耐1200℃陶瓷瓦重复使用性能

针对目前比较成熟的耐1 200℃陶瓷瓦开展了1 200℃多次重复热处理,研究了陶瓷瓦的结构和性能演变行为和重复使用性能。结果表明:1 200℃热处理20次后,耐1 200℃陶瓷瓦表现出良好的宏观热稳定性;重复热处理过程中,纤维间烧结,黏接熔融和石英纤维析晶及晶粒长大,使纤维直径发生变化,出现缩颈,进而导致了Z向收缩,收缩率达14%,从而使得压缩强度略有增大,隔热性能降低;经过1 260℃、11次单面辐射加热后,Z向收缩率为5.58%,隔热效果降低了7.59%,但隔热材料能够在6次重复加热后保持材料隔热性能不降低。     

3mm波段混凝土屏蔽材料的研究

在混凝土中添加标准砂,钢纤维,铁晶矿砂,炭纤维毡,氧化锌晶须,铁氧体,乙炔碳黑,羰基铁粉等材料,制成了具有微波吸收性能的混凝土屏蔽材料,以期能探索一条大型建筑及军事掩体的电磁防护的新途径。在3mm波段范围内对混凝土屏蔽材料进行了初步的实验研究,研究了不同材料、不同掺量下电磁波的吸收衰减特性,并分析了它们之间的关系,为进一步的研究指明了方向。     

T300和JC2#纤维增强C/SiC复合材料力学性能对比

以聚碳硅烷(PCS)为先驱体,采用聚合物浸渍裂解法(PIP)分别制备得到T300碳纤维和JC2#碳纤维增强C/SiC复合材料。JC2#C/SiC复合材料具有优异的力学性能,抗弯强度和断裂韧性分别达到662MPa和19.5MPa.m1/2;T300 C/SiC复合材料表现出低强度、高脆性,其抗弯强度和断裂韧性不足前者的四分之一。T300 C/SiC复合材料低性能的根本原因在于T300纤维在PCS裂解过程中性能严重下降,复合材料中纤维与基体间存在强界面结合是另一个影响因素。     

Effect of nano powder (Al2O3-CaO) addition on the mechanical properties of the polymer blend matrix composite

This work describes the preparation and study of the properties of composite nanoparticles prepared by the sol-gel method which consists of two materials (Al₂O₃-CaO), and study the effect of these nanoparticles on the mechanical behavior of a polymer blend (EP 4% + 96% UPE). The powder was evaluated by X-ray diffraction analysis, scanning electron microscopy analysis (SEM), particle size analysis, and energy dispersive X-ray analysis (EDX). The mechanical behavior of the composite material was assessed by tensile test, bending test and hardness test. The evaluation results of the composite nanoparticles showed good distribution of the chemical composition between aluminum oxide and calcium oxide, smoothness in particles' size at calcination in high and low temperatures, formation of different shapes of nanoparticles and different (kappa and gamma) phases of the Al₂O₃ particles. The results of mechanical behavior tests showed marked improvement in the mechanical properties of the resulted composite material, especially at 1.5%, compared with polymer blend material without nano powder addition. The tensile properties improved about (24 and 14.9) % and bending resistance about (23.5 and 16.8) % and hardness by (25 and 22) % when adding particles of size (63.8 and 68.6) respectively. Therefore, this reflects the efficiency of the proposed method to manufacture the nanocomposite powder and the possibility of using this powder as a strengthening material for the composite materials and using these composite materials in bio applications, especially in the fabrication of artificial limbs.     

The effect of sintering and cooling process on geometry distortion and mechanical properties transition of PTFE/Al reactive materials

In this research, the effect of the sintering and cooling process on geometry distortion and mechanical properties of PTFE/Al reactive material is investigated. Six particularly selected sintering temperatures, three different cooling modes (annealing cooling, normalizing cooling and rapid cooling), three different initial cooling temperatures, as well as six different final cooling temperatures were designed to compare the effects of sintering temperature, cooling rate, initial cooling temperature and final cooling temperature on the properties of reactive materials. Geometry distortion was quantitatively analyzed by a statistic on the dimensional changes of the specimens and microscopic morphology. A mechanical response properties transition from brittle to ductile was found and analyzed. By combining the thermodynamic properties of PTFE and unsteady heat conduction theory, mechanisms of cooling induced morphology change, temperature induced distortion and strength decrease were obtained. The results showed that the cooling rate has the most significant effect on the morphology transformation, while initial cooling temperature has more significant effect on the dimensional distortion than final cooling temperature. As to the mechanical properties transition from brittle to plastic, a more prominent effect of initial cooling temperature than cooling rate and final temperature was revealed.     

