMP to various metal oxides and initial reaction steps cleaving various bonds from the chemisorbed molecules. For selected oxides, these ex-periments were supported by quantum-mechanical calculations. In other studies, the capacity of oxide surfaces to adsorb and decompose DMMP was quantified. In most cases, porous catalysts were used although limited experimental data are available for aerosolized nonporous oxide particles. The reported experimental data applicable to scenarios involving prompt decomposition of CWA are summarized. It is noted that information is lacking describing respective heterogeneous reaction kinetics. Preliminary estimates of aerosolized smoke particle concentrations required to destroy CWA are made considering gas phase diffusion rates and reported values of the oxide capacity to decompose CWA or their surrogates.     

爆炸沸腾研究进展

分析讨论了液体过热极限、汽泡内压力等爆炸沸腾的重要参数 ,综述了三种主要实验方法 ,提出了有待进一步研究的问题 .     

Novel aluminum-based fuel: Facile preparation to improve thermal reactions

To improve the thermal properties of aluminum (Al) in the energetic system, a coated structure with ammonium perchlorate (AP) was prepared by a facile approach. And N, N-Dimethylformamide (DMF) was chosen as an ideal solvent based on heterogeneous nucleation theory and molecular dynamics simulation. This coated structure could enlarge the contact area and improve the reaction environment to enhance the thermal properties. The addition of AP could accelerate oxidation temperature of Al with around 17.5 °C. And the heat release of 85@15 composition rises to 26.13 kJ/g and the reaction degree is 97.6% with higher peak pressure (254.6 kPa) and rise rate (1.397 MPa/s). An ideal ratio with 15 wt% AP was probed primarily. The high energy laser-induced shockwave experiment was utilized to simulate the reaction behavior in hot field. And the larger activated mixture of coated powder could release more energy to promote the growth of shockwave with higher speed up to 518.7 ± 55.9 m/s. In conclusion, 85@15 composition is expected to be applied in energetic system as a novel metal fuel.     

多晶硅制绒中影响金字塔结构因素的研究

通过分析不同碱性溶液及添加不同活性剂制备出的具有不同金字塔结构的绒面,探讨了影响金字塔成核的因素。采用扫描电镜和紫外一可见分光光度计对绒面的金字塔结构和反射特性进行了分析,结果表明,腐蚀速率与金字塔尺寸成正比,金字塔结构影响绒面减反特性。对造成金字塔结构差异的原因和金字塔成核过程进行了分析。     

基于MPI+CUDA的异构并行可压缩流求解器

在CPU/GPU异构体系结构计算集群上,建立了基于MPI+CUDA的异构并行可压缩流求解器。讨论了异构结构上的可压缩流并行算法的并行模式,在CPU上执行计算密集度低、指令复杂的计算任务,在GPU上执行计算密集度高、指令单一的计算任务。通过数个算例,对比了异构并行计算和传统CPU并行计算计算结果和计算效率。将该算法运用于高超声速流动的数值模拟中,数值结果显示,基于MPI+CUDA的异构并行可压缩流求解器鲁棒性好,计算效率较CPU同构并行计算提高10倍以上。     

非均匀形核法制备Cu包覆纳米SiO2复合粉体

采用非均匀形核法制备了Cu包覆纳米SiO2复合颗粒,利用X射线衍射仪、扫描电镜、能谱仪及透射电镜等分析手段对复合颗粒进行了表征,并探讨了包覆结构的形成机制。结果表明:复合颗粒分散均匀,无团聚,单颗粒内包含多个分布均匀的纳米SiO2颗粒,且均被Cu包覆层隔离,纳米SiO2颗粒的分散性得到了显著改善;新制备的复合颗粒不存在氧化,在存放或者制样过程中会部分氧化为Cu2O;纳米SiO2颗粒表面Cu包覆层的形成机制主要是非均匀形核作用,包覆的结构取决于 Cu晶粒在纳米SiO2颗粒表面的沉积以及对复合颗粒的团聚控制。