固冲发动机补燃室凝相碳颗粒燃烧研究

应用改进的移动火焰锋面(MFF)模型,分析了环境压力、温度等参数对碳颗粒燃烧过程的影响。在此基础上,研究了固冲发动机补燃室内碳颗粒的燃烧过程,得到了固冲补燃室环境中的碳颗粒燃烧特性,并通过固冲直连式试验验证了数值模拟结果。结果表明:补燃室中大部分碳颗粒在进气道出口附近燃烧。     

进气道角度对含硼推进剂固冲发动机性能的影响

为了提高含硼推进剂固体火箭冲压发动机内硼颗粒的燃烧效率,采用颗粒轨道模型进行了补燃室两相流的数值模拟,其中硼颗粒的点火和燃烧模型采用的是King模型,建立了发动机补燃室内简单反应流模型,在该模型下研究了进气道的位置对非壅塞固体火箭冲压发动机燃烧效率的影响,并在此基础上进行直连式试验研究.结果表明,后进气道角度为60°时的燃烧效率比90°时高.     

头部两侧和单侧进气对固冲发动机燃烧影响

为了研究进气道布局形式对固冲发动机二次燃烧性能的影响,分别对头部两侧进气和单侧进气2种布局方案的固冲发动机开展了二次燃烧仿真和试验对比研究。结果表明:单侧进气时补燃室掺混燃烧效果优于两侧进气;单侧进气会导致补燃室局部出现高温高速区域,对补燃室热防护不利;在相同的工况下单侧进气获得的推力与两侧进气相当。     

带有中心预燃室的冲压发动机数值模拟研究

为提高低压条件下燃烧室点火和火焰稳定性能,设计了一种中心预燃室结构的冲压发动机。运用数值模拟方法对简化燃烧室内部的喷雾燃烧流场进行了分析。结果表明:随着燃烧室工作阶段的不同,预燃室尾部收缩段对内外涵气流相互作用的影响存在差异;由于局部压差的增大,预燃室取气口将出现局部加速效应;预燃室内流动过程受下游燃烧的影响。     

数值模拟气/气喷嘴速度比对燃烧性能的影响

为研究应用于全流量补燃循环发动机的不同气/气喷嘴得到的燃烧流场,通过求解NavierStokes方程组,对不同燃料与氧化剂速度比下的流动燃烧过程进行了数值计算,计算结果与实验结果吻合。仿真结果表明:增加速度比能使燃烧火焰面提前,燃烧效率变大。如果发动机的长度受到限制,可以适当增加速度比以实现高效燃烧。     

固冲发动机进气道工作过程干扰因素

分析了固冲发动机进气道、补燃室、尾喷管一体化流场中,在不同干扰因素下的进气道工作过程,研究了进气道出口燃气压力在时间上和空间上的突变以及尾喷管喉径的突变对进气道内部流动过程的影响,得到了不同干扰因素下的进气道工作特性.结果表明:进气道出口燃气压力在时间上的突变容易引起进气道出口燃气反压分布不均;进气道内流场对压力空间突...     

气态煤油超声速燃烧简化化学反应模型

为探究超燃冲压发动机燃烧室中煤油燃料燃烧的化学动力学过程，综合采用敏感性分析方法与路径分析方法，针对RP-3航空煤油三组分替代燃料的详细反应模型进行简化，建立一种适用于超声速燃烧流场数值模拟的新型26组分89反应简化燃烧反应模型。采用该简化燃烧模型对RP-3航空煤油替代燃料的点火、燃烧特性进行数值模拟，并与详细反应模型结果和试验数据进行对比校验。此外，将该简化燃烧模型与超声速燃烧流场计算方法相结合，数值分析了典型超燃冲压发动机燃烧室流场内化学动力学特性。研究结果表明：新型简化燃烧反应模型在不影响数值模拟精度的前提下，有效减少了反应组分与反应方程个数，提高了超声速复杂燃烧流场的数值模拟效率，并且能够准确获得烯烃、炔烃等重要中间燃烧产物以及小分子活性基团的空间分布规律，给出更全面的流场信息。     

