油漆稀料燃烧残留物的薄层色谱分析

采用薄层色谱扫描分析技术对醇酸、硝基油漆稀料在不同载体下的燃烧残留物进行了研究。制备了不同载体上的油漆稀料燃烧残留物,并以三氯甲烷为萃取剂对残留物进行提取,得到分析样品;结果显示,不同成分的油漆稀料特征组分不同,而不同载体对特征组分Rf值影响不同;通过对油漆稀料燃烧残留物的薄层色谱扫描分析,可以帮助火灾调查人员准确、快速的判断火场中油漆稀料的存在,为鉴定油漆稀料放火火灾提供借鉴。     

汽油燃烧产物GC-MS分析的萃取剂研究

应用色谱/质谱联用技术对提取93#汽油燃烧烟尘及残留物特征组分的五种萃取剂进行了对比研究。在确保制样过程中汽油组分提取量尽可能一致性的条件下,以提取出的有机特征组分的种类和相对峰面积为标准,利用总离子流色谱图和质量色谱图定性分析了五种萃取剂的萃取效果。     

细水雾灭室内池火实验研究

实验研究了燃烧热释放速率和腔室开口面积对细水雾灭室内池火的影响.结果表明,开口面积一定时,灭火时间随池火燃烧热释放速率先减小后增大;燃烧室全封闭时,灭火时间随燃烧热释放速率单调下降.当燃烧热释放速率一定时,开口面积越小,极限氧气浓度越低,表明燃烧产物对燃烧的抑制作用增加;开口面积一定时,随着燃烧热释放速率的增加,极限氧气浓度出现先减小后增大的变化规律,表明水雾对燃烧的抑制作用先降低后增加.     

典型包装材料燃烧性能实验研究

使用锥形量热仪对典型包装材料———内衬聚苯乙烯(PS)泡沫塑料外包装硬纸板的燃烧性能进行了实验研究,测得了不同热辐射强度下包装材料样品的点燃时间、热释放速率、质量损失率、比消光面积(发烟量)、CO的产率等燃烧性能参数。实验结果表明,包装材料受热辐射时很容易被点燃,燃烧时放出大量的热和有毒烟气。     

基于缸盖振动的燃油喷射系统故障诊断

对V型12缸柴油机缸盖振动燃烧段信号与缸内压力进行了时域对比,分析了失火时的缸盖振动响应,研究了供油规律随转速变化情况。分析表明缸盖振动中包含喷油器针阀落座的振动响应,研究了基于短时能量动态双阈值端点检测提取针阀落座响应时间特征的方法,利用振动信号的峰值加速度来表征针阀落座的强度。在不同工况及不同状态下提取了针阀落座时间及强度的振动特征,结果表明：振动特征能够有效反映针阀的工作情况,可以用于燃油喷射系统故障的诊断。     

漏磁信号特征提取及检测研究

介绍了漏磁检测原理和用有限元法计算漏磁场的方法,漏磁场法向分量的峰-峰值随缺陷深度增加而增加,峰-峰值间隔随缺陷宽度增大而增大。在检测中,先去除漏磁信号的奇异值,然后用峰-峰值算法提取缺陷信号特征,根据信号的峰-峰值大小和信号梯度变化作为缺陷判别标准。     

室内装饰织物燃烧特性研究

室内装饰织物因其容易点燃、燃烧速度快、蔓延迅速等燃烧特性,对室内火灾的发展蔓延及火灾危害都有重要影响。运用锥形量热仪对棉麻、涤纶、帆布、泡纱、条绒等5种室内装饰织物的燃烧性能进行了实验研究,测量了室内装饰织物在不同热辐射条件下的燃烧特性,并对实验数据进行图像拟合,通过具体的实验数据和图像分析比较了5种室内装饰织物在不同热辐射条件下的点燃时间、热释放速率、质量损失速率、比消光面积及CO生成量。最后得出了各种织物的火灾危险性相对大小。     

