3-喹咛酮的新合成方法研究

以二乙醇胺和乙酰乙酸乙酯作为原料,经过6步反应合成了3-喹咛酮。反应步骤为：二乙醇胺磺酰化后,磺酸酯与乙酰乙酸乙酯反应形成六氢吡啶环;接着六氢吡啶衍生物脱苯磺酰基、溴化和脱羧;最后经分子内成环反应获得3-喹咛酮。     

人－航天服系统静电起电位实验研究

人体及其航天服产生的静电是航天飞船的主要静电危害源之一.在地面上和模拟舱内,对人-航天服系统静电起电电位进行了模拟实验研究,测量了航天员的正常操作过程中产生的静电电位,分析了形成静电危害的可能性.     

6β—羟基—8—甲基—8—氮杂双环［3，2，1］辛烷—3—酮的合成

6β-羟基-8-甲基-8-氮杂双环［3,2,1］辛烷-3-酮是合成托品生物碱及其类似物的重要中间体,它是通过羟基丁二醛,甲胺盐酸盐,3-酮基戊二酸在水溶液中的Robinson-Schopf缩合反应制备的。对文献报道关于它的不同合成路线进行了综述,通过实验对它的提取方式进行了改进,缩短了提取时间,提高了收率,并对合成中影响收率的因素进行了讨论。     

新型硫代双烯镍络合物合成及其对菁染料的光稳定作用

在合成中间体二(4-叔丁基苯基)羟乙酮基础上,进一步合成了双(1,2-二(4-叔丁基苯基)-1,2-二硫代双烯)镍络合物(DYE-02),利用核磁共振氢谱、红外光谱和元素分析等方法对中间体及DYE-02的结构进行了表征,并研究了DYE-02自身的光稳定性能及其对菁染料(Cy7)的光稳定作用.结果表明,与双(1,2-二苯基-1,2-二硫代双烯)镍络合物(DYE-01)相比,苯环上引入叔丁基后,DYE-02的最大近红外吸收波长在885nm,发生明显的红移,具备更好的自身光稳定性,并且能明显提高菁染料的光稳定性.     

1, 4-二氯甲基-2, 5-二甲基苯与1, 4-二氯甲基-2-甲氧基-5-辛氧基苯的共聚研究

用1,4-二氯甲基-2,5-二甲基苯和1,4-二氯甲基-2-甲氧基-5-辛氧基苯共聚合成了一种可溶的聚对苯乙炔的衍生物,对共聚物结构进行了红外光谱、核磁共振氢谱表征     

一种自适应的ISAR图像时－频分析方法

提出一种自适应的逆合成孔径雷达 (ISAR)图像的时频分析方法 ,它将时频信号分解算法—自适应高斯基表示 (AGR)方法与ISAR图像处理相结合。得益于高斯基函数方差的自适应调整 ,可自动地将图像中的理想点散射中心与非点散射结构区分开来。分别对ISAR图像的径向与横向距离轴进行上述变换 ,可解构出非点散射中心随角度或随频率变化的特性。应用该方法对仿真数据及飞机目标实测数据所成的ISAR图像进行时 -频分析 ,结果表明该方法正确可行 ,且物理意义明确     

幂零群和π－正规化子

有限群的结构与其子群的性质间的关系问题是群论的一个重要研究方向，通过群的极大子群、正规子群、半正规子群等对该群进行研究，已有一系列结果，将先用群G的p-Sylow子群P及其极大子群去研究群的结构，得到G是幂零群的一个充要条件，然后给出了π－正规化子的定义，讨论了它的一些性质，得到了π－正规化子的一些结论。     

中国第一坦克系列的发展－－59式中型坦克型号演变和变型车

59式中型坦克为基型车先后发展了59-1式,59-2式和59-2A式中型坦克以及64式、73式中型坦克抢救牵引车、64式重型履带牵引车、64式履带挖壕机等变型车。     