空气/煤油/水燃气发生器点火特性试验

燃气发生器是超燃冲压发动机地面试验系统中的关键设备,为提高系统安全性和经济性设计了空气/煤油/水燃气发生器,在富燃状态下进行了一系列点火试验,试验结果表明:该型燃气发生器,实现可靠点火的余氧系数下限为0.51;水的加入使得化学反应速率和火焰传播速度降低,燃气发生器点火和火焰稳定困难,提高余氧系数可以提高点火可靠性。同时,水的加入容易引起燃烧不稳定,通过提高余氧系数来消除低频不稳定燃烧。     

空气/煤油/水燃气发生器点火特性试验研究

燃气发生器是超燃冲压发动机地面试验系统中的关键设备,为提高系统安全性和经济性设计了空气/煤油/水燃气发生器,在富燃状态下进行了一系列点火试验,试验结果表明：该型燃气发生器,实现可靠点火的余氧系数下限为0.51;水的加入使得化学反应速率和火焰传播速度降低,燃气发生器点火和火焰稳定困难,提高余氧系数可以提高点火可靠性。同时水的加入容易引起燃烧不稳定,通过提高余氧系数可消除低频不稳定燃烧。     

预燃室内气氢气氧射流燃烧过程数值分析

建立了液体火箭发动机预燃室内气氢气氧射流燃烧过程的数学模型,包括燃烧过程控制守恒方程、湍流流动方程和湍流燃烧模型,以及求解控制方程所需的辅助关系式;给出了模拟射流燃烧过程的数值方法。对于给定的预燃室结构型式和尺寸,研究了喷嘴构型和氧的喷射方式对化学反应流场和燃烧性能的影响规律。结果表明,喷嘴构型和氧的喷射方式对流动过程和燃烧性能都有影响,且喷嘴结构的影响较为明显。     

Liquid phase in-situ synthesis of LiF coated boron powder composite and performance study

Among practical metal additives, boron (B) has a high volumetric heating value, making it a promising choice as a fuel additive. Although B can theoretically yield a large amount of energy upon complete combustion, its combustion is retarded by the initial presence of B oxide, which coats the surfaces of B particle. To improve the ignition and combustion properties of B powder, LiOH and NH₄F were used as precursors to synthesize uniformly LiF-coated B composites (LiF-B) in situ. The LiF-B mixture was also prepared for comparison using a physical method. X-ray diffraction (XRD), Fourier-transform infrared (FTIR), scanning electron microscope (SEM), and energy-dispersive X-ray spectroscopy (EDS) were used to characterize the morphologies and compositions of the products. The thermal and combustion properties of the samples were characterized by thermal gravity-differential thermal gravity (TG-DTG), differential scanning calorimetry (DSC) and closed bomb experiment. The XRD, FTIR, SEM and EDS results demonstrated the successful preparation of the coated LiF-B sample. The TG-DTG and closed bomb experiment results indicated that the addition of LiF decreased the ignition temperature of B powder, and increasing its reaction efficiency. DSC results show that when LiF-B was added, the released heat of underwater explosive increased by 6727.2, 7280.4 and 3109.6 J/g at heating rates of 5, 10, and 15 °C/min, respectively. Moreover, LiF-B decreased the activation energy of secondary combustion reaction of explosive system as calculated through Kissinger's method by 28.9%, which indicated an excellent catalytic effect for the thermal decomposition of underwater explosive. The results reveal that LiF can improve the combustion efficiency of B powder, thereby increasing the total energy of explosives. The mechanical sensitivity increased slightly after adding LiF-B to the underwater explosive. Compared to the underwater explosive with added B, the mechanical sensitivity of the explosive with added LiF-B was significantly lower.     

