Effect of energy content of the nitraminic plastic bonded explosives on their performance and sensitivity characteristics

Information about the forty nine nitraminic plastic bonded explosives (PBXs) and different nitramines were collected. Fillers of these PBXs are nitramines 1,3,5-trinitro-1,3,5-triazinane (RDX) and β-1,3,5,7-tetranitro-1,3,5-tetrazocane (β-HMX), cis-1,3,4,6-tetranitro-octahydroimidazo-[4,5-d]imidazole (bicyclo-HMX, BCHMX) and ε-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (ε-HNIW, CL-20) which are bonded by polyfluoro-elastomers, polydimethyl-siloxane, poly-glycidyl azide, polyisobutylene, polystyrene-butadiene, poly-acrylonitrile-butadiene and hydroxyl-terminated polybutadiene in addition to a melt cast compositions based on 2,4,6-trinitrotoluene. For thirty two of these PBXs the relationships are specified and analyzed between heats of their combustion and relative explosive strengths; by means of these relationships it might be possible to estimate, which groupings in the macromolecule of binder could be liable to their primary fission in the PBXs initiation. Similarly, for forty two of these explosives, the relationships are described and analyzed between their enthalpies of formation and impact sensitivities; here is especially attention paid to PBXs filled by BCHMX. Specific rate constants from Vacuum Stability Test (VST) of four nitramines and twenty PBXs are introduced into relationships with their enthalpies of formation. Regarding to all the mentioned cases, increasing of energy content of the studied explosives leads to increase of the relative explosive strength or initiation reactivity, respectively. Exception with the opposite trend, the outputs of VST are for BCHMX, where in PBXs are matrices with the esteric plasticizers or the energetic poly-glycidyl azide. Admixture of RDX or HMX, respectively, into the BCHX PBXs gives ternary PBXs whose thermal stability, in the sense of applied VST, is higher comparing to the original binary explosives.     

Structure design and property adjustment of new cage rich-nitrogen pentazolyltetraazacubanes as potential high energy density compounds

In this study, based on two attractive energetic compounds pentazole (PZ) and tetraazacubane (TAC), a new family of high energy and high nitrogen compounds pentazolyltetraazacubanes were designed. Then, a different number of NH₂ or NO₂ groups were introduced into the system to further adjust the property. The structures, properties, and the structure-property relationship of designed molecules were investigated theoretically. The results showed that all nine designed compounds have extremely high heat of formation (HOF, 1226-2734 kJ/mol), good density (1.73–1.88 g/cm³), high detonation velocity (8.30–9.35 km/s), high detonation pressure (29.8–39.7 GPa) and acceptable sensitivity (ΔV: 41-87 ų). These properties could be effectively positive adjusted by replacing one or two PZ rings by NH₂ or/and NO₂ groups, especially for the energy and sensitivity performance, which were increased and decreased obviously, respectively. As a result, two designed pentazolyltetraazacubanes were predicted to have higher energy and lower sensitivity than the famous high energy compound in use 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane, while two others have better combination property than 1,3,5-Trinitro-1,3,5-triazacyclohexane. In all, four new pentazolyltetraazacubanes with good combination performance were successfully designed by combining PZ with TAC, and the further property adjustment strategy of introducing a suitable amount of NH₂/NO₂ groups into the system. This work may help develop new cage energetic compounds.     

Cell-type continuous electromagnetic radiation system generating millimeter waves for active denial system applications

The cell-type continuous electromagnetic radiation system is a demonstration device capable of generating high-power millimeter electromagnetic waves of a specific wavelength and observing their effects on living organisms. It irradiates a biological sample placed in a 30 × 30 × 50 cm³ cell with electromagnetic waves in the 3.15-mm-wavelength region (with an output of ≥1 W) and analyzes the temperature change of the sample. A vacuum electronic device-based coupled-cavity backward-wave oscillator converts the electron energy of the electron beam into radiofrequency (RF) energy and radiates it to the target through an antenna, increasing the temperature through the absorption of RF energy in the skin. The system causes pain and ultimately reduces combat power. A cell-type continuous electromagnetic radiation system consisting of four parts—an electromagnetic-wave generator, a high-voltage power supply, a test cell, and a system controller—generates an RF signal of ≥1 W in a continuous waveform at a 95-GHz center frequency, as well as a chemical solution with a dielectric constant similar to that of the skin of a living organism. An increase of 5 °C lasting approximately 10 s was confirmed through an experiment.     

