Effect of bending temperatures on the microstructure and springback of a TRIP steel sheet

Transformation-induced plasticity (TRIP) steel possesses high strength and formability, enabling the use of a thinner gauge material and allowing for the fabrication of complex shapes. In this research, we measured the effect of bending temperatures on the microstructure and air-bending springback angle of TRIP steel at temperatures from 25 to 600 °C. Real-time in situ X-ray diffraction and scanning electron microscopy were used for pre- and postbending analysis. As the prebending temperature increased from 25 °C to 600 °C, the retained austenite (RA) volume fraction decreased, and the RA transformed to bainite at temperatures above 400 °C. The springback angle was positively correlated with the prebending RA volume fraction, with the smallest springback angle achieved at 400 °C. Additionally, the springback angle was positively correlated with the bending angle, because the RA transformation ratio contributed to increased strain hardening. Further microstructure analysis revealed that the RA became elongated in the tension direction as the bending temperatures increased.     

Neural network modeling to evaluate the dynamic flow stress of high strength armor steels under high strain rate compression

An artificial neural network (ANN) constitutive model is developed for high strength armor steel tempered at 500 °C, 600 °C and 650 °C based on high strain rate data generated from split Hopkinson pressure bar (SHPB) experiments. A new neural network configuration consisting of both training and validation is effectively employed to predict flow stress. Tempering temperature, strain rate and strain are considered as inputs, whereas flow stress is taken as output of the neural network. A comparative study on Johnson–Cook (J–C) model and neural network model is performed. It was observed that the developed neural network model could predict flow stress under various strain rates and tempering temperatures. The experimental stress–strain data obtained from high strain rate compression tests using SHPB, over a range of tempering temperatures (500–650 °C), strains (0.05–0.2) and strain rates (1000–5500/s) are employed to formulate J–C model to predict the high strain rate deformation behavior of high strength armor steels. The J-C model and the back-propagation ANN model were developed to predict the high strain rate deformation behavior of high strength armor steel and their predictability is evaluated in terms of correlation coefficient (R) and average absolute relative error (AARE). R and AARE for the J–C model are found to be 0.7461 and 27.624%, respectively, while R and AARE for the ANN model are 0.9995 and 2.58%, respectively. It was observed that the predictions by ANN model are in consistence with the experimental data for all tempering temperatures.     

Thermal decomposition of ammonium perchlorate catalyzed with CuO nanoparticles

Ammonium perchlorate (APC) is the most common oxidizer in use for solid rocket propulsion systems. However its initial thermal decomposition is an endothermic process that requires 102.5 J·g⁻¹. This manner involves high activation energy and could render high burning rate regime. This study reports on the sustainable fabrication of CuO nanoparticles as a novel catalyzing agent for APC oxidizer. Colloidal CuO nanoparticles with consistent product quality were fabricated by using hydrothermal processing. TEM micrographs demonstrated mono-dispersed particles of 15 nm particle size. XRD diffractogram demonstrated highly crystalline material. The synthesized colloidal CuO particles were effectively coated with APC particles via co-precipitation by using fast-crash solvent–antisolvent technique. The impact of copper oxide particles on APC thermal behavior has been investigated using DSC and TGA techniques. APC demonstrated an initial endothermic decomposition stage at 242 °C with subsequent two exothermic decomposition stages at 297.8 °C and 452.8 °C respectively. At 1 wt%, copper oxide offered decrease in initial endothermic decomposition stage by 30%. The main outcome of this study is that the two main exothermic decomposition peaks were merged into one single peak with an increase in total heat release by 53%. These novel features can inherit copper oxide particles unique catalyzing ability for advanced highly energetic systems.     