The surface activation of boron to improve ignition and combustion characteristic

Boron is a very promising and highly attractive fuel because of high calorific value. However, the practical applications in explosives and propellants of boron have been limited by long ignition delay time and low combustion efficiency. Herein, nano-Al and graphene fluoride (GF) as surface activated materials are employed to coat boron (B) particles to improve ignition and combustion performance. The reaction heat of nano-Al coated B/KNO₃ and GF coated B/KNO₃ are 1116.83 J/g and 862.69 J/g, respectively, which are higher than that of pure B/KNO₃ (823.39 J/g). The ignition delay time of B/KNO₃ could be reduced through nano-Al coating. The shortest ignition delay time is only 75 ms for B coated with nano-Al of 8 wt%, which is much shorter than that of pure B/KNO₃ (109 ms). However, the ignition delay time of B/KNO₃ coated with GF has been increased from 109 to 187 ms. B coated with GF and nano-Al shown significantly influence on the pressure output and flame structure of B/KNO₃. Furthermore, the effects of B/O ratios on the pressure output and ignition delay time have been further fully studied. For B/KNO₃ coated with nano-Al and GF, the highest pressures are 88 KPa and 59 KPa for B/O ratio of 4:6, and the minimum ignition delay time are 94 ms and 148 ms for B/O ratio of 7:3. Based on the above results, the reaction process of boron coated with GF and nano-Al has been proposed to understand combustion mechanism.     

Combustion of B4C/KNO3 binary pyrotechnic system

Presented herein is an experimental study on the combustion of B4C/KNO3 binary pyrotechnic system.Combustion products were tested using X-ray diffraction(XRD),scanning electron microscopy(SEM),and energy dispersive spectrometer(EDS).According to the results of tests and CEA calculation,the combustion reaction equation was established.The flames and burning rates were recorded by a high speed camera and a spectrophotometer.The effect of B4C particle size on the thermal sensitivity of B4C/KNO3 was investigated by differential scanning calorimetry(DSC)techniques.In addition,a reliable method for calculating the flame temperature was proposed.Based on the results of experiments,the combustion reaction mechanism was briefly analyzed.The burning rate,flame temperature and thermal sensitivity of B4C/KNC3 increase with the decrease of B4C particle size.The mass ratio of B4C/KNO3 has a great effect on combustion properties.Oxidizer-rich compositions have low flame temperatures,low burning rates,and provide green light emission.The combustion reactions of fuel-rich compositions are vigorous,and the B4C/KNO3 with mass ratio of 25:75 has the highest burning rate and the highest flame temperature.     

粉末燃料冲压发动机内镁粉尘云层流燃烧模型

对粉末燃料冲压发动机预燃室内镁粉尘云燃烧过程进行了研究,建立了镁粉尘云的一维层流预混燃烧模型。研究表明,镁粉尘云层流火焰传播很稳定,燃烧过程中火焰结构基本不变,燃烧区很薄,而预热区厚度约是燃烧区的2-3倍。粉尘云中镁颗粒的蒸发和气相镁与氧气的均相反应是产生火焰的直接原因,也是火焰得以传播的关键。预热区气相温度升高主要靠燃烧区气体的导热和扩散过来的气相镁与氧气反应释放热量,而预热区颗粒相温度升高主要靠气相对其对流传热。分析了各参数对粉尘云燃烧的影响,颗粒相对浓度对粉尘云燃烧的影响比较复杂,在浓度较低的情况下,增大颗粒相对浓度有利于粉尘云快速燃烧;而在浓度较高的情况下,增大颗粒相对浓度则不利于粉尘云快速燃烧。随颗粒粒径的增加,火焰传播速度减小,火焰温度升高,预热区厚度增大。火焰传播速度和火焰温度随粉尘云初温增加线性增长,预热区厚度随粉尘云初温增加抛物线增长。数值模拟与文献中试验结果的变化趋势相一致。     

Tuning the reactivity of Al–Ni by fine coating of halogen-containing energetic composites

