聚碳硅烷／二乙烯基苯快速升温裂解制备Cf/SiC复合材料

以聚碳硅烷(PCS)/二乙烯基苯(DVB)为先驱体,采用快速升温裂解制备了3D-B Cf/SiC复合材料.结果证明:裂解升温速率的提高可以大大缩短制备周期,同时可以提高材料密度和形成较好的界面结合,从而提高材料的力学性能.制备得到的Cf/SiC材料室温弯曲强度达到556.7MPa.     

三维编织碳纤维增强莫来石复合材料的制备与性能

结合Al2O3溶胶—凝胶技术和聚硅氧烷浸渍裂解技术制备出三维编织碳纤维增强莫来石复合材料(3D BCf/mullite)。研究表明,以AlCl3·6H2O和(CH2)6N4为原料的溶胶—凝胶工艺能制备出纳米γ Al2O3粉,它与聚硅氧烷在1400℃N2中共裂解可反应生成莫来石。所得3D BCf/mullite的密度为1.784g/cm3,弯曲强度和断裂韧性分别为282.5MPa和17.7MPa·m1/2。材料中较多的孔隙是材料密度和弯曲强度不高的原因所在。     

高温空气下C/SiC复合材料力学性能测试

测试了C/SiC复合材料在高温空气下的压缩、弯曲和拉伸性能,利用扫描电子显微镜分析复合材料在室温与高温条件下的断口微观形貌。结果表明:从室温升温到1 000 ℃测试温度时,C/SiC复合材料的压缩强度由247 MPa降低至78 MPa,性能降低68%;弯曲强度由480 MPa降低至277 MPa,性能降低42%;拉伸强度由247 MPa降低至152 MPa,性能降低38%。高温氧化导致界面退化,损伤材料基体与碳纤维结构,加剧了纤维断裂程度,改变了纤维与基体的结合状态,纤维增韧机制逐渐消失,导致复合材料性能下降。     

Micromechanical simulation and experimental investigation of aluminum-based nanocomposites

Ceramic reinforced metal matrix nanocomposites are widely used in aerospace and auto industries due to their enhanced mechanical and physical properties. In this research, we investigate the mechanical properties of aluminum/Nano-silica composites through experiments and simulations. Aluminum/Nano-silica composite samples with different weight percentages of silica nanoparticles are prepared via powder metallurgy. In this method, Nano-silica and aluminum powders are mixed and compressed in a mold, followed by sintering at high temperatures. Uniaxial tensile testing of the nanocomposite samples shows that adding one percent of Nano-silica causes a considerable increase in mechanical properties of nanocomposite compared to pure aluminum. A computational micromechanical model, based on a representative volume element of aluminum/silica nanocomposite, is developed in a commercial finite element software. The model employs an elastoplastic material model along with a ductile damage model for aluminum matrix and linear elastic model for nano-silica particles. Via careful determination of model parameters from the experimental results of pure aluminum samples prepared by powder metallurgy, the proposed computational model has shown satisfactory agreement with experiments. The validated computational model can be used to perform a parametric study to optimize the micro-structure of nanocomposite for enhanced mechanical properties.     

3维C/SiC-ZrC复合材料的制备及其性能研究

针对超高温环境应用需求,采用化学气相渗透工艺(CVI)与先驱体浸渍-裂解工艺(PIP)联用制备了3维碳纤维增强SiC-ZrC基复合材料(C/SiC-zrC),并研究了SiC含量对C/SiC-ZrC复合材料力学性能、抗氧化性能和抗烧蚀性能的影响.结果表明,随着SiC含量的增加,C/SiC-ZrC复合材料的强度逐渐降低,静...     

侧面封边对玻璃纤维增强环氧树脂基复合材料吸湿规律的影响

采用称量法和排水法联合,研究了侧面封边和未封边单向玻璃纤维增强环氧树脂基复合材料层合板试件的吸湿量和体积变化率与浸泡时间的关系,结果显示,复合材料侧面吸湿的速度远大于表面吸湿速度;侧面封边复合材料试件的饱和吸湿量为1.30％,而未封边试件的为2.26％,即与侧面封边试件相比,未封边试件的饱和吸湿量(质量比)增加了73....     

纳米材料和纳米技术提升传统产业

纳米材料具有一些特殊的、优异的性能,将纳米材料作为复合添加剂对某些传统产品进行改性,可以显著提高产品的性能或使他们具有新的功能。研究了不同的纳米复合材料在聚胺酯合成革、外墙涂料、塑料、抗菌剂、永磁铁氧体以及润滑油等方面的改性和工程应用,并简述了利用纳米技术在改造和提升传统产业方面取得的成果以及在产业化方面做出的实质性业绩。     

T300和JC2#纤维增强C/SiC复合材料力学性能对比

以聚碳硅烷(PCS)为先驱体,采用聚合物浸渍裂解法(PIP)分别制备得到T300碳纤维和JC2#碳纤维增强C/SiC复合材料。JC2#C/SiC复合材料具有优异的力学性能,抗弯强度和断裂韧性分别达到662MPa和19.5MPa.m1/2;T300 C/SiC复合材料表现出低强度、高脆性,其抗弯强度和断裂韧性不足前者的四分之一。T300 C/SiC复合材料低性能的根本原因在于T300纤维在PCS裂解过程中性能严重下降,复合材料中纤维与基体间存在强界面结合是另一个影响因素。     

Performance study of jute-epoxy composites/sandwiches under normal ballistic impact

This study is undertaken to explore the use of natural fiber Jute-epoxy (JE), Jute-epoxy-rubber (JRE) sandwich composite for ballistic energy absorption. Energy absorbed and residual velocities for these composites are evaluated analytically and through Finite Element Analysis (FEA). FE analysis of JE plates is carried out for different thicknesses (3, 5, 10 and 15 mm). JE plates and JRE sandwiches having the same thickness (15 mm) are fabricated and tested to measure residual velocity and energy absorbed. The analytical results are found to agree well with the results of FE analysis with a maximum error of 9%. The study on JE composite plate reveals that thickness influences the energy absorption. Experimental and FE analysis study showed that JRE sandwiches have better energy absorption than JE plates. Energy absorption of a JRE sandwich is about 71% greater than JE plates. Damages obtained from FEA and testing are in good agreement. SEM analysis confirms composites failed by fiber rupture and fragmentation.     

吸湿环境对石英纤维增强环氧树脂面板/PMI泡沫夹层结构复合材料吸湿行为的影响

研究了不同温度、湿度环境下,夹层结构石英纤维增强环氧树脂面板/PMI泡沫夹层结构复合材料及其芯材和面板的吸湿规律。将石英纤维增强环氧树脂面板、PMI泡沫、复合材料面板/PMI泡沫夹层结构试样在不同吸湿环境中进行吸湿处理后,对其吸湿行为进行分析。结果表明:浸水环境下面板、PMI泡沫、PMI泡沫夹层结构复合材料都表现出更为严重的吸湿行为;在潮湿环境中,50℃至70℃范围内,温度越高,试样在吸湿过程中的质量损失越多,最终的饱和吸湿率越小;在60℃以内的潮湿环境中,PMI泡沫夹层结构复合材料的饱和吸湿率可以通过相同环境下面板复合材料和PMI泡沫的吸湿率进行预测。