对羟基取代苄基胺的制备研究

研究对羟基取代苄基胺的制备 ,用羟基苯甲醛与氨水、氢气发生胺化反应 ,RaneyNi作催化剂制备对羟基苄胺和 4-羟基 - 3-甲氧基苄胺 (香草基胺 ) ,此方法最大的优点是无需高的氢压 ,反应时可以加少量低级脂肪醇作溶剂 ,反应简便、安全 ,产品的元素分析均在误差范围之内。     

面向未来的“织女星－3”升级型作战系统

70年代汤姆森-CFS公司的"织女星"(Vega)小型舰指挥和武器控制系统在世界销售取得显著的成果.该公司又开发出了Vega3升级型作战系统.该系统采用了模块化和可塑结构,具有最大的升级和扩展潜力.     

A note on circular error probabilities

An approximation for P(X² + Y² ≤ K²σ²₁) based on an unpublished result of Kleinecke is derived, where X and Y are independent normal variables having zero means and variances σ²₁ and σ²₂ and σ₁ ≥ σ₂. Also, we provide asymptotic expressions for the probabilities for large values of β = K²(1 - c²)/4c² where c = σ₂/σ₁. These are illustrated by comparing with values tabulated by Harter [6]. Solution of K for specified P and c is also considered. The main point of this note is that simple and easily calculable approximations for P and K can be developed and there is no need for numerical evaluation of integrals.     

生物降解聚酯材料L-PLA 与ε-PCL 共混行为的研究

本文用本体融熔共混法研究了聚(L-丙交酯)与聚(ε-己内酯)的共混行为。发现在存在少量催化剂钛酸丁酯Ti(OBu)_4情况下,两种均聚物于150C°明显降解。~(13)C-NMR 核磁共振精细谱图及扫描示差热分析DSC 谱图证实它们间发生酯交换。由~(13)C-NMR 与~1H-NMR 谱图计算出共聚物中L-LA 与-CL 嵌段平均链长与它们的摩尔比值。     

An approximate dynamic programing approach to the development of heuristics for the scheduling of impatient jobs in a clearing system

A single server is faced with a collection of jobs of varying duration and urgency. Each job has a random lifetime during which it is available for nonpreemptive service. Should a job's lifetime expire before its service begins then it is lost from the system unserved. The goal is to schedule the jobs for service to maximize the expected number served to completion. Two heuristics have been proposed in the literature. One (labeled π^S) operates a static priority among the job classes and works well in a “no premature job loss” limit, whereas the second (π^M) is a myopic heuristic which works well when lifetimes are short. Both can exhibit poor performance for problems at some distance from the regimes for which they were designed. We develop a robustly good heuristic by an approximative approach to the application of a policy improvement step to the asymptotically optimal heuristic π^S, in which we use a fluid model to obtain an approximation for the value function of π^S. The performance of the proposed heuristic is investigated in an extensive numerical study. © 2010 Wiley Periodicals, Inc. Naval Research Logistics 2010     

一种支持高效并发访问的移动对象索引

针对移动对象当前及未来位置索引不能有效支持多用户并发访问的问题,提出了一种支持高效并发访问的移动对象索引CS2B-tree(Concurrent Space-filling curve enabled Cache Sensitive B+-tree)。该索引结合了Bx-tree和CSB+-tree的特点,因而能够支持对移动对象进行预测查询且具有缓存敏感特性。重点研究了一种针对CS2B-tree的两层锁并发访问机制,特别是设计了一种网格锁备忘录结构,使得索引能够支持多任务并发执行。基于并发访问机制,分别提出了CS2B-tree的并发更新算法及并发预测范围查询算法。实验表明,相对于Bx-tree,CS2B-tree的并发访问的吞吐量提高了15.1%,响应时间减少了14.9%。     

Test for the extreme value and weibull distributions based on normalized spacings

Discussed in this article are tests for the extreme-value distribution, or, equivalently, for the two-parameter Weibull distribution when parameters are unknown and the sample may be censored. The three tests investigated are based on the median, the mean, and the Anderson-Darling A² statistic calculated from a set zⁱ of values derived from the spacings of the sample. The median and the mean have previously been discussed by Mann, Scheuer, and Fertig [10] and by Tiku and Singh [14]. Asymptotic distributions and points are given for the test statistics, based on recently developed theory, and power studies are conducted to compare them with each other and with two other statistics suitable for the test. Of the normalized spacings tests, A² is recommended overall; the mean also gives good power in many situations, but can be nonconsistent.     

