Nitro-tetrazole based high performing explosives: Recent overview of synthesis and energetic properties

Heterocyclic skeleton (Azoles) and different energetic groups containing high performing explosives are highly emerged in recent years to meet the challenging requirements of energetic materials in both military and civilian applications with improved performance. For this purpose tetrazole (Azole) is identified as an attractive heterocyclic backbone with energetic functional groups nitro (-NO₂), nitrato (-ONO₂), nitrimino (-NNO₂), and nitramino (–NH–NO₂) to replace the traditionally used high performing explosives. The tetrazole based compounds having these energetic functional groups demonstrated advanced energetic performance (detonation velocity and pressure), densities, and heat of formation (HOF) and became a potential replacement of traditional energetic compounds such as RDX. This review presents a summary of the recently reported nitro-tetrazole energetic compounds containing poly-nitro, di/mono-nitro, nitrato/nitramino/nitrimino, bridged/bis/di tetrazole and nitro functional groups, describing their preparation methods, advance energetic properties, and further applications as high-performing explosives, especially those reported in the last decade. This review aims to provide a fresh concept for designing nitro-tetrazole based high performing explosives together with major challenges and perspectives.     

Explaining the impact of militancy on Iran–Pakistan relations

ABSTRACT

Sectarian militants have for years launched attacks from Pakistan across the border to Iran. Finding sanctuary in a neighbouring country can make the difference between success and failure for militants. Conventional wisdom holds that a lasting transnational militancy challenge would typically create serious interstate conflict. Militancy has triggered armed encounters between Iran and Pakistan. This article argues that despite some tension militancy has resulted in deeper cooperation in the ambivalent dyad. Both states’ overarching security concerns, having exhausted other options, the believed involvement of third-party states, and economic potential, have moderately alleviated negative pressure caused by militancy.