定应变作用下NEPE推进剂老化特性及寿命预估研究

为考察定应变作用下NEPE推进剂的老化特性,研究了20%定应变作用下NEPE推进剂贮存老化过程中力学性能、凝胶性能和界面性能的变化.研究结果表明:定应变作用下NEPE推进剂在贮存老化过程中最大抗拉强度降低,最大延伸率变化较小,其老化失效主要表现为强度的失效;定应变下NEPE推进剂的凝胶百分数和粘附功随老化时间的延长而降低,NEPE推进剂粘合剂基体的降解断裂和界面的"脱湿"是其主要的老化机理;定应变下NEPE推进剂的力学性能与细观性能的相关性研究表明,最大抗拉强度与凝胶百分数和粘附功存在相关关系,计算了其关系式,建立了由细观性能评估推进剂宏观力学性能的方法;选择最大抗拉强度下降30%时失效,20%定应变下NEPE推进剂的贮存寿命为8.3年.     

添加SiC微粉对硅树脂先驱体转化3D Cf/Si-O-C材料性能的影响

以三维碳纤维织物和廉价的硅树脂为原料,采用先驱体转化工艺制备3D G/Si-O-C材料,考察了浸渍液中添加SiC填料对材料微观结构、力学性能和抗氧化性能影响.结果表明:添加适量的SiC填料有助于减少基体孔隙,改善界面结合,从而提高材料的力学性能;而SiC含量过高时,容易在材料内部形成闭孔,从而导致材料力学性能下降.当SiC微粉含量为18.2%时,材料具有最好的力学性能,弯曲强度和断裂韧度分别为421.3MPa和13.0 MPa·m1/2;而材料的抗氧化性能随着SiC微粉含量的增加而增加,当SiC微粉含量为25.0%时,材料的弯曲强度保留率最高,达到了89.5%.     

Multifunctional A356 alloy/ PKSAnp composites: Microstructure and mechanical properties

Mechanical properties and microstructure of multifunctional composites produced with palm kernel shell ash nanoparticle (PKSAnp)-A356 alloy composites was studied. The composites were produced using Double layer feeding stir casting method (DLF-SCM) by adding 1 wt%‒4 wt.% PKSAnp. The microstructure, density, electrical and mechanical properties were determined. The results shows that there was a uniform distribution of the PKSAnp in A356 alloy. The mismatch at the interface between the PKSAnp and A356 alloy was 4.26%. Improvement of 30.47%, 41.91%, 49.52%, 40.90% and 65.09% were obtained for hardness values, tensile, yield strength, %elongation and impact energy at 4 wt% PKASnp. The work has established that the developed composites can be used for multifunctional applications where combination of toughness and strength is vital.     

室内装饰织物燃烧特性研究

室内装饰织物因其容易点燃、燃烧速度快、蔓延迅速等燃烧特性,对室内火灾的发展蔓延及火灾危害都有重要影响。运用锥形量热仪对棉麻、涤纶、帆布、泡纱、条绒等5种室内装饰织物的燃烧性能进行了实验研究,测量了室内装饰织物在不同热辐射条件下的燃烧特性,并对实验数据进行图像拟合,通过具体的实验数据和图像分析比较了5种室内装饰织物在不同热辐射条件下的点燃时间、热释放速率、质量损失速率、比消光面积及CO生成量。最后得出了各种织物的火灾危险性相对大小。     

Synergistic effect of hybrid Himalayan Nettle/Bauhinia-vahlii fibers on physico-mechanical and sliding wear properties of epoxy composites

The cellulosic bast fibers are recognized as a justifiable and biodegradable substitute for producing moderate strength polymer composite materials because of their characteristics of renewability, eco-friendliness, and higher specific strength. Hence the aim of this research work is to fabricate Himalayan bast fibers (Nettle fiber (NF)/bauhinia vahlii fiber (BF)) based mono/hybrid epoxy composites at varying weight percentage of 2–6 wt% and evaluate the physical (void fraction and water absorption), mechanical (tensile strength, flexural strength, hardness) and sliding wear properties of as-fabricated composites. The 6 wt% NBF reinforced composites exhibited higher mechanical properties as compared to NF and BF composites with tensile strength of 34.04 MPa, flexural strength of 42.45 MPa, and hardness of 37.01 H_v respectively. The influence of various control factors (sliding velocity, NF/BF/NBF contents, normal load and sliding distance) on specific sliding wear rate of composites was evaluated by Taguchi (three factors at three levels) experimental design and the percentage contribution of these selected parameters on sliding wear performance was examined by Analysis of variance (ANOVA). The sliding wear property of as-developed composites was found to be greatly influenced by sliding velocity and the wear resistance was observed to be improved with the NF/BF/NBF contents. The wear mechanism of the as-fabricated composites has been elucidated by scanning electron microscopy analysis. The research outcomes demonstrated that the hybridization of Bauhinia vahlii fiber with Nettle fiber led to improve the mechanical and wear properties of epoxy composites.     