Tuning the reactivity of Al–Ni by fine coating of halogen-containing energetic composites

In this paper, various core-shell structured Al–Ni@ECs composites have been prepared by a spray-drying technique. The involved ECs refer to the energetic composites (ECs) of ammonium perchlorate/nitrocellulose (AP/NC, NA) and polyvinylidene fluoride/hexanitrohexaazaisowurtzitane (PVDF/CL-20, PC). Two Al–Ni mixtures were prepared at atomic ratios of 1:1 and 1:3 and named as Al/Ni and Al/3Ni, respectively. The thermal reactivity and combustion behaviors of Al–Ni@ECs composites have been comprehensively investigated. Results showed that the reactivity and combustion performance of Al–Ni could be enhanced by introducing both NA and PC energetic composites. Among which the Al/Ni@NA composite exhibited higher reactivity and improved combustion performance. The measured flame propagation rate (v = 20.6 mm/s), average combustion wave temperature (T_max = 1567.0 °C) and maximum temperature rise rate (γ_t = 1633.6 °C/s) of Al/Ni@NA are higher than that of the Al/Ni (v = 15.8 mm/s, T_max = 858.0 °C, and γ_t = 143.5 °C/s). The enhancement in combustion properties could be due to presence of the acidic gaseous products from ECs, which could etch the Al₂O₃ shell on the surface of Al particles, and make the inner active Al to be easier transported, so that an intimate and faster intermetallic reaction between Al and Ni would be realized. Furthermore, the morphologies and chemical compositions of the condensed combustion products (CCPs) of Al–Ni@ECs composites were found to be different depending on the types of ECs. The compositions of CCPs are dominated with the Al–Ni intermetallics, combining with a trace amount of Al₅O₆N and Al₂O₃.     

The properties of Sn–Zn–Al–La fusible alloy for mitigation devices of solid propellant rocket motors

The Al and La elements are added to the Sn9Zn alloy to obtain the fusible alloy for the mitigation devices of solid propellant rocket motors. Differential scanning calorimetry (DSC), metallographic analysis, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), tensile testing and fracture analysis were used to study the effect of Al and La elements on the microstructure, melting characteristics, and mechanical properties of the Sn9Zn alloy. Whether the fusible diaphragm can effectively relieve pressure was investigated by the hydrostatic pressure at high-temperature test. Experimental results show that the melting point of the Sn9Zn-0.8Al0·2La and Sn9Zn–3Al0·2La fusible alloys can meet the predetermined working temperature of ventilation. The mechanical properties of those are more than 35% higher than that of the Sn9Zn alloy at −50 °C–70 °C, and the mechanical strength is reduced by 80% at 175 °C. It is proven by the hydrostatic pressure at high-temperature test that the fusible diaphragm can relieve pressure effectively and can be used for the design of the mitigation devices of solid propellant rocket motors.     

Effect of Drying on Particle Size and Sensitivities of Nano hexahydro-1,3,5-trinitro-1,3,5-triazine

Nano hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) was prepared using a bi-directional rotation mill and dried under different conditions (liquid, temperature and drying). It shows that the samples cake seriously and the particles grow up obviously by ordinary drying in different liquids at 70 °C, which occurs again after vacuum drying. With the increase of temperature, the degrees of caking and aggregation are enhanced. Well dispersed sample maintaining constant particle size is extracted by supercritical drying, especially freeze drying. Furthermore, the mechanical sensitivities of I-RDX, O-RDX and F-RDX, of which the average sizes are 88.03 μm, 15.32 μm and 0.16 μm, respectively, are evaluated. Compared with I-RDX, the friction, impact and shock sensitivities of O-RDX are slightly lower. However, the friction, impact and shock sensitivities of F-RDX are reduced by 30%, 99.0% and 59.9%, respectively.     

Experimental investigation of a cook-off temperature in a hot barrel

The experimental investigations of the effect of contact time/temperature on initiating the cook-off using 7.62 mm calibre cartridge cases (CC) were conducted previously. These cartridges were filled with commercial off-the-shelf (COTS) double based (DB) propellant (Bulls Eye) and were loaded in a hot chamber. The thermal explosion temperature is of great significance to both weapon designers and safety inspectors as it provides the operational limit and safe operating temperature. For CC under test, it was found that the cook-off temperatures of this propellant were encountered with the heat transfer profile of the simulated gun barrel between 151.4 °C and 153.4 °C, with a reaction occurring in less than 300 s after the round was chambered. Usefully, each experiment was found to be consistent and repeatable.     

Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.     

Novel aluminum-based fuel: Facile preparation to improve thermal reactions

To improve the thermal properties of aluminum (Al) in the energetic system, a coated structure with ammonium perchlorate (AP) was prepared by a facile approach. And N, N-Dimethylformamide (DMF) was chosen as an ideal solvent based on heterogeneous nucleation theory and molecular dynamics simulation. This coated structure could enlarge the contact area and improve the reaction environment to enhance the thermal properties. The addition of AP could accelerate oxidation temperature of Al with around 17.5 °C. And the heat release of 85@15 composition rises to 26.13 kJ/g and the reaction degree is 97.6% with higher peak pressure (254.6 kPa) and rise rate (1.397 MPa/s). An ideal ratio with 15 wt% AP was probed primarily. The high energy laser-induced shockwave experiment was utilized to simulate the reaction behavior in hot field. And the larger activated mixture of coated powder could release more energy to promote the growth of shockwave with higher speed up to 518.7 ± 55.9 m/s. In conclusion, 85@15 composition is expected to be applied in energetic system as a novel metal fuel.     

Cell-type continuous electromagnetic radiation system generating millimeter waves for active denial system applications

The cell-type continuous electromagnetic radiation system is a demonstration device capable of generating high-power millimeter electromagnetic waves of a specific wavelength and observing their effects on living organisms. It irradiates a biological sample placed in a 30 × 30 × 50 cm³ cell with electromagnetic waves in the 3.15-mm-wavelength region (with an output of ≥1 W) and analyzes the temperature change of the sample. A vacuum electronic device-based coupled-cavity backward-wave oscillator converts the electron energy of the electron beam into radiofrequency (RF) energy and radiates it to the target through an antenna, increasing the temperature through the absorption of RF energy in the skin. The system causes pain and ultimately reduces combat power. A cell-type continuous electromagnetic radiation system consisting of four parts—an electromagnetic-wave generator, a high-voltage power supply, a test cell, and a system controller—generates an RF signal of ≥1 W in a continuous waveform at a 95-GHz center frequency, as well as a chemical solution with a dielectric constant similar to that of the skin of a living organism. An increase of 5 °C lasting approximately 10 s was confirmed through an experiment.     

Aerodynamics analysis of a hypersonic electromagnetic gun launched projectile

A hypersonic aerodynamics analysis of an electromagnetic gun (EM gun) launched projectile configuration is undertaken in order to ameliorate the basic aerodynamic characteristics in comparison with the regular projectile layout. Static margin and pendulum motion analysis models have been applied to evaluate the flight stability of a new airframe configuration. With a steady state computational fluid dynamics (CFD) simulation, the basic density, pressure and velocity contours of the EM gun projectile flow field at Mach number 5.0, 6.0 and 7.0 (angle of attack = 0°) have been analyzed. Furthermore, the static margin values are enhanced dramatically for the EM gun projectile with configuration optimization. Drag, lift and pitch property variations are all illustrated with the changes of Mach number and angle of attack. A particle ballistic calculation was completed for the pendulum analysis. The results show that the configuration optimized projectile, launched from the EM gun at Mach number 5.0 to 7.0, acts in a much more stable way than the projectiles with regular aerodynamic layout.     

Kevlar fabric reinforced polybenzoxazine composites filled with silane treated microcrystalline cellulose in the interlayers: The next generation of multi-layered armor panels

The design of astonishing combinations of benzoxazine resins with various fillers is nowadays of great interest for high quality products, especially in ballistic armors. The objective of this study is to investigate a new hybrid material prepared as multi-layered composite plate by hand lay-up technique. Different composites were manufactured from Kevlar fabrics reinforced polybenzoxazine, which was filled with silane treated microcrystalline cellulose (MCC Si) at various amounts in the interlayers. The developed materials were tested for their flexural, dynamic mechanical and ballistic performance. The aim was to highlight the effect of adding different amounts of MCC Si on the behavior of the different plates. Compared to the baseline, the dynamic mechanical and bending tests revealed an obvious decrease of the glass transition of 21 °C and a notable increase in storage modulus and flexural strength of about 180 %and17%, respectively, upon adding 1% MMC Si as filler. Similarly, the ballistic test exhibited an enhancement in kinetic energy absorption for which the composite supplemented with 1% MCC Si had the maximal energy absorption of 166.60 J. These results indicated that the developed panels, with interesting mechanical and ballistic features, are suitable to be employed as raw materials to produce body armor.     

