双酚A环氧树脂改性二氧化双环戊二烯体系固化动力学分析及其性能研究

二氧化双环戊二烯(CDR -0122)环氧树脂固化物的耐热性较好,但脆性大.采用不同质量分数的环氧(E -51)改性CDR -0122.对不同的改性体系进行DSC分析,确定其活化能、反应级数和最佳固化工艺.对改性的CDR - 0122环氧树脂固化物进行力学性能和耐温性能测试.结果表明:当加入E-51的质量分数为30％时,CDR -0122的树脂体系的综合性能最优.相比改性前,改性后的树脂体系活化能略有下降,并且其拉伸强度和弯曲强度分别提高了52.38％和54.77％,但玻璃化转变温度略有下降.     

一种低黏度环氧树脂的制备及性能研究

采用一种新型增韧剂CC对环氧树脂进行增韧改性,获得一种低黏度中温固化环氧树脂体系。测试了树脂的力学性能,并通过红外光谱和动态热机械能分析等方法,对树脂的组织和性能进行了研究。结果表明：当CC的质量分数为19%时,环氧树脂的剪切强度和拉伸强度最大,分别为25.1 MPa和55.88 MPa;该环氧树脂具有较低的黏度;固化过程中各组分反应完全,树脂刚度较大,玻璃温度Tg达110.36℃。     

典型指控网络小世界特性仿真研究

分析了小世界网络国内外现状,诠释了指控网络仿真中需要重点考虑的因素和评价指标,并基于VRNETDeveloper对典型指控网络的组网方案和仿真主流程进行设计。通过仿真实验,验证了指控网络在传输指控信息、协同信息和态势信息时的小世界特性,为指控网络顶层设计和基于网络指挥的战术战法研究提供了基础数据和理论参考。     

Influence of magnetically constricted arc traverse speed (MCATS) on tensile properties and microstructural characteristics of welded Inconel 718 alloy sheets

The magnetically constricted arc technique was implemented to mitigate the heat input related metal-lurgical problems in Gas Tungsten Arc Welding (GTAW) of Inconel 718 alloy particularly Nb segregation and subsequent laves phase evolution in fusion zone. This paper reports the direct effect of magnetically constricted arc traverse speed (MCATS) on bead profile, tensile properties and microstructural evolution of Inconel 718 alloy sheets joined by Gas Tungsten Constricted Arc Welding (GTCAW) process. The mechanism amenable for the microstructural modification and corresponding influence on the tensile properties of joints is investigated both in qualitative and quantitative manner related to the mechanics of arc constriction and pulsing. It is correlated to the solidification conditions during welding. The relationship between MCATS and Arc Constriction Current (ACC) was derived. Its interaction effect on the magnetic arc constriction and joint performance was analysed. Results showed that the joints fabricated using CATS of 70 mm/min exhibited superior tensile properties (98.39% of base metal strength with 31.50% elongation). It is attributed to the grain refinement in fusion zone microstructure leading to the evolution of finer, discrete laves phase in interdendritic areas.     

Preservation of unimodality under shock models

A number of results pertaining to preservation of aging properties (IFR, IFRA etc.) under various shock models are available in the literature. Our aim in this paper is to examine in the same spirit, the preservation of unimodality under various shock models. For example, it is proved that in a non-homogeneous Poisson shock model if {p_k}_K≥0, the sequence of probabilities with which the device fails on the kth shock, is unimodal then under some suitable conditions on the mean value function Λ (t), the corresponding survival function is also unimodal. The other shock models under which the preservation of unimodality is considered in this paper are pure birth shock model and a more general shock model in which shocks occur according to a general counting process. © 1999 John Wiley & Sons, Inc. Naval Research Logistics 46: 952–957, 1999     

NEPE类推进剂燃烧模拟

在分析、研究硝胺和AP CMDB推进剂燃烧模型的基础上,结合NEPE类推进剂的配方和燃烧性能特点,建立了NEPE类推进剂燃烧的物理模型,并进行了燃速和压强指数的理论计算。结果表明,几乎100%的计算结果都在实验值的±10%范围内。这说明所建立的模型基本合理,编制的NEPE类推进剂燃速计算程序基本可行。     

一步法制备石蜡微胶囊的中试研究及性能表征

采用一步法在100L反应釜内进行石蜡微胶囊制备的中试，表征了石蜡微胶囊的微胶囊化率、粒径和热性能，探讨了中试工艺对产品性能的影响。结果表明中试产品与实验室小试产品的性能基本接近。中试石蜡微胶囊的微胶囊化率为70％，平均粒径为54．0μm，相变范围为40～80℃，相变峰值和热焓分别为65℃，114J／g，分解温度达250℃。     

水动力空化效应的实验研究与理论分析

在研制空化射流实验装置的基础上，采用实验与理论分析相结合的方式，以苯酚溶液为对象，对水动力空化效应进行了研究。考察了进口压力、孔板结构与空化数的关系，研究了反应时间、进口压力和空化数对苯酚降解效果的影响。得出孔板在水动力空化过程中起决定性作用，一定结构的孔板还能有效抑制超空化现象的发生，确保较好的苯酚降解效果。     

酚醛-石英混杂纤维增强苯并噁嗪复合材料高温失效特征

通过模压工艺制备了酚醛-石英混织纤维增强苯并噁嗪复合材料(P-Q/BZ)试样,考察了其力学性能、烧蚀性能和耐冲刷性能,分析了该试样在高温环境中的主要失效特征,研究其在高温环境中的适用性。结果表明,未经热处理的P-Q/BZ试样平均弯曲强度、弯曲模量和层间剪切强度分别为283 MPa、10.8 GPa和22.6 MPa;经300℃,N_2处理15 min后,试样均匀膨胀,厚度增加22%,弯曲强度、弯曲模量和层间剪切强度分别下降58%、41%和58%;在氧乙炔焰的平均质量烧蚀率和线烧蚀率分别为0.048 4 g/s和-0.081 mm/s,烧蚀后试样宏观不分层,表面炭层微观分层严重,酚醛纤维热解炭、树脂基体热解炭、熔融石英纤维以及碳硅氧化产物相互分离;该试样耐冲刷能力差,在发动机尾焰烧蚀平台模拟的热-力耦合环境中的质量损失率高达59%。P-Q/BZ复合材料需要解决热解膨胀问题,进一步提高抗冲刷性能。     

工作电压对喷射电沉积Ni镀层形貌及性能的影响

采用喷射电沉积技术制备了Ni镀层。研究了工作电压对电流特性、镀层表面形貌、显微硬度和摩擦学性能的影响。结果表明：随着工作电压的升高,平均电流密度逐渐增大,镀层的显微硬度和耐磨性逐渐增强,镀层表面的平整度和减摩效果下降。