Liquid phase in-situ synthesis of LiF coated boron powder composite and performance study

Among practical metal additives, boron (B) has a high volumetric heating value, making it a promising choice as a fuel additive. Although B can theoretically yield a large amount of energy upon complete combustion, its combustion is retarded by the initial presence of B oxide, which coats the surfaces of B particle. To improve the ignition and combustion properties of B powder, LiOH and NH₄F were used as precursors to synthesize uniformly LiF-coated B composites (LiF-B) in situ. The LiF-B mixture was also prepared for comparison using a physical method. X-ray diffraction (XRD), Fourier-transform infrared (FTIR), scanning electron microscope (SEM), and energy-dispersive X-ray spectroscopy (EDS) were used to characterize the morphologies and compositions of the products. The thermal and combustion properties of the samples were characterized by thermal gravity-differential thermal gravity (TG-DTG), differential scanning calorimetry (DSC) and closed bomb experiment. The XRD, FTIR, SEM and EDS results demonstrated the successful preparation of the coated LiF-B sample. The TG-DTG and closed bomb experiment results indicated that the addition of LiF decreased the ignition temperature of B powder, and increasing its reaction efficiency. DSC results show that when LiF-B was added, the released heat of underwater explosive increased by 6727.2, 7280.4 and 3109.6 J/g at heating rates of 5, 10, and 15 °C/min, respectively. Moreover, LiF-B decreased the activation energy of secondary combustion reaction of explosive system as calculated through Kissinger's method by 28.9%, which indicated an excellent catalytic effect for the thermal decomposition of underwater explosive. The results reveal that LiF can improve the combustion efficiency of B powder, thereby increasing the total energy of explosives. The mechanical sensitivity increased slightly after adding LiF-B to the underwater explosive. Compared to the underwater explosive with added B, the mechanical sensitivity of the explosive with added LiF-B was significantly lower.     

电缆热老化寿命预测

利用热分析技术，对电缆绝缘材料的热老化寿命进行了研究，得到了电缆绝缘材料热老化寿命的计算公式。在不同载流量下，对电缆绝缘材料热老化寿命进行了比较，给出了电缆热老化寿命与载流量的函数关系，为电流致热型线缆火灾的防治提供了基础数据。     

复合材料修补金属裂损结构吸湿老化的试验与有限元分析

暴露在湿热环境中的复合材料修补金属裂损结构易吸湿老化,导致该结构性能下降,服役寿命缩短。为研究吸湿性对复合材料修补金属裂损结构修补效果和耐久性的影响,利用试验方法分析了吸湿性对复合材料胶补金属裂损结构及胶黏剂力学性能的影响;利用有限元方法评估了吸湿性对复合材料胶补金属裂损结构试验件修补效果和耐久性的影响。研究结果表明:吸湿后含穿透双边裂纹铝合金板玻璃纤维单面胶补试验件的疲劳裂纹扩展寿命和极限载荷的平均值分别下降为吸湿前的71%和90%;吸湿造成拉伸条件下复合材料胶补金属裂损结构胶层失效模式由内聚破坏为主转变为界面破坏为主;在"湿-热"老化30天后,E44/聚酰胺环氧树脂胶黏剂试验件吸水饱和,弹性模量下降为未老化前的40%,塑性应变超过了总应变的25%;有限元分析发现胶层损伤受吸湿影响明显,吸湿性加速了胶层损伤,且裂纹长度越长,加速作用越明显;同时吸湿使得裂纹尖端的J积分值急剧增大,导致修补结构的疲劳裂纹扩展寿命缩短,裂纹长度越长,吸湿性对于复合材料胶接修补效果的危害越严重。     

Ni-Co-P／导电聚苯胺复合材料电磁和红外性能

采用化学镀对高氯酸掺杂聚苯胺（PANI/HClO4）粉体进行Ni-Co-P合金化改性,改性材料磁损耗因子得到提高。进行红外光谱分析,PANI/HClO4在3-5μm和8-14μm 2个大气窗口没有强吸收峰,具有雷达红外隐身兼容特性。     

材料力学性能纳米压入测试仪器发展综述

综述了材料力学性能纳米压入测试仪器的发展现状。阐述了纳米压入测试技术的发展历程;从驱动、载荷测量和位移测量3方面对目前材料力学性能纳米压入测试仪器的基本结构进行了比较分析;介绍了材料力学性能纳米压入测试仪器集成技术,包括影响压入深度测量精度的集成技术、观测技术、大载荷模块和高温试验模块等;最后,对未来材料力学性能纳米压力测试仪器的发展趋势作了展望。