水下激光成像系统在反蛙人侦察中的应用

水下激光成像系统作为一种主要的水下光电侦察装备,具有抗干扰能力强、探测距离远、成像质量高等诸多优点,可用于探测水下多种类型的目标。针对水下激光成像系统的反蛙人侦察应用问题展开研究,介绍了水下激光成像系统反蛙人侦察的技术、特点和现状,重点研究了水下激光成像系统几种典型的反蛙人侦察使用方法,并对今后水下激光成像系统反蛙人侦察的发展趋势进行了分析。     

Enhancing the explosive characteristics of a Semtex explosive by involving admixtures of BCHMX and HMX

A well-known ternary plastic explosive, Czech Semtex 1H, contains a mixture of PETN and RDX softened by SBR. In this work, BCHMX was used to replace PETN in Semtex 1H to form Sem-BC+RDX. In addition, another mixture based on BCHMX and HMX as energetic fillers bonded by the polymeric matrix of Semtex 1H (Sem-BC+HMX) was studied. The particle size distribution of each individual explosive was determined to obtain the optimum mixing conditions. Friction and impact sensitivities were determined. The velocity of detonation was reported practically and the detonation properties were calculated by EXPLO5 code. The explosive strength of each sample was measured by the ballistic mortar test. The conclusion confirms that the velocity of detonation of Sem-BC+HMX was the highest in comparison with the prepared samples. Sem-BC+RDX has the least impact and frictions sensitivities. Sem-BC+RDX has higher detonation velocity, detonation properties and explosive strength than Semtex 1H. Addition of BCHMX in Semtex 1H as a replacement for PETN is the candidate to produce a high performance advanced Czech plastic explosive.     

Effect of Drying on Particle Size and Sensitivities of Nano hexahydro-1,3,5-trinitro-1,3,5-triazine

Nano hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) was prepared using a bi-directional rotation mill and dried under different conditions (liquid, temperature and drying). It shows that the samples cake seriously and the particles grow up obviously by ordinary drying in different liquids at 70 °C, which occurs again after vacuum drying. With the increase of temperature, the degrees of caking and aggregation are enhanced. Well dispersed sample maintaining constant particle size is extracted by supercritical drying, especially freeze drying. Furthermore, the mechanical sensitivities of I-RDX, O-RDX and F-RDX, of which the average sizes are 88.03 μm, 15.32 μm and 0.16 μm, respectively, are evaluated. Compared with I-RDX, the friction, impact and shock sensitivities of O-RDX are slightly lower. However, the friction, impact and shock sensitivities of F-RDX are reduced by 30%, 99.0% and 59.9%, respectively.     

Burning characteristics of high density foamed GAP/CL-20 propellants

The monolithic foamed propellants with high densities were prepared by casting and two-step foaming processes. Glycidyl azide polymer (GAP) and isocyanate were used as the binder system and 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW, CL-20) was employed as the energetic component. The newly designed formulation containing 60 % CL-20 produced a force constant of 1077 J/g and low flame temperature of 2817 K. Two foamed propellants with densities of 1.32 g/cm³ and 1.53 g/cm³ were fabricated by a confined foaming process and examined by closed bomb tests. The results revealed that porosity significantly affects burning performance. A size effect on combustion behaviors was observed for the foamed propellant with 5.56 % porosity, and a double-hump progressive dynamic vivacity curve was obtained. At last, the 30 mm gun test was carried out to demonstrate the interior ballistic performance, and the muzzle velocity increased by 120 m/s at the same maximum chamber pressure when monolithic propellant was added in the charge.     

Shock initiation performance of NTO-based polymer bonded explosive

3-nitro-1,2,4-tri-azol-5-one (NTO) is a high energy insensitive explosive. To study the shock initiation process of NTO-based polymer bonded explosive JEOL-1 (32%octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), 32% NTO, 28% Al and 8% binder system), the cylinder test, the gap experiments and numerical simulation were carried out. Firstly, we got the detonation velocity (7746 m/s) and the parameters of Jones-Wilkins-Lee (JWL) equation of state (EOS) for detonation product by cylinder test and numerical simulation. Secondly, the Hugoniot curve of unreacted explosive for JEOL-1 was obtained calculating the data of pressure and time at different Lagrangian positions. Then the JWL EOS of unreacted explosive was obtained by utilizing the Hugoniot curve as the reference curve. Finally, we got the pressure growth history of JEOL-1 under shock wave stimulation and the parameters of the ignition and growth reaction rate equation were obtained by the pressure-time curves measured by the shock-initiation gap experiment and numerical simulation. The determined trinomial ignition and growth model (IG model) parameters can be applied to subsequently simulation analysis and design of insensitive ammunition with NTO-based polymer bonded explosive.     

皮秒脉冲泵浦的高功率超连续谱光源

实验研究利用皮秒脉冲泵浦光子晶体光纤产生高功率超连续谱输出,探讨制作高功率全光纤超连续谱光源的关键技术,分析不同结构皮秒脉冲光纤激光器泵浦光子晶体光纤产生超连续谱的优缺点.应用重复频率倍增技术降低激光器自身的非线性效应,得到性能参数合适的高功率皮秒脉冲光纤激光器;采用后处理技术将光子晶体光纤输入端扩芯后与双包层光纤进行...     

Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.     

利用OH-PLIF技术显示超声速燃烧的火焰结构

针对在来流马赫数为1.72的空气来流中横向喷注氢气发生超声速燃烧的流场,利用平面激光诱导氢氧基荧光(OH-PLIF)技术,对超燃燃烧室中三个不同的流向截面进行了二维成像测量。选择波长为283.553nm的染料激光倍频光作为激发光,可近似认为获得的OH基荧光信号强度与OH基的摩尔分数成正比。瞬态的OH基PLIF图像揭示了超声速燃烧火焰结构具有高度湍流特性,在凹腔内部存在稳定的燃烧区,为整个燃烧反应提供值班火焰,起到了促进和稳定超声速燃烧的作用。超燃火焰在沿流向传播的同时还沿径向传播,凹腔展向尺度增大时火焰沿流向的火焰区会有所减小。     

基于散射探测的鱼眼激光告警方法

分析了鱼眼激光告警系统的工作原理,建立了基于散射探测的鱼眼激光告警系统的探测模型,推导出系统的目标光斑成像公式及目标光斑到达探测系统的单像元能量公式,最后引用美国休斯飞机公司AN/TVQ-2激光目标指示器参数进行数值模拟分析,得出激光传输距离及鱼眼告警系统设置高度与探测器单像元能量的关系。     

Theoretical design of new bridge-ring insensitive high energy compounds by selected normal Diels-Alder reactions between NH2-substituted oxazoles and NO2/NF2/NHNO2-substituted ethylenes/acetylenes

In this work, NH₂-substituted oxazoles and NO₂/NF₂/NHNO₂-substituted ethylenes/acetylenes were designed and used as dienes and dienophiles, respectively, in order to develop new bridge-ring insensitive high energy compounds through the Diels-Alder reaction between them. The reaction type, reaction feasibility and performance of reaction products were investigated in detail theoretically. The results showed that dienes most possibly react with dienophiles through the HOMO-diene controlled normal Diels-Alder reaction at relatively low energy barrier. Tetranitroethylene could react with the designed dienes much more easily than other dienophiles, and was employed to further design 29 new bridge-ring energetic compounds. Due to high heat of formation, density and oxygen balance, all designed bridge-ring energetic compounds have outstanding detonation performance, 16 of them have higher energy than HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazocine) and 2 others even possess comparative energy with the representative of high energy compounds CL-20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane). The predicted average h₅₀ value of these bridge-ring energetic compounds is 83 cm, showing their low impact sensitivity. The NH₂ groups could obviously impel the proceeding of Diels-Alder reactions, but would slightly decrease the energy and sensitivity performance. In all, the new designed bridge-ring compounds have both high energy and low sensitivity, and may be produced through Diels-Alder reactions at relatively low energy barrier. This paper may be helpful for the theoretical design and experiment synthesis of new advanced insensitive high energy compounds.     

组合激光作用下CdS探测器破坏阈值实验研究

采用组合激光(即响应波段内532nm激光和响应波段外1319nm激光)对光导型CdS探测器进行辐照,测量了CdS探测器的破坏阈值。当1319nm激光辐照功率密度保持不变时,波段内激光的加入明显缩短了CdS探测器被破坏时激光所需的辐照时间,并且随着532nm激光功率密度的不断增大,辐照时间先减少后增加;当1319nm激光辐照时间保持不变时,随着532nm激光功率密度的增大,CdS探测器被破坏所需的1319nm激光功率密度先减小后增大,但恢复值仍比没有532nm激光加入时要小,说明了波段内激光的增强作用。上述两种变化趋势与相同条件下探测器的电压响应变化规律一致。     

Deconsolidation and combustion performance of thermally consolidated propellants deterred by multi-layers coating

Both heating and solvent-spray methods are used to consolidate the standard grains of double-base oblate sphere propellants plasticized with triethyleneglycol dinitrate (TEGDN) (TEGDN propellants) to high density propellants. The obtained consolidated propellants are deterred and coated with the slow burning multi-layer coating. The maximum compaction density of deterred and coated consolidated propellants can reach up to 1.39 g/cm³. Their mechanic, deconsolidation and combustion performances are tested by the materials test machine, interrupted burning set-up and closed vessel, respectively. The static compression strength of consolidated propellants deterred by multi-layer coating increases significantly to 18 MPa, indicating that they can be applied in most circumstances of charge service. And the samples are easy to deconsolidate in the interrupted burning test. Furthermore, the closed bomb burning curves of the samples indicate a two-stage combustion phenomenon under the condition of certain thickness of coated multi-layers. After the outer deterred multi-layer coating of consolidated samples is finished burning, the inner consolidated propellants continue to burn and breakup into aggregates and grains. The high burning progressivity can be carefully obtained by the smart control of deconsolidation process and duration of consolidated propellants. The preliminary results of consolidated propellants show that a rapid deconsolidation process at higher deconsolidation pressure is presented in the dynamic vivacity curves of closed bomb test. Higher density and higher macro progressivity of consolidated propellants can be obtained by the techniques in this paper.     

