Thermal and combustion behavior of Al-MnO2 nanothermite with poly(vinylidene fluoride -co- hexafluoropropylene) energetic binder

Fluoropolymers get increasing attention in energetic materials application due to the high fluorine content. To explore the effect of poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP)) on Al/MnO2 nanothermite, the samples with different contents are prepared and characterized by SEM, TG-DSC, XRD, and their ignition and combustion behavior are tested and recorded. The results show that P(VDF-HFP) as an energetic binder can combine the nanothermite components together, even exist in the gaps. The integrity of energetic materials has been improved. Thermal analysis shows that the addition of P(VDF-HFP) greatly changes the thermal reaction processes, and the exothermic peaks appear early, but the utilization of fuel and oxidizer is not efficient from the XRD results. Furthermore, the appropriate addition of P(VDF-HFP) can directly reduce the ignition energy threshold and increase the combustion time, which is necessary for the potential ignition charge application. The possible reasons for above phenomena are discussed and analyzed. This research provides a reference for improvement of thermite-based ignition charge formulation.     

Simulation of the plasticizing behavior of composite modified double-base (CMDB) propellant in grooved calendar based on adaptive grid technology

The frequent occurrence of safety accidents during the calendering process is caused by the flammable and explosive properties of composite modified double-base (CMDB) propellant. Optimization of process parameters with the aid of fluid simulation technology could effectively ensure the safety of the calendering process. To improve the accuracy of the simulation results, material parameters and model structure were corrected based on actual conditions, and adaptive grid technology was applied in the local mesh refinement. In addition, the rheological behavior, motion trajectories and heat transfer mechanisms of CMDB propellant slurry were studied with different gaps, rotational rates and temperatures of two rollers. The results indicated that the refined mesh could significantly improve the contour clarity of boundaries and simulate the characteristics of CMDB propellant slurry reflux movement caused by the convergent flow near the outlet. Compared with the gap, the increased rotational rate of roller could promote the reflux movement and intensify the shear flow of slurry inside the flow region by viscous shear dragging. Meanwhile, under the synergistic effect of contact heat transfer as well as convective heat exchange, heat accumulated near the outlet and diffused along the reflux movement, which led to the countercurrent heat dissipation behavior of CMDB propellant slurry. The plasticizing mechanism of slurry and the safety of calendering under different conditions were explored, which provided theoretical guidance and reference data for the optimization of calendering process conditions. Based on the simulation results, the safety of the CMDB propellant calendering process could be significantly improved with a few tests conducted during a short research and development cycle.     

Formation and characterization of core-shell CL-20/TNT composite prepared by spray-drying technique

The core-shell 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane/2,4,6-Trinitrotoluene (CL-20/TNT) composite was prepared by spray-drying method in which sensitive high energy explosive (CL-20) was coated with insensitive explosive (TNT). The structure and properties of different formulations of CL-20/TNT composite and CL-20/TNT mixture were characterized by scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Laser particle size analyzer, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), differential scanning calorimetry (DSC), impact sensitivity test and detonation performance. The results of SEM, TEM, XPS and XRD show that ϵ-CL-20 particles are coated by TNT. When the ratio of CL-20/TNT is 75/25, core-shell structure is well formed, and thickness of the shell is about 20–30 nm. And the analysis of heat and impact show that with the increase of TNT content, the TNT coating on the core-shell composite material can not only catalyze the thermal decomposition of core material (CL-20), but also greatly reduce the impact sensitivity. Compared with the CL-20/TNT mixture (75/25) at the same ratio, the characteristic drop height of core-shell CL-20/TNT composite (75/25) increased by 47.6% and the TNT coating can accelerate the nuclear decomposition in the CL-20/TNT composites. Therefore, the preparation of the core-shell composites can be regarded as a unique means, by which the composites are characterized by controllable decomposition rate, high energy and excellent mechanical sensitivity and could be applied to propellants and other fields.     