The non-isothermal gravimetric method for study the thermal decomposition kinetic of HNBB and HNS explosives

The hexanitrostilben (HNS) is a thermally stable explosive that can be prepared from hexanitrobibenzyl (HNBB). Therefore, the investigation of thermal stability of HNBB can be important in the yield of preparation of HNS. The decomposition kinetic of HNBB and HNS are studied by non-isothermal gravimetric method. The TG/DTG curves in non-isothermal method are obtained in range of 25°C–400 °C at heating rates of 3 °C/min, 5 °C/min, 8 °C/min, 10 °C/min and 12 °C/min. The data of weight-temperature are used for calculation of activation energy (E_a) of thermal decomposition reactions by methods of Ozawa, Kissinger, Ozawa-Flynn-Wall (OFW) and Kissinger-Akahira-Sunose (KAS) as model-free methods and Strink's equation as model-fitting method. The compensation effect is used for prediction of mechanism and determination of pre-exponential factor (lnA) of the decomposition reaction. A reduction 60 kj/mol for the average of activation energy of thermal decomposition reaction of HNBB is obtained versus HNS. This result shows the lower thermal stability of HNBB in comparison to HNS. The Avrami equation (A_3/2) with function f(α) = 3/2(1-α)[-ln(1-α)]^1/3 indicates the predicted mechanism for thermal decomposition reaction both explosives.     

Low velocity impact studies of E-glass/epoxy composite laminates at different thicknesses and temperatures

Low velocity impact experiments were carried out on E-glass/epoxy composite laminates having varying thicknesses at sub zero and elevated temperatures using hemi spherical steel impactor of 16 mm diameter with impact energies in the rage of 50–150 J. The performance of the laminates was assessed in terms of energy absorption, maximum displacement, peak force and failure behaviour. Results indicated that the effect of temperature on energy absorption of the laminate is negligible although the laminates are embrittling at sub zero temperatures. However it has influence on failure behaviour and displacement. Peak force has increased linearly with increase in laminate thickness from 5 to 10 mm. However it got reduced by 25% when temperature was increased from −20 °C to 100 °C. Based on experimental results, laminate perforation energies were predicted using curve fitting equations. Statistical analysis was carried out using Taguchi method to identify the global effects of various parameters on laminate performance and confirmed that the laminate thickness has significant influence as compared to temperature, for the studied range.     

Investigation of normal,lateral, and oblique impact of microscale projectiles into unidirectional glass/epoxy composites

Spacesuits and spacecraft must endure high velocity impacts from micrometeoroids. This work considers the impact of 100 μm diameter projectiles into composite targets at velocities from 0.5 km/s to 2 km/s. This work begins by presenting an energy-based theoretical model relating depth of penetration (DoP) and impact force to impact velocity, characteristic time, and threshold velocity and force. Next, this work compares numerical simulations of normal impact on composites to the theoretical model. Numerical simulations are conducted with LS-DYNA and the well-known composite model, MAT-162. The numerical models consider unidirectional S2-glass fiber reinforced SC-15 epoxy composite laminates. The numerical model shows good correlation with the theoretical model. The numerical model also investigates lateral impact, parallel to the fiber direction, and oblique impact at angles from 30° to 82.5°. This work decomposes oblique impact into normal and lateral components, and compares them with normal and lateral impact results. The results show good correlation of the normal component of oblique results with the theoretical model. This numerical and theoretical study focuses on DoP, velocity, and penetration resistance force as functions of time. The theoretical model and numerical simulations are used to determine new DoP parameters: characteristic time of depth of penetration and threshold impact velocity. These models are a first step in developing the capability to predict DoP for oblique, microscale, high-speed impact on composite materials.     

