Ti含量对Ti-B4C-C体系自蔓延高温合成的影响

以14Ti+3B4C+5C为基础反应体系,通过热力学分析及静态燃烧合成实验研究了钛含量对该体系SHS反应的绝热温度、反应速度和产物致密度的影响.研究表明,Ti含量适当增加,能够使反应速度加快、产物致密度提高.当Ti过量16%(摩尔分数)时,体系的绝热温度仍高达3 193K,反应速度最快,产物的致密度也较高.     

一种改进的混合BLISS多学科设计优化方法

针对BLISS 2000优化过程中权值系数的引入给实际应用带来的困难,提出一种改进的BLISS优化过程——混合BLISS( Hybrid BLISS,HBLISS).该方法在保持BLISS 2000的基本算法结构的基础上取消权值系数,利用耦合变量的最小残差协调子系统级和系统级优化,给出了HBLISS的算法结构和基本流程...     

Recent advances in the synthesis and energetic properties of potassium-based potential green primary explosives

Primary explosives are utilized as a reliable initiator for secondary explosives in an extensive range of military and civilian operations. Heavy–metal–based primary explosives are moderate performing, more sensitive, and environmentally hazardous, posing a direct and indirect threat to health and safety. Therefore, heavy–metal–based primaries have been replaced by environment-friendly metal-based primary explosives, such as potassium complexes. This review presents not only a summary of the current progress of new-generation potassium-based primary explosives and their methods of preparation, energetic properties, and applications, but also a further comparison with traditional primary explosives. In addition, this work discusses the necessity of heavy metal–free primary explosives and the major challenges faced in replacing traditional primary explosives.     

Scale-up synthesis and characterization of 