反"战斧"导弹的GPS欺骗措施分析与同温层气球干扰平台的实现

针对“战斧”(DeepFire)巡航导弹武器系统弱点提出对抗和干扰欺骗措施 ,指出了GPS导航系统的弱点 ,设计了GPS干扰 /欺骗机 (GPSSpoofor)的原理模型 ,提出应用同温层气球作为GPS干扰 /欺骗机载体 ,并作了可行性分析、系统生存能力分析、系统对抗效能分析。详细介绍了同温层气球平台的地面、空中保障系统。     

装备研制技术风险流传导与耦合过程的CFD模拟

装备研制中风险间的相关性导致风险传导与耦合的产生,为深化对技术风险动态传导效应和非线性耦合机理的认识,探索研制技术风险管理与控制的有效思路或工具,在对风险传导与耦合进行定义的基础上,给出了装备研制中的风险传导模式,基于CFD技术对两种不同的耦合模式进行了数值模拟,结合仿真结果分析了风险的耦合机理,所提方法对于揭示装备研制技术风险传导与耦合规律有一定的促进作用,为下阶段求解关键风险因子间的关联关系奠定了良好基础。     

高含钛量碳化硅纤维的研制

本文采用一种聚钛硅氧烷与聚碳硅烷反应,制得了Ti/Si摩尔比为0.10的聚钛碳硅烷。该聚合物具有良好的成丝性与稳定性,经熔融纺丝,再经不熔化处理后,在氮气气氛保护下1300℃热处理后制得了高含钛量的碳化硅纤维。文中对聚钛硅氧烷的合成与结构,它与聚碳硅烷的反应过程及聚钛碳硅烷的热分解特性进行了分析与研究。     

连续碳化硅纤维的研制

本文研究了用先驱体法制备连续碳化硅(SiC)纤维的全过程。通过常压高温裂解法制得纺丝性能好的聚碳硅烷,经100孔熔融纺丝、不熔化处理和高温烧成等一系列工艺处理,制得了高性能的SiC纤维。该纤维单丝直径8～15微米,连续长度达100米,抗拉强度为2～2.3GPa,抗拉模量178GPa。主要性能达到日本同类产品八十年代的水平。本文还对制备工艺的一些基本规律及连续纤维的主要性能进行了研究。     

Evaluation of base-stock policies in multiechelon inventory systems with state-dependent demands part I: State-independent policies

This article analyzes a model of a multiechelon inventory system. The exogenous demands form Markov-modulated Poisson processes. That is, the demand rates are functions of an underlying Markov chain. Each location follows a base-stock policy which is independent of the state of the underlying Markov chain. We employ the exogenous transit mechanism introduced by Zipkin [7] and Svoronos and Zipkin [6]. The transit times between locations have phase-type distributions. An exact procedure to compute steady-state performance measures is presented. © 1992 John Wiley & Sons, Inc.     

宋时轮在雁北

全国抗日战争初期,时任八路军第120师第358旅第716团团长的宋时轮奉命挺进雁北,开展敌后抗日斗争.他坚持广泛发动群众,积极筹划建立地方各级行政组织和抗日武装,认真贯彻抗日民族统一战线方针政策,狠狠地打击日寇,壮大自己,开创了雁北地区的抗日局面,为中国人民的抗日救国事业作出了贡献.     

多普勒雷达测速信号滤波方法分析

针对四波束多普勒雷达测速信号的特点,提出了适用于光纤捷联惯导/多普勒雷达/气压高度表组合导航系统应用的多普勒雷达测速信号滤波方法.分别分析了卡尔曼滤波、经典数字滤波和小波变换滤波方法在从含有噪声和野值的多普勒雷达测速信号中提取出原始信号的特点,并对实际跑车试验中测得的多普勒雷达测速数据进行了滤波处理.结果表明:小波滤波方法在降噪以及剔除野值方面性能更好,更能适用于组合导航中对多普勒雷达测速信号的精度要求.