酚醛-石英混杂纤维增强苯并噁嗪复合材料高温失效特征

通过模压工艺制备了酚醛-石英混织纤维增强苯并噁嗪复合材料(P-Q/BZ)试样,考察了其力学性能、烧蚀性能和耐冲刷性能,分析了该试样在高温环境中的主要失效特征,研究其在高温环境中的适用性。结果表明,未经热处理的P-Q/BZ试样平均弯曲强度、弯曲模量和层间剪切强度分别为283 MPa、10.8 GPa和22.6 MPa;经300℃,N_2处理15 min后,试样均匀膨胀,厚度增加22%,弯曲强度、弯曲模量和层间剪切强度分别下降58%、41%和58%;在氧乙炔焰的平均质量烧蚀率和线烧蚀率分别为0.048 4 g/s和-0.081 mm/s,烧蚀后试样宏观不分层,表面炭层微观分层严重,酚醛纤维热解炭、树脂基体热解炭、熔融石英纤维以及碳硅氧化产物相互分离;该试样耐冲刷能力差,在发动机尾焰烧蚀平台模拟的热-力耦合环境中的质量损失率高达59%。P-Q/BZ复合材料需要解决热解膨胀问题,进一步提高抗冲刷性能。     

深紫外非线性晶体KBe_2BO_3F_2的光学倍频特性

通过理论模拟计算详细分析了KBe2BO3F2（KBBF）晶体的光学倍频特性,得到了Nd∶YVO4激光6倍频输出的深紫外激光光源（177.3 nm）的相关技术参数。结果对于KBBF晶体用于产生深紫外全固态激光（DPL）的实验研究提供了重要的理论依据。     

多弧离子镀CrNx涂层的工艺与摩擦磨损性能

为了改善发动机活塞环的摩擦学性能和提高其使用寿命,采用多弧离子镀技术在活塞环表面制备了不同N2含量和弧电流的CrNx硬膜,采用X射线衍射技术、扫描电子显微镜、纳米硬度仪和发动机台架试验装置,分别测试了薄膜相结构、表面形貌、纳米硬度和抗高温摩擦磨损性能。研究结果表明：当N2质量分数为45%时,薄膜纳米硬度相对较高,CrNx薄膜中主要以CrN（220）相为主;随着弧电流的增加,薄膜的表面颗粒尺寸增加,当弧电流为60A时,薄膜纳米硬度相对较高。与Cr电镀层活塞环相比,CrNx涂层活塞环具有较强的抗高温粘着磨损性能。     

添加SiC微粉对硅树脂先驱体转化3D Cf/Si-O-C材料性能的影响

以三维碳纤维织物和廉价的硅树脂为原料,采用先驱体转化工艺制备3D G/Si-O-C材料,考察了浸渍液中添加SiC填料对材料微观结构、力学性能和抗氧化性能影响.结果表明:添加适量的SiC填料有助于减少基体孔隙,改善界面结合,从而提高材料的力学性能;而SiC含量过高时,容易在材料内部形成闭孔,从而导致材料力学性能下降.当SiC微粉含量为18.2%时,材料具有最好的力学性能,弯曲强度和断裂韧度分别为421.3MPa和13.0 MPa·m1/2;而材料的抗氧化性能随着SiC微粉含量的增加而增加,当SiC微粉含量为25.0%时,材料的弯曲强度保留率最高,达到了89.5%.     

Multifunctional A356 alloy/ PKSAnp composites: Microstructure and mechanical properties

Mechanical properties and microstructure of multifunctional composites produced with palm kernel shell ash nanoparticle (PKSAnp)-A356 alloy composites was studied. The composites were produced using Double layer feeding stir casting method (DLF-SCM) by adding 1 wt%‒4 wt.% PKSAnp. The microstructure, density, electrical and mechanical properties were determined. The results shows that there was a uniform distribution of the PKSAnp in A356 alloy. The mismatch at the interface between the PKSAnp and A356 alloy was 4.26%. Improvement of 30.47%, 41.91%, 49.52%, 40.90% and 65.09% were obtained for hardness values, tensile, yield strength, %elongation and impact energy at 4 wt% PKASnp. The work has established that the developed composites can be used for multifunctional applications where combination of toughness and strength is vital.