Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.     

Orbix的分布对象计算性能分析

通过一个计数器的分布对象设计及Orbix实现,阐明了先进的分布对象技术标准CORBA的核心概念以及符合CORBA2．0标准的中间件产品Orbix的分布对象设计和实现过程,通过计算比较并分析了Orbix在单机和网络分布环境下实现效率的差异,并提出了用单机模拟网络环境下分布对象实现效率的方法．     

血小板在凝血中作用的动力学模型

在生化实验的基础上提出了血小板在凝血中作用的动力学模型,通过定性分析和数值模拟,得到了血小板的激活比率、因子Ⅷ、Ⅸ对凝血酶生成有重要影响的一系列结论.     

电刷镀含纳米粉复合镀层结构和磨损性能

用含纳米金刚石粉的镍镀液电刷镀复合镀层,系统试验研究了复合镀层中纳米金刚石对镀层显微结构、力学性能及耐磨性能的影响.结果表明,纳米金刚石的弥散强化作用,可有效改善镀层的生长、减小内应力,提高镀层的显微硬度.含纳米金刚石粉的复合镀层在室温、高负荷下具有优良的抗疲劳和抗磨损性能,其耐磨性是纯镍镀层的4倍.     

概率化认知控制模式下人为差错概率的量化方法

在现有成果的基础上,对CREAM方法中的人为差错概率量化进行了改进.介绍了CREAM基本法量化人为差错概率的基本思想;讨论了两种概率化认知控制模式的确定方法:贝叶斯网络法和模糊逻辑法,强调了概率化认知控制模式下量化人为差错概率的必要性.通过理论推导,构建了概率化认知控制模式下人为差错概率的量化方法.另外,为了提高计算效...     

低轨预警自由段弹道估计的多项式逼近算法

低轨单星对自由段弹道的估计是天基预警系统需解决的关键技术之一.建立了低轨预警卫星对自由段弹道的观测模型,针对极大似然估计批处理算法的大运算量问题,给出了一种多项式逼近算法,由观测数据的逼近多项式在一些特定采样点的值形成伪观测数据,以伪观测数据代替原观测数据进行弹道估计.仿真表明,精度与极大似然估计相当,运算量显著降低.     

I.I.D.并行分布式检测网相同门限假定的合理性条件

并行分布式检测网最优设计是复杂难解的,相同门限假定使Ｉ．Ｉ．Ｄ．网的设计极度简化,并在实际工程中广泛使用。本文研究了相同门限假定的合理性条件,为合理采用习惯性处理方法提供了理论依据。     

机械系统FMECA应用中的几个问题

本文着重讨论了FMECA技术在机械产品可靠性工程应用中所遇到的一些问题,并进行了分析,提出了解决办法.     

CCD实现管材和线材在线测量研究

介绍了用CCD器件完成玻璃管外径和壁厚在线测量的实现方法,测试系统的结构和硬件及软件设计思想。本测试系统也适合于对其它透明或非透明管材及线材的在线测量。     

4-羟甲基-2,6,7-三氧杂二环(2.2.2)辛烷的合成

介绍了双环原酸酯个4-羟甲基-2,6,7-二氧杂二环（2．2．2）辛烷的合成方法,并提供了一条简单可行的合成途径．