某型引信压电陶瓷加速老化试验

压电陶瓷作为压电引信的关键元件,其贮存可靠性至关重要。为研究贮存对压电陶瓷性能变化的影响,进行了历时176天的某型引信用压电陶瓷加速老化试验。根据试验结果研究了陶瓷的压电参数随试验条件和老化时间变化的规律,探索了压电陶瓷的贮存可靠性和可靠贮存寿命。     

Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging

In order to study the cross-linking density and aging constitutive relationship of HTPB coating during storage, the thermal accelerated aging tests at 0%, 3%, 6% and 9% prestrains were carried out. The cross-linking density of HTPB coating at different aging stages were tested using low-field ¹H NMR and the variation of cross-linking density was analyzed. The aging model of cross-linking density considering the chemical aging and the physical stretching factors was established. The uniaxial tensile tests were carried out on HTPB coating at different aging stages and the cross-linking density was introduced into Ogden hyperelastic constitutive model as a characterization parameter of correction coefficient. Combined with uniaxial tensile test results, a prestrain aging constitutive model of HTPB coating was established. The results show that the cross-linking density of HTPB coating increases rapidly at first and then slowly with the increase of thermal accelerated aging time without prestrain. Under prestrain conditions, the cross-linking density of HTPB coating decreases at the early stage, and increases rapidly at first and then slowly at the middle and late stages of thermal accelerated aging. The correlation coefficients of aging model of cross-linking density and aging constitutive model with test results are R > 0.9500 and R > 0.9900 respectively, which can be used to accurately describe the cross-linking density and aging constitutive relationship of HTPB coating under prestrain accelerated thermal aging conditions.     

老化对阻燃玻璃钢燃烧性能影响初探

通过对玻璃钢阻燃技术的介绍,以及老化对玻璃钢性能的影响,提出阻燃玻璃钢材质在自然环境中同样存在因老化而出现阻燃性降低的问题。     

舰船电缆热老化寿命的研究

介绍了某船用电缆热老化寿命研究的有关试验和结果分析．对电统绝缘材料失效的判断、机械性能变化的预测,以及如何根据电缆的负载情况和周围的环境温度确定绝缘材料的老化温度等,提出了相应的观点和方法．     

A higher order coupled frequency characteristics study of smartmagneto-electro-elastic composite plates with cut-outs using finite element methods

This article deals with investigating the effect of cut-outs on the natural frequencies of magneto-electro-elastic (MEE) plates incorporating finite element methods based on higher order shear deformation theory (HSDT). In order to consider the influence of cut-out, the energy of the cut-out domain is sub-tracted from the total energy of the entire plate. The governing equations of motions are derived through incorporating Hamilton's principle and the solution is obtained using condensation technique. The proposed numerical formulation is verified with the results of previously published literature as well as the numerical software. In addition, this research focuses on evaluating the effect of geometrical skewness and boundary conditions on the frequency response. The influence of cut-outs on the degree of coupling between magnetic, electric and elasticfields is also investigated.     

Physical and damping properties of kenaf fibre filled natural rubber/thermoplastic polyurethane composites

The paper presents the investigation of the effect of alkaline treatment of sodium hydroxide (NaOH) on physical and dynamic mechanical analysis (DMA) viscoelastic properties of kenaf fibre filled natural rubber (NR)/thermoplastic polyurethane (TPU) composites. The treated kenaf fiber, NR and TPU were weighed and proportioned according to the required compositions and were blended using hot mixed Brabender machine. The polymer composites were then fabricated using the hot press to form a sample board. The sample was cut and prepared and water absorption, density, thickness swelling and DMA tests were performed. As far as physical properties are concerned, composites with the highest NR amount of shows the best results, which indicates good fiber bonding adhesion. The polymer composites with the highest amount of TPU shows the highest damping properties at high temperature.     

定应变作用下NEPE推进剂老化特性及寿命预估研究

为考察定应变作用下NEPE推进剂的老化特性,研究了20%定应变作用下NEPE推进剂贮存老化过程中力学性能、凝胶性能和界面性能的变化.研究结果表明:定应变作用下NEPE推进剂在贮存老化过程中最大抗拉强度降低,最大延伸率变化较小,其老化失效主要表现为强度的失效;定应变下NEPE推进剂的凝胶百分数和粘附功随老化时间的延长而降低,NEPE推进剂粘合剂基体的降解断裂和界面的"脱湿"是其主要的老化机理;定应变下NEPE推进剂的力学性能与细观性能的相关性研究表明,最大抗拉强度与凝胶百分数和粘附功存在相关关系,计算了其关系式,建立了由细观性能评估推进剂宏观力学性能的方法;选择最大抗拉强度下降30%时失效,20%定应变下NEPE推进剂的贮存寿命为8.3年.     

Military Expenditures and Natural Resources: Evidence from Rentier States in the Middle East and North Africa

It has been argued that the discovery of a new natural resource greatly increases the risk of conflict. This research aims to study the effect of natural resources on military spending, using the data from rentier states in the Middle East and North Africa (MENA) countries from 1987 to 2012. In considering the ‘resource curse,’ the types of natural resources matter. Our empirical results demonstrate that the ‘resource curse’ arising from the abundance of certain natural resources, particularly oil and forest resources, leads to increases in military spending. In contrast, the rent from coal and natural gas has a negative impact on military spending, while the rent from minerals has no impact on military spending, controlling for GDP growth and per capita income.     

长贮过程中发动机HTPB推进剂老化机理分析

为揭示固体推进剂在长期贮存过程中的老化机理,解剖了自然贮存19年贴壁浇注的端羟基聚丁二烯橡胶推进剂装药发动机,沿着药柱径向不同位置进行了取样,并采用扫描电镜、能量色散X射线光谱仪、红外吸收光谱、交联密度等多种手段对这些样品进行了测试分析。研究发现：贴壁浇注发动机药柱不同位置推进剂的老化程度不尽相同,越靠近非金属壳体位置,推进剂的老化程度越严重。进一步深入分析表明：除了丁羟胶中双键的氧化断链和端羟基的缩合等影响推进剂老化,铝粉氧化产生的铝离子会催化丁羟胶双键与氯气或水发生加成反应生成■双键和仲醇,而铝离子迁移和分布的不均匀会引起药柱老化的不均匀性。研究结果对推进剂配方设计和防老化措施的研究具有重要意义。     

耐海水高耐候丙烯酸树脂的合成及面漆性能分析

为合成耐海水与高耐候的丙烯酸树脂,选择甲基丙烯酸甲酯、甲基丙烯酸羟丁酯、丙烯酸异辛酯和丙烯酸已内酯,经引发剂作用,采用同步滴加法进行聚合反应,通过调节温度并测定酸价控制反应历程,并将合成的不同玻璃化温度的丙烯酸树脂配制成具有适当玻璃化温度梯度的耐海水面漆成膜树脂体系。选择HDT-90固化剂与丙烯酸成膜树脂作用,制备耐海水面漆涂层样品。性能测试结果表明,研制的耐海水面漆具有优良的耐候性和抗老化性。