粉末燃料冲压发动机内镁粉尘云层流燃烧模型

对粉末燃料冲压发动机预燃室内镁粉尘云燃烧过程进行了研究,建立了镁粉尘云的一维层流预混燃烧模型。研究表明,镁粉尘云层流火焰传播很稳定,燃烧过程中火焰结构基本不变,燃烧区很薄,而预热区厚度约是燃烧区的2-3倍。粉尘云中镁颗粒的蒸发和气相镁与氧气的均相反应是产生火焰的直接原因,也是火焰得以传播的关键。预热区气相温度升高主要靠燃烧区气体的导热和扩散过来的气相镁与氧气反应释放热量,而预热区颗粒相温度升高主要靠气相对其对流传热。分析了各参数对粉尘云燃烧的影响,颗粒相对浓度对粉尘云燃烧的影响比较复杂,在浓度较低的情况下,增大颗粒相对浓度有利于粉尘云快速燃烧;而在浓度较高的情况下,增大颗粒相对浓度则不利于粉尘云快速燃烧。随颗粒粒径的增加,火焰传播速度减小,火焰温度升高,预热区厚度增大。火焰传播速度和火焰温度随粉尘云初温增加线性增长,预热区厚度随粉尘云初温增加抛物线增长。数值模拟与文献中试验结果的变化趋势相一致。     

微波加热辅助多孔介质水合物制样方法与装置

针对多孔介质中人工合成水合物分布不均匀问题,提出采用微波加热法制备多孔介质水合物样品的新途径,并设计了专用微波加热装置。基于电磁场理论及微波加热均匀性影响因素分析,设计了多馈源可调式波导加热系统。通过数值模拟和加热试验分析馈能口与样品间相对位置变化对装置加热均匀性影响,探讨该装置用于水合物样品制备的可行性。结果表明:装置加热均匀性受馈能口与样品间相对位置影响较大,其加热均匀性随二者间距的增加而显著提高,数值模拟与试验结果取得了较好的一致性;加热时间对装置的加热均匀性影响较小,该微波加热装置可满足制备均匀分布水合物样品的要求,同时对于其他对加热均匀性有一定要求的试验装置的设计具有参考意义。     

电缆高辐射热通量下燃烧性能实验研究

利用锥形量热仪对国产典型PVC电缆进行实验研究,分析其在高辐射热通量条件下的热释放速率（HRR）、质量损失速率（MLR）、比消光面积（SEA）、CO产率、火灾性能指数（FPI）、点燃时间（TTI）随直径的变化规律,以及不同热辐射通量对这些燃烧参数的影响。实验结果表明：在相同实验条件下,PVC电缆的HRR、MLR、SEA、CO产率均随直径的增大而增大,FPI随直径的增大而减小,火灾危险性增大;电缆直径的变化对点燃时间影响不大;随着热辐射通量的增大,PVC电缆的点燃时间缩短,HRR、MLR增大,其峰值也增大,烟释放速率（SPR）和总烟释放量（TSR）增加,FPI减小,火灾危险性增大。     

小汽车火灾燃烧特性及影响因素研究

在系统调研国内外全尺寸小汽车火灾试验的基础上,对小汽车火灾燃烧特性及影响因素进行了分析,提出了点火时间、燃烧持续时间、发展到HRR峰值所用时间、HRR峰值、热释放总量、单位可燃物热释放值等反映小汽车火灾燃烧特性的6个主要参数,并分析了对小汽车火灾燃烧特性产生较大影响的小汽车本身的燃烧性能、点火部位和点火方式、试验空间的围合状态以及油箱材质和油料数量等主要影响因素。     

燃气发生器低频非稳态燃烧统计分析

针对冲压发动机地面试验需求,设计燃气发生器,通过试验统计研究其燃烧稳定性特征。结果表明:该燃气发生器发生低频非稳态燃烧的概率为32.7%,存在两种振荡形态。一种存在振荡主频,即低频不稳定燃烧;另一种没有主频,燃烧形态为粗暴燃烧。粗暴燃烧发生概率高且与余氧系数存在较强的相关性,低频不稳定燃烧发生概率低。两种形态的振荡能量分布位置不同。     