In this paper, various core-shell structured Al–Ni@ECs composites have been prepared by a spray-drying technique. The involved ECs refer to the energetic composites (ECs) of ammonium perchlorate/nitrocellulose (AP/NC, NA) and polyvinylidene fluoride/hexanitrohexaazaisowurtzitane (PVDF/CL-20, PC). Two Al–Ni mixtures were prepared at atomic ratios of 1:1 and 1:3 and named as Al/Ni and Al/3Ni, respectively. The thermal reactivity and combustion behaviors of Al–Ni@ECs composites have been comprehensively investigated. Results showed that the reactivity and combustion performance of Al–Ni could be enhanced by introducing both NA and PC energetic composites. Among which the Al/Ni@NA composite exhibited higher reactivity and improved combustion performance. The measured flame propagation rate (v = 20.6 mm/s), average combustion wave temperature (T_max = 1567.0 °C) and maximum temperature rise rate (γ_t = 1633.6 °C/s) of Al/Ni@NA are higher than that of the Al/Ni (v = 15.8 mm/s, T_max = 858.0 °C, and γ_t = 143.5 °C/s). The enhancement in combustion properties could be due to presence of the acidic gaseous products from ECs, which could etch the Al₂O₃ shell on the surface of Al particles, and make the inner active Al to be easier transported, so that an intimate and faster intermetallic reaction between Al and Ni would be realized. Furthermore, the morphologies and chemical compositions of the condensed combustion products (CCPs) of Al–Ni@ECs composites were found to be different depending on the types of ECs. The compositions of CCPs are dominated with the Al–Ni intermetallics, combining with a trace amount of Al₅O₆N and Al₂O₃.     

复合固体推进剂颗粒填充模型及其统计特性分析

复合固体推进剂属于高填充比颗粒类复合材料,氧化剂和金属颗粒在基体中的随机分布使其在细观尺度具有非均质的特点。从细观尺度研究固体推进剂燃烧及力学性能时,必须考虑颗粒级配、空间分布和种类等因素的影响。采用分子动力学方法,以硝酸酯增塑聚醚高能复合固体推进剂为研究对象,将固体颗粒模型化为球形,生成其在基体内随机分布的颗粒填充模型。利用Monte-Carlo算法模拟计算颗粒填充模型细观结构的两点概率函数,并研究了颗粒填充体积分数、尺寸与级配等参数对其的影响规律。从统计意义上给出具有各态历经性、统计均匀性和各向同性特点的颗粒填充构型最小周期性代表体元尺寸,可有效减小后续研究的计算量,节约计算成本。所构建的推进剂细观几何构型及对最小周期性代表体元尺寸的计算为后续开展复合固体推进剂细观尺度燃烧、燃面处铝团聚及力学性能数值研究奠定了基础。     

Combustion characteristic and aging behavior of bimetal thermite powders

Nanothermites have been employed as fuel additives in energetic formulations due to their higher en-ergy density over CHNO energetics. Nevertheless, sintering and degradation of nanoparticles signifi-cantly limit the practical use of nanothermites. In this work, combustion characteristic and aging behavior of aluminum/iron oxide (Al/Fe2O3) nanothermite mixtures were investigated in the presence of micron-scale nickel aimed to produce bimetal thermite powders. The results showed that the alumina content in the combustion residue increased from 88.3％ for Al/Fe2O3 nanothermite to 96.5％ for the nanothermite mixture containing 20 wt％nickel. Finer particle sizes of combustion residue were obtained for the nanothermite mixtures containing nickel, indicative of the reduced agglomeration. Both results suggested a more complete combustion in the bimetal thermite powders. Aging behavior of the nano-thermite mixture was also assessed by measuring the heat of combustion of the mixture before and after aging process. The reduction in heat of combustion of nanothermite mixtures containing nickel was less severe as compared to a significant decrease for the nanothermite mixture without nickel, indicating better aging resistance of the bimetal thermite powders.     

阻燃PA系列材料燃烧性能研究

通过氧指数测定、水平垂直燃烧性能测试以及差示热量扫描法分析，研究了以PA为基材的塑料的燃烧性能。结果表明，含不同阻燃剂的PA塑料的氧指数、初始分解温度、分解峰值温度等燃烧性能参数有显著不同，燃烧性能具有明显差别。