改进AgCl浊度法测定舰船火灾烟气中氯

为快速、准确地测定出现场舰船火灾烟气中氯的含量,在体系中加入适量的十二烷基苯磺酸钠(DBS)、聚乙烯醇溶液(PVA)和吐温-80,对传统AgCl浊度法进行了改进。结果表明,系统的稳定性、灵敏度均大幅度提高,检测限则由3.5×10-1mg/l降低至3.1×10-2mg/l。改进后的方法线性范围宽、重现性好。     

On computing the expected discounted return in a markov chain

The discounted return associated with a finite state Markov chain X₁, X₂… is given by g(X₁)+ αg(X₂) + α²g(X₃) + …, where g(x) represents the immediate return from state x. Knowing the transition matrix of the chain, it is desired to compute the expected discounted return (present worth) given the initial state. This type of problem arises in inventory theory, dynamic programming, and elsewhere. Usually the solution is approximated by solving the system of linear equations characterizing the expected return. These equations can be solved by a variety of well-known methods. This paper describes yet another method, which is a slight modification of the classical iterative scheme. The method gives sequences of upper and lower bounds which converge mono-tonely to the solution. Hence, the method is relatively free of error control problems. Computational experiments were conducted which suggest that for problems with a large number of states, the method is quite efficient. The amount of computation required to obtain the solution increases much slower with an increase in the number of states, N, than with the conventional methods. In fact, computational time is more nearly proportional to N², than to N³.     

航空发动机在超声速引射系统中的应用分析

航空发动机可以对空气增压,并且增加气流温度,理论上存在应用于超声速引射系统的可能。分析了气源对引射器性能的影响以及引气对航空发动机的影响,介绍了3种航空发动机在超声速引射系统中可能的布局方案。针对某领域内的排气参数要求,分别对3种布局方案进行了计算分析。计算结果表明,当上游气体压强为0.044×10⁵ Pa和0.029 3×10⁵ Pa时,通过合理选择发动机的布局以及工作参数,发动机可以直接将上游气体排出或者作为驱动气源应用于超声速引射系统。     

Application of renewal theory to continuous sampling plans

Renewal theory is used to study the effectiveness of a class of continuous sampling plans first introduced by Dodge. This approach provides a simple way of viewing and computing the long-run Average Outgoing Quality (AOQ) and its maximum AOQL. More importantly, it is used to study the average outgoing quality in a short production run through an approximation formula AOQ^*(t). Formulas for AOQ and AOQ^*(t) are provided. By simulation, it is found that AOQ^*(t) is sufficiently accurate in situations corresponding to actual practice.     

Sojourn time analysis of a queueing system with two‐phase service and server vacations

We consider a two‐phase service queueing system with batch Poisson arrivals and server vacations denoted by M^X/G₁‐G₂/1. The first phase service is an exhaustive or a gated bulk service, and the second phase is given individually to the members of a batch. By a reduction to an M^X/G/1 vacation system and applying the level‐crossing method to a workload process with two types of vacations, we obtain the Laplace–Stieltjes transform of the sojourn time distribution in the M^X/G₁‐G₂/1 with single or multiple vacations. The decomposition expression is derived for the Laplace–Stieltjes transform of the sojourn time distribution, and the first two moments of the sojourn time are provided. © 2006 Wiley Periodicals, Inc. Naval Research Logistics, 2007