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发射药的分解机理及其安定性研究
引用本文:杜仕国.发射药的分解机理及其安定性研究[J].军械工程学院学报,1994(1).
作者姓名:杜仕国
作者单位:弹药试验中心
摘    要:在研究发射药中硝酸酯的分解机理及其与发射药安定性关系的基础上,分析了热分解,水解和自动催化作用对发射药安定性的影响,以色谱法和粘度法等实验手段探索发射药安定性的变化规律,通过不同温度下发射药老化过程的动力学研究,提出了确定发射药安全使用寿命的可靠方法。

关 键 词:发射药  硝酸酯  安定性  分解机理  动力学

STUDY OF THE DECOMPOSITION MECHANISM AND THE STABILITY OF PROPELLANT
Du Shiguo.STUDY OF THE DECOMPOSITION MECHANISM AND THE STABILITY OF PROPELLANT[J].Journal of Ordnance Engineering College,1994(1).
Authors:Du Shiguo
Institution:The Centre of Ammunition Test
Abstract:The mechanism of decomposition of nitric ester in propelknt and the stability of propellant are studied in this paper. The effect of thermolysis, hydrolytic decomposition and autocatalysis on the propellant stability is discussed. It presents the experimental methods of chromatography and viscosity, which detect the varying law of the propelant stability. The relia-ble process determining the safe operating life of propellant is given by means of propelknt aging dynamics at different temperature.
Keywords:propellant  nitric ester  stability  mechanism of decomposition  dynamics  
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