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本文用差示扫描量热仪(DSC7)测得了几种单质炸药和样品混合炸药的非等温DSC曲线,对热分解反应速率方程进行了研究,编制了由一条非等温DSC曲线的信息计算炸药热分解反应动力学参数的程序,并证明DSC的线性升温速率对动力学参数没有明显影响。 相似文献
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Li-xiaosong Du Shao-hua Jin Qing-hai Shu Li-jie Li Kun Chen Ming-lei Chen Jun-feng Wang 《防务技术》2022,18(1):72-80
3-nitro-1,2,4-triazol-5-one (NTO) is the main component of insensitive munitions (IM) formulation because of its outstanding insensitive properties.In this paper,a series of NTO/HMX-based composite explosives were prepared and characterized.The study focuses on the effect of NTO on the performance of the formulations,especially the safety performance.The results revealed that the mechanical sensi-tivity of formulations was associated with NTO content,as well as the thermal conductivity,specific heat capacity and Arrhenius parameters.Then,the high amount of NTO using in formulation was proved to be helpful for NTO/HMX-based formulation to exhibit good thermal safety.Besides,by accelerating rate calorimeter (ARC) and a modified cook-offequipment,the pressure and pressure rise rate were proved as the important indicator for judging the thermal safety performance in confined spaces.Finally,the numerical simulation was used as a credible method for predicting the respond temperature of cook-off experiment. 相似文献
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频率搅拌混响室内小屏蔽体的场均匀性检验 总被引:1,自引:0,他引:1
为了研究频率搅拌混响室内小屏蔽体的屏蔽效能测试方法,需要检验小屏蔽体内的场均匀性.通过对混响室的场均匀性测试方法的研究,提出基于矢量网络分析仪的测试方法,通过计算工作区域任意两点的功率比检验场均匀性,并用该方法检验工作区域内小屏蔽体的场均匀性.实验结果表明:混响室采用扫频信号实现频率搅拌时,放置于工作区域的小屏蔽体内部同样有较好的场均匀性. 相似文献
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电磁辐射对桥丝式电火工品性能影响研究 总被引:1,自引:0,他引:1
利用传导方法研究射频对桥丝式电火工品的桥丝电阻、烤爆、迟发火以及瞎火等性能影响。研究结果表明,在10%发火功率和0.4MHz的敏感频率条件下,所研究的3种电火工品在照射1~5min后,电阻增加1.2%~7.4%,并且17.3%的试样在照射的过程中出现了烤爆;在对经过照射后的试样进行正常的发火感度试验中,发火时间显著增加,出现了不同程度的迟发火,16.9%的试样瞎火。 相似文献
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Shockwaves from fuel-air explosive (FAE) cloud explosions may cause significant casualties. The ground overpressure field is usually used to evaluate the damage range of explosion shockwaves. In this paper, a finite element model of multi-sources FAE explosion is established to simulate the process of multiple shockwaves propagation and interaction. The model is verified with the experimental data of a fourfold-source FAE explosion, with the total fuel mass of 340 kg. Simulation results show that the overpressure fields of multi-sources FAE explosions are different from that of the single-source. In the case of multi-sources, the overpressure fields are influenced significantly by source scattering distance and source number. Subsequently, damage ranges of overpressure under three different levels are calculated. Within a suitable source scattering distance, the damage range of multi-sources situation is greater than that of the single-source, under the same amount of total fuel mass. This research provides a basis for personnel shockwave protection from multi-sources FAE explosion. 相似文献
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The photostabilies of hexanitrostillbene(HNS)were studied at 1%wt.of photostabilizers.The photo-stabilizers of Chiguard BP-12(UV-531),ADK STAB LA-326(UV-326),ADK STAB LA-32(UV-P),Irganox 1010 and Everstab LS944 were used in this study.A photoreactor including a 30 W monochromatic UV lamp was used for investigation of photodegradations of solid HNS.The changes in surface area of HNS peak in HPLC chromatogram at time intervals of 2,4,6 and 8 h were used for calculation of kinetic rate constants of photodegradation process.The compound of UV-P photostabilizer was found to have the greatest effect on enhancing photostability for HNS among the investigated photostabilizers.The kinetic rate constants were obtained 6.2 × 10-2 and 4.1 × 10-2 h-1,respectively,for photodegradation process of HNS in absence and in presence of UV-P. 相似文献
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In order to improve the energy level of fuel air explosive(FAE) with delayed secondary igniters, high energetic metal powders were added to liquid fuels mainly composed of ether and isopropyl nitrate. Metal powders' explosive properties and reaction mechanisms in FAE were studied by high-speed video, pressure test system, and infrared thermal imager. The results show that compared with pure liquid fuels, the shock wave overpressure, maximum surface fireball temperature and high temperature duration of the mixture were significantly increased after adding high energetic metal powder. The overpressure values of the liquid-solid mixture at all measuring points were higher than that of the pure liquid fuels. And the maximum temperature of the fireball was up to 1700 ℃, which was higher than that of the pure liquid fuels. After replacing 30%of aluminum powder with boron or magnesium hydride, the shock wave pressure of the mixture was further increased. The high heat of combustion of boron and the hydrogen released by magnesium hydride could effectively increase the blast effect of the mixture. The improvement of the explosion performance of boron was better than magnesium hydride. It shows that adding high energetic metal powder to liquid fuels can effectively improve the explosion performance of FAE. 相似文献
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A new model has been defined that enables the estimation of the lethal radius (radius of efficiency) of HE (High Explosive) artillery projectiles against human targets. The model is made of several modules: CAD (Computer Aided Design) modeling, fragment mass distribution estimation, fragment initial velocity prediction, fragment trajectory calculation, effective fragment density estimation, and high explosive projectile lethal radius estimation. The results were compared with the experimental results obtained based on tests in the arena used in our country, and the agreement of the results was good. This model can be used in any terminal-ballistics scenario for high explosive projectiles since it is general, para-metric, fast and relatively easy to implement. 相似文献
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