最小自由能法计算烟火药剂热值

烟火药剂的热值计算在烟火研究领域有着重要的作用．本文根据最小自由能原理，通过一系列基本假设计算出了体系燃烧爆炸反应后的热值，计算结果与实验衡量数据相吻合，并且程序可通过进一步完善，扩展应用于非理想气体，提高计算精度．

Application of minimized free energy theory in calculation of caloric of pyrotechnic compounds

It is very important that the caloric of pyrotechnic compounds is calculated in the pyrotechnic research field. Based on minimized free energy theory, the caloric of combustion-explosive reaction is calculated by a series of hypothesis. The results of caclulation are more consistent with the experimental results. The calculated program has extendible application to the nonideal gas and enhance the calculational precision in the future.