多点喷射空气酒精燃气发生器试验验证

为有效解决现有燃气引射气源存在的诸多缺点,适应一种引射系统大流量、小型化的需要,在综合分析各燃气引射气源方案的基础上,研制了一种以空气、酒精作为推进剂的多点喷射结构的燃气发生器,并开展了多种工况下的试验研究。结果表明:采用的多点喷射方案大大提高了空间利用率,有效满足了引射系统小型化的要求;喷雾性能好,喷雾锥角及粒径优于设计指标要求;点火可靠性高,解决了领域内现有燃气发生器点火可靠性低的缺点;点火迅速,燃烧平稳,可实现较为均匀的出口温度场;燃气发生器工作范围较宽,能在余气系数2.52～4.34范围内稳定燃烧;高效的火焰筒内壁空气冷却方式有效保证了燃气发生器长时间工作运行。     

The properties of Sn–Zn–Al–La fusible alloy for mitigation devices of solid propellant rocket motors

The Al and La elements are added to the Sn9Zn alloy to obtain the fusible alloy for the mitigation devices of solid propellant rocket motors. Differential scanning calorimetry (DSC), metallographic analysis, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), tensile testing and fracture analysis were used to study the effect of Al and La elements on the microstructure, melting characteristics, and mechanical properties of the Sn9Zn alloy. Whether the fusible diaphragm can effectively relieve pressure was investigated by the hydrostatic pressure at high-temperature test. Experimental results show that the melting point of the Sn9Zn-0.8Al0·2La and Sn9Zn–3Al0·2La fusible alloys can meet the predetermined working temperature of ventilation. The mechanical properties of those are more than 35% higher than that of the Sn9Zn alloy at −50 °C–70 °C, and the mechanical strength is reduced by 80% at 175 °C. It is proven by the hydrostatic pressure at high-temperature test that the fusible diaphragm can relieve pressure effectively and can be used for the design of the mitigation devices of solid propellant rocket motors.     

丁羟（HTPB）推进剂老化研究（IV）——过氯酸铵（AP）粒度对老化性能的影响

本文研究了HTPB/AP推进剂中AP粒度对推进剂老化性能的影响。实验是在90℃的空气中进行的。老化性能以推进剂的拉伸性能、邵氏硬度,失重%和燃烧速度等参数为判据,并以DSC图谱作参考。实验结果表明:HTPB/AP推进剂中AP粒度的减小,有助于推进剂贮存老化性能的提高。各种粒度AP的DSC图谱,也进一步证实了这一结论。     

发射装药非稳态温度场仿真

弹药在长期贮存过程中,极易受环境温度和湿度的作用,使发射装药出现热分解、裂解、结霜等,严重影响弹药装药的贮存可靠性;在射击试验中,发射药温度也会对弹道性能产生极大的影响。由于不允许对弹药进行破坏性开孔,因此借助Ansys的热分析模块,对发射装药非稳态温度场进行仿真研究,获取发射装药在不同环境条件下的温度场及不同节点的温度变化规律,为弹药的贮存、试验提供一定的参考价值。     

Investigation on the foaming behaviors of NC-based gun propellants

To prepare the porous NC-based (nitrocellulose-based) gun propellants, the batch foaming process of using supercritical CO₂ as the physical blowing agent is used. The solubilities of CO₂ in the single-base propellants and TEGDN (trimethyleneglycol dinitrate) propellants are measured by the gravimetric method, and SEM (scanning electron microscope) is used to observe the morphology of foamed propellants. The result shows that a large amount of CO₂ could be dissolved in NC-based propellants. The experimental results also reveal that the energetic plasticizer TEGDN exerts an important influence on the pore structure. The triaxial tensile failure mechanism for solid-state nucleation is used to explain the nucleation of NC-based propellants in the solid state. Since some specific foaming behaviors of NC-based propellants can not be explained by the failure mechanism, a solid-state nucleation mechanism which revises the triaxial tensile failure mechanism is proposed and discussed.     

复合固体推进剂颗粒填充模型及其统计特性分析

复合固体推进剂属于高填充比颗粒类复合材料,氧化剂和金属颗粒在基体中的随机分布使其在细观尺度具有非均质的特点。从细观尺度研究固体推进剂燃烧及力学性能时,必须考虑颗粒级配、空间分布和种类等因素的影响。采用分子动力学方法,以硝酸酯增塑聚醚高能复合固体推进剂为研究对象,将固体颗粒模型化为球形,生成其在基体内随机分布的颗粒填充模型。利用Monte-Carlo算法模拟计算颗粒填充模型细观结构的两点概率函数,并研究了颗粒填充体积分数、尺寸与级配等参数对其的影响规律。从统计意义上给出具有各态历经性、统计均匀性和各向同性特点的颗粒填充构型最小周期性代表体元尺寸,可有效减小后续研究的计算量,节约计算成本。所构建的推进剂细观几何构型及对最小周期性代表体元尺寸的计算为后续开展复合固体推进剂细观尺度燃烧、燃面处铝团聚及力学性能数值研究奠定了基础。     

Simulation of the plasticizing behavior of composite modified double-base (CMDB) propellant in grooved calendar based on adaptive grid technology

The frequent occurrence of safety accidents during the calendering process is caused by the flammable and explosive properties of composite modified double-base (CMDB) propellant. Optimization of process parameters with the aid of fluid simulation technology could effectively ensure the safety of the calendering process. To improve the accuracy of the simulation results, material parameters and model structure were corrected based on actual conditions, and adaptive grid technology was applied in the local mesh refinement. In addition, the rheological behavior, motion trajectories and heat transfer mechanisms of CMDB propellant slurry were studied with different gaps, rotational rates and temperatures of two rollers. The results indicated that the refined mesh could significantly improve the contour clarity of boundaries and simulate the characteristics of CMDB propellant slurry reflux movement caused by the convergent flow near the outlet. Compared with the gap, the increased rotational rate of roller could promote the reflux movement and intensify the shear flow of slurry inside the flow region by viscous shear dragging. Meanwhile, under the synergistic effect of contact heat transfer as well as convective heat exchange, heat accumulated near the outlet and diffused along the reflux movement, which led to the countercurrent heat dissipation behavior of CMDB propellant slurry. The plasticizing mechanism of slurry and the safety of calendering under different conditions were explored, which provided theoretical guidance and reference data for the optimization of calendering process conditions. Based on the simulation results, the safety of the CMDB propellant calendering process could be significantly improved with a few tests conducted during a short research and development cycle.     

聚氨酯型复合推进剂的性能研究

本文研究聚氨酯型复合推进剂的力学性能和燃烧性能,给出了提高推进剂力学性能的有效途径,测试了推进剂燃烧性能的基本特征参数,采用光电子能谱(ESCA)对这种复合推进剂的界面作用机理进行了微观探讨.     

单基发射药的热自燃数值模拟与其剩余能量变化研究

建立了单基发射药柱热自燃的数学模型 ,根据模型利用数值模拟的方法计算了单基发射药的中心温度与其剩余能量 ,并对中心温度的模拟结果与实验结果进行了比较。解决了其热分解动力学参数的非唯一性问题 ,为装填有单基发射药各种弹药的热自燃计算提供了依据