Burning characteristics of high density foamed GAP/CL-20 propellants

The monolithic foamed propellants with high densities were prepared by casting and two-step foaming processes. Glycidyl azide polymer (GAP) and isocyanate were used as the binder system and 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW, CL-20) was employed as the energetic component. The newly designed formulation containing 60 % CL-20 produced a force constant of 1077 J/g and low flame temperature of 2817 K. Two foamed propellants with densities of 1.32 g/cm³ and 1.53 g/cm³ were fabricated by a confined foaming process and examined by closed bomb tests. The results revealed that porosity significantly affects burning performance. A size effect on combustion behaviors was observed for the foamed propellant with 5.56 % porosity, and a double-hump progressive dynamic vivacity curve was obtained. At last, the 30 mm gun test was carried out to demonstrate the interior ballistic performance, and the muzzle velocity increased by 120 m/s at the same maximum chamber pressure when monolithic propellant was added in the charge.     

Crashworthiness performance of hybrid kenaf/glass fiber reinforced epoxy tube on winding orientation effect under quasi-static compression load

This research was aimed to study the effect winding orientation on the crashworthiness performance of hybrid tube. The specimens tested under quasi-static compression load involve of three winding parameters (θ = 30°, 45° and 70°) of hybrid kenaf/glass fiber reinforced epoxy and glass fiber reinforced epoxy as contrast specimen. The automated filament winding technique has been used in fabrication of hybrid and non-hybrid composite tube and crashworthiness performance was investigated experimentally. The effects of winding orientation on energy absorption capabilities and crashworthiness characteristic were investigated through quasi-static compression load and the result are compared with the glass fiber composite tube to justify the capability of hybrid natural/synthetic as energy absorption application. Hybridized samples proved to enhancing the progressive crushing capability as combination of local buckling, delaminate and brittle fracturing as progressive crushing modes.In the view of winding orientation aspect, the results of high winding orientation of hybrid composite tube elevated the crush load efficiency, specific energy absorption and energy absorption capability compared to glass composite tube (GFRP). The hybrid kenaf/glass composite tube with high winding orientation showed the best winding orientation to enhance the energy absorber characteristics as energy absorption application.     

北斗GEO卫星用户算法的改进方法研究*

针对北斗GEO用户算法需要进行5?倾角的坐标旋转处理这一过程,本文提出了采用经典广播星历参数用户算法直接解算北斗GEO卫星位置的改进方法,并同时给出了相应的基于第二类无奇点根数的广播星历拟合算法。该算法采用第二类无奇点轨道根数代替经典轨道根数,解决了由GEO轨道的小倾角特性引起的经典广播星历参数拟合过程中法化矩阵奇异的问题。从而避免了北斗GEO用户算法中坐标旋转处理过程,减少了GEO用户算法的计算步骤。经过仿真验证,本文提出的改进方法在卫星轨道拟合过程中与原算法精度相当;在卫星轨道外推过程中与原算法相比略有精度损失,但仍满足用户导航定位精度的需求。最后,采用实际北斗GEO星历解算的轨道数据验证了改进算法的有效性。     

Dynamic modeling and parameter identification of a gun saddle ring

In this study, a theoretical nonlinear dynamic model was established for a saddle ring based on a dynamic force analysis of the launching process and the structure according to contact-impact theory. The ADAMS software was used to build a parameterized dynamic model of the saddle ring. A parameter identification method for the ring was proposed based on the particle swarm optimization algorithm. A loading test was designed and performed several times at different elevation angles. The response histories of the saddle ring with different loads were then obtained. The parameters of the saddle ring dynamic model were identified from statistics generated at a 50° elevation angle to verify the feasibility and accuracy of the proposed method. The actual loading history of the ring at a 70° elevation angle was taken as the model input. The response histories of the ring under these working conditions were obtained through a simulation. The simulation results agreed with the actual response. Thus, the effectiveness and applicability of the proposed dynamic model were verified, and it provides an effective method for modeling saddle rings.