Combustion of B4C/KNO3 binary pyrotechnic system

Presented herein is an experimental study on the combustion of B4C/KNO3 binary pyrotechnic system.Combustion products were tested using X-ray diffraction(XRD),scanning electron microscopy(SEM),and energy dispersive spectrometer(EDS).According to the results of tests and CEA calculation,the combustion reaction equation was established.The flames and burning rates were recorded by a high speed camera and a spectrophotometer.The effect of B4C particle size on the thermal sensitivity of B4C/KNO3 was investigated by differential scanning calorimetry(DSC)techniques.In addition,a reliable method for calculating the flame temperature was proposed.Based on the results of experiments,the combustion reaction mechanism was briefly analyzed.The burning rate,flame temperature and thermal sensitivity of B4C/KNC3 increase with the decrease of B4C particle size.The mass ratio of B4C/KNO3 has a great effect on combustion properties.Oxidizer-rich compositions have low flame temperatures,low burning rates,and provide green light emission.The combustion reactions of fuel-rich compositions are vigorous,and the B4C/KNO3 with mass ratio of 25:75 has the highest burning rate and the highest flame temperature.     

液氧与气氧对空气加热器燃烧流场的影响分析

针对一种基于液体火箭发动机燃烧室结构的空气加热器,采用数值仿真技术研究了加热器内部喷雾燃烧、燃气掺混以及出口流场分布等参数.分析对比了采用酒精/液氧/空气与酒精/气氧/空气两种不同氧化剂物态三组元同轴直流式喷嘴所得到的燃烧流场的区别,并通过改变燃烧室特征长度,分析了两种计算工况的加热器的性能差异.结果表明,喷入氧化剂的物态对燃烧流场影响较大,采用液氧喷嘴的火焰较长,气氧喷嘴的火焰分布较宽,且相对于液氧喷嘴,气氧喷嘴的燃烧室前端回流区由于掺混较多的燃气,导致喷注面板附近燃气温度较高,面板承热压力较大.设计的加热器均可保证两种喷嘴的出口流场品质较高,在保证流场出口品质的原则上,气氧喷嘴的燃烧室特征长度可至少小于液氧喷嘴的1/4.     

Multiproduct batching and scheduling with buffered rework: The case of a car paint shop

We study a problem of scheduling products on the same facility, which is motivated by a car paint shop. Items of the same product are identical. Operations on the items are performed sequentially in batches, where each batch is a set of operations on the same product. Some of the produced items are of the required good quality and some items can be defective. Defectiveness of an item is determined by a given simulated function of its product, its preceding product, and the position of its operation in the batch. Defective items are kept in a buffer of a limited capacity, and they are then remanufactured at the same facility. A minimum waiting time exists for any defective item before its remanufacturing can commence. Each product has a sequence independent setup time which precedes its first operation or its operation following an operation of another product. A due date is given for each product such that all items of the same product have the same due date and the objective is to find a schedule which minimizes maximum lateness of product completion times with respect to their due dates. The problem is proved NP‐hard in the strong sense, and a heuristic Group Technology (GT) solution approach is suggested and analyzed. The results justify application of the GT approach to scheduling real car paint shops with buffered rework. © 2014 Wiley Periodicals, Inc. Naval Research Logistics 61: 458–471, 2014     

固冲发动机补燃室凝相碳颗粒燃烧研究

应用改进的移动火焰锋面(MFF)模型,分析了环境压力、温度等参数对碳颗粒燃烧过程的影响。在此基础上,研究了固冲发动机补燃室内碳颗粒的燃烧过程,得到了固冲补燃室环境中的碳颗粒燃烧特性,并通过固冲直连式试验验证了数值模拟结果。结果表明:补燃室中大部分碳颗粒在进气道出口附近燃烧。     

Sensitivity Test and Data Analysis for Storage Reliability Assessment of Explosive Initiator

The explosive initiator is one kind of sensitivity products with long life and high reliability.In order to improve the storage reliability assessment,the method of storage reliability assessment for explosive initiator was proposed based on time series model using the sensitivity test data.In the method,the up and down test was used to estimate the distribution parameters of threshold.And an approach to design the up and down test was present to draw better estimations.Furthermore,the method of shrinkage estimation was introduced to get a better estimation of scale parameter by combining the sample information with prior information.The simulation result shows that the shrinkage estimation is better than traditional estimation under certain conditions.With the distribution parameters estimations,the time series models were used to describe the changing trends of distribution parameters along with storage time.Then for a fixed storage time,the distribution parameters were predicted based on the models.Finally,the confidence interval of storage reliability was obtained by fiducial inference.The illustrative example shows that the method is available for storage reliability assessment of the explosive initiator with high reliability.