Influence of yttrium on microstructure and properties of Ni–Al alloy coatings prepared by laser cladding

Ni–Al alloy coatings with different Y additions are prepared on 45^# medium steel by laser cladding. The influence of Y contents on the microstructure and properties of Ni–Al alloy coatings is investigated using X-ray diffraction, scanning electron microscopy, electron probe microanalyzer, Vickers hardness tester, friction wear testing machine, and thermal analyzer. The results show that the cladding layers are mainly composed of NiAl dendrites, and the dendrites are gradually refined with the increase in Y additions. The purification effect of Y can effectively prevent Al₂O₃ oxide from forming. However, when the atomic percent of Y addition exceeds 1.5%, the extra Y addition will react with O to form Y₂O₃ oxide, even to form Al₅Y₃O₁₂ oxide, depending on the amount of Y added. The Y addition in a range of 1.5–3.5 at.% reduces the hardness and anti-attrition of cladding layer, but improves obviously its wear and oxidation resistances.     

Influence of high frequency pulse on electrode wear in micro-EDM

An electromagnetic coupling mathematical model is established by finite element method and is verified by the contrastive experiments of copper matrix Ni–TiN cylindrical coating electrode, copper electrode and Cu50W electrode. The wear mechanism of Ni–TiN/Cu composite electrode in the case of high-frequency pulse current is studied, and the influence of the fluctuation frequency of discharge current on electrode wear in micro-EDM is found out. Compared with the electrode made from homogeneous material, the high frequency electromagnetic properties of Ni–TiN composite layer can be used effectively to inhibit the effect of high frequency pulse on the electrode and improve the distribution trend of current density.     

电刷镀Ni镀层在海水中的腐蚀磨损试验

研究了电刷镀Ni镀层在海水中腐蚀磨损的失重情况。应用扫描电镜(SEM)和能谱仪(EDS)分别观测了Ni镀层在海水中腐蚀磨损后的形貌,并进行了成分分析,结果表明:Ni镀层腐蚀磨损后表面新增加了C、lO、Fe等元素,镀层表面除了有犁削沟槽,局部还出现了被海水腐蚀溶解的形貌。通过腐蚀磨损协同率计算得出:Ni镀层在海水中腐蚀磨损时,腐蚀与磨损发生了正协同作用,但磨损是材料流失的主要形式。     

低Ni/改性Al2O3催化剂表面性质表征

本文用氧吸附法和程序升温脱附（ＴＰＤ）法分别考察低Ｎｉ／改性Ａｌ２Ｏ３催化剂的分散度，环已烷和苯的吸附脱附性能。结果表明：该催化剂分散性好，表面至少存在两种吸附中心。苯、环已烷在该催化剂的表面上属于一级可逆吸附脱附过程，催化剂表面能量分布不均匀。     

气相苯加氢低Ni/改性Al2O3催化剂性能评价

通过对γ－Ａｌ２Ｏ３载体进行化学改性处理,把Ｎｉ的含量降低（在５％以内）制得气相苯加氢低Ｎｉ／改性Ａｌ２Ｏ３催化剂。考察反应条件对其催化活性影响,并对催化剂的活性稳定性、耐热性、抗毒物能力进行评价。结果表明：该催化剂的性能良好     

在单晶硅片上直接电化学沉积制备镍反opal光子晶体

采用电化学沉积工艺直接向组装在单晶硅片上的聚苯乙烯胶体晶体中填充金属Ni,成功制备了Ni的反opal光子晶体。采用线性扫描伏安法研究了单晶硅表面的化学刻蚀对Ni的电化学沉积过程的影响,并采用扫描电子显微镜(SEM)、X射线衍射等对Ni反opal光子晶体的形貌和结构进行了观察分析,对其光学性能进行了初步研究。研究结果表明,对单晶硅片表面进行化学刻蚀有利于金属Ni的电化学沉积;在PS胶体晶体模板中电化学生长的金属Ni呈多晶状态,去除模板后形成了金属Ni的有序多孔结构。     

掺镍氧化钨钼薄膜的阻抗特性

用溶胶凝胶的方法在ITO导电基片上制备了一组不同掺镍量的氧化钨钼薄膜,分别测量了该系统及ITO电极浸泡于1 mol氯化钠溶液中不同频率下的电化学阻抗,应用等效电路法模拟了该系统的阻抗谱,从而获得了有关掺镍薄膜的电阻、电容及溶液在薄膜内扩散等信息.研究表明,与ITO电极所产生的吸附层的等效元件参数相比较,掺镍氧化钨钼薄膜大大提高了ITO电极传输电荷的能力.     

超音速等离子制备Al/Ni涂层的性能特点

以超音速等离子喷涂系统(HEPJet)为平台,采用铝包镍(Al/Ni)自粘结粉末,借助Spray Watch2i在线监测系统、扫描电子显微镜(SEM)、X射线衍射仪(XRD)和WE-10A万能拉伸试验机,研究了超音速等离子喷涂Al/Ni粒子的速度、温度及涂层的组织性能。研究结果表明:超音速等离子喷涂Al/Ni自粘结粉末时,与普通火焰喷涂不同,射流中无明显的放热反应特征,涂层中也未发现Al-Ni化合物;超音速等离子的喷涂功率、喷涂距离等参数对Al/Ni喷涂粒子的状态和涂层组织性能影响显著,当功率为54.6kW、喷涂距离为150mm时,Al/Ni涂层组织致密,与基体的结合强度高达56MPa。