Estimation of the kinetic parameters for thermal decomposition of HNIW and its adiabatic time-to-explosion by Kooij formula

A differential/integral method to estimate the kinetic parameters (apparent activation energy E_a and pre-exponential factor A) for thermal decomposition reaction of energetic materials based on Kooij formula are applied to study the nonisothermal decomposition reaction kinetics of hexanitrohexaazaisowurtzitane (HNIW) by analyzing nonisothermal DSC curve data. The apparent activation energy (E_a) obtained by the integral isoconversional non-isothermal method based on Kooij formula is used to check the constancy and validity of apparent activation energy by the differential/integral method based on Kooij formula. The most probable mechanism function of thermal decomposition reaction of HNIW is determined by a logical choice method. The equations for calculating the critical temperatures of thermal explosion (T_b) and adiabatic time-to-explosion (t_TIad) based on Kooij formula are used to calculate the values of T_b and t_TIad to evaluate the thermal safety and heat-resistant ability of HNIW. All the original data needed for analyzing the kinetic parameters are from nonisothermal DSC curves. The results show that the kinetic model function in differential form and the values of E_a and A of decomposition reaction of HNIW are 3(1 − α)[−ln(1 − α)]^2/3, 152.73 kJ mol⁻¹ and 10^11.97 s⁻¹, respectively, and the values of self-accelerating decomposition temperature (T_SADT), T_b and t_TIad are 486.55 K, 493.11 K and 52.01 s, respectively.     

基于LOG算子的激光雷达图象边缘检测算法改进

针对LOG算子的不足之处,提出了一种激光雷达图像的边缘检测改进LOG算子算法:用二维自适应Wiener滤波代替Gaussian滤波。仿真结果表明:对于含有高斯噪声和乘性噪声的激光雷达图像,该算法能够有效提高LOG算子的边缘检测能力。     

Noise and vibration measurements in a Viking military vehicle

Noise and whole-body vibration measurements were made in a Viking military vehicle to determine the variation that should be expected during repeat measures, the effect of speed (up to 60 km/h in 5 km/h increments), and during travel over different types of terrain (comprising concrete road, gravel track and rough cross-country). Measurements were made at various crew positions (including the driver and commander) in both the front and the rear cabs in the vehicles. Three translational axes of vibration were measured in each seat. Two speeds were investigated over road (35 km/h and 55–60 km/h) and gravel (20 km/h and 35 km/h) surfaces. The effect of varying speed of the vehicle on the measured noise and vibration magnitudes was also investigated. The highest sound pressure level (L_Aeq) of 104 dB(A) was measured at the commander’s standing position during travel over concrete road at 55 km/h. Higher noise levels occurred for a standing commander compared with when sitting on the seat. A maximum single axis frequency-weighted vibration magnitude of 1.0 m/s² r.m.s. was measured on the driver’s seat during travel over track at 35 km/h. Higher vibration magnitudes occurred during travel over track compared with travel over road. Both noise and vibration exposure of crew within the Viking vehicle increased with increasing speed of the vehicle.     

基于时间反转声学理论的超声相控阵超分辨率成像方法

在超声相控阵检测领域,常规成像方法遵守瑞利准则,其成像分辨率受到波长限制。研究时间反转多信号分类(Time Reversal-MUltiple SIgnal Classification, TR-MUSIC)方法,在保持超声波工作频率不变且不影响系统探测深度的前提下,可提高成像分辨率,实现超分辨率成像。通过全矩阵采集方法获取被测对象的超声阵列数据;利用平面B扫描和TR-MUSIC方法处理数据,得到二维和三维超声图像;依据图像特征评估被测对象内部状况。实验选取加工不锈钢试块作为被测对象,搭建超声相控阵检测系统,在试块内部加工6个直径为1 mm、可视为点散射体的相邻贯通孔作为缺陷。实验表明,TR-MUSIC方法能够区分并定位这6个相邻点散射体,而平面B扫描方法则不能。因此,基于时间反转声学理论的TR-MUSIC方法可以提高成像分辨率,改善超声图像质量。     

激光成像自动对焦系统的散斑噪声滤波算法

针对激光主动探测成像的散斑（Speckle）噪声影响自动对焦系统的清晰度评价函数曲线,从而影响对焦性能的问题,提出一种多方向线型加权形态滤波方法。实验证明：基于该方法构造的滤波器明显改善了激光图像清晰度评价曲线（即自动对焦曲线）的形状,降低了误对焦率,提高了自动对焦系统的稳定性。