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61.
《防务技术》2014,10(4):384-392
Computations by density functional theory (DFT) method are performed on a series of di-1H-1,3,4-triazole derivatives with different substituents and linkages. The heat of formation (HOF) is predicted by the designed isodesmic reactions. The predicted results reveal that –N3 and –NN– groups are effective structural units for increasing the HOF values of the di-1H-1,3,4-triazole derivatives. The HOMO–LUMO gap is affected by the substituents and linkage groups. Detonation performance is evaluated using the Kamlet–Jacobs approach based on the calculated density and HOF. The results indicate that –NO2, –NF2, –NH–, –NH–NH– and –NN– groups are helpful for enhancing the detonation properties of di-1H-1,3,4-triazole derivatives. The bond dissociation energy and bond order of the weakest bonds are analyzed to investigate their stability. It is observed that the –CH2–, –CH2–CH2– and –CHCH– groups are effective structural units for improving the stabilities of these derivatives. Considering the detonation performance and the stability, five compounds are screened as the potential candidates for high energy density materials. 相似文献
62.
《防务技术》2014,10(4):343-348
2,6-diamino-3,5-dinitropyrazine-1-oxide (ANPZO), as an insensitive high explosive, with a high yield and excellent purity has been prepared at pilot plant scale by an improved method. The synthesized ANPZO is characterized by IR, laser granularity measurement, SEM and HPLC. The particle analysis revealed that the improved method could offer desired product with average particle size of 40 μm and high purity (>98.45%). The experimental parameters exhibited that the detonation velocity of the formulation based on ANPZO was higher than that of the corresponding TATB formulation. The DSC curve showed that the exothermic decomposition of the product occurred at the temperature between 300.5 °C and 360.4 °C. Furthermore, the sensitivity test suggests its safe nature towards mechanical stimulus. 相似文献
63.
《防务技术》2014,10(2):211-218
It has been said that, once a bomb casing has fractured, “detonation gases will then stream around the fragments or bypass them, and the acceleration process stops there.” However, while apparently copious gas flow through casing fractures indicates some pressure release, it is also an indication of significant gas drive pressure, post casing fracture. This paper shows two approaches to the problem of calculating the actual loss of drive. One presents first-order analytical calculations, in cylindrical geometry, of pressure loss to the inside surface of a fractured casing. The second shows the modelling of a selected example in the CTH code. Both approaches reveal that gas escape, while occurring at its own sound-speed relative to the adjacent casing fragments, has to compete with rapid radial expansion of the casing. Together with some historic experiments now publicly available, our calculations indicate that post-fracture casing fragment acceleration is, for most systems, unlikely to be reduced significantly. 相似文献
64.
《防务技术》2014,10(3):285-293
According to the dimensionless formulae of DOP (depth of penetration) of a rigid projectile into different targets, the resistive force which a target exerts on the projectile during the penetration of rigid projectile is theoretically analyzed. In particular, the threshold Vc of impact velocity applicable for the assumption of constant resistive force is formulated through impulse analysis. The various values of Vc corresponding to different pairs of projectile-target are calculated, and the consistency of the relative test data and numerical results is observed. 相似文献
65.
为有效解决传统载荷设计方法中存在的诸多不足,提出一种适用于一类飞行器载荷设计的三分段法,即分段刚度、分段质量和分段气动。该方法能够很好地逼近飞行器的真实质量分布和气动载荷分布。针对简化飞行器,分别利用三分段法、理论计算法和质量分站法计算其模态参数和截面载荷。结果表明,三分段法和理论计算法在模型参数、计算原理上是一致的,基本可以认为是一种方法,因而它们的模态参数和截面载荷完全吻合;质量分站法所得左、右截面载荷不一致,且相差很大,还不符合真实载荷情况。总之,采用三分段法能够得到较为真实、合理的飞行器截面载荷分布,且工程应用简便,方法合理、可信,同时还可以在很大程度上降低飞行器载荷设计和结构设计的难度。 相似文献
66.
针对再入机动弹头垂直打击目标的要求,研究了具有末端落角约束的复合导引律.该导引律包括俯冲平面内的制导方程和转弯平面内的制导方程,通过在最优导引律的基础上引入滑模变结构控制,增强导引律的鲁棒性.为了减小控制量的抖振和能量损耗,提出了采用RBF(径向基函数)神经网络自适应调节切换项增益的方案,数学仿真验证了该方案的有效性.仿真结果还表明,与最优导引律相比,复合导引律在外界干扰的影响下仍能保持较高的制导精度. 相似文献
67.
建立了对接过程对组合体初始姿态影响的解析与数值模型。解析模型采用相对于整体质心的动量矩定理,给出了对接完成后组合体姿态角速度计算的解析表达式。结合追踪器的绝对运动方程和目标器的相对运动方程,建立了基于对接动力学的数值模型。通过单一偏差和组合偏差两种算例,对解析和数值模型得到的组合体初始姿态角速度进行了对比分析。计算结果表明,两种模型绝对偏差在0.07°/s以内,相对偏差在10%以内,另外给出了两种模型在工程任务中各自的适用阶段。 相似文献
68.
69.
提出了一种测速定轨的实时算法。该方法基于样条表示飞行轨道速度参数 ,在只有多个测速元信息的情况下 ,建立了自适应Kalman滤波递推算法 ,实时给出了较高精度的飞行器轨道参数 相似文献
70.
本文深入研究了基于YH-F2系统的算术表达式的并行计算特点,提出了嵌套层次树的概念和相应的计算模式。这种模式充分利用了YH-F2系统的并行计算能力,完满地解决了基于YH-F2的算术表达式的并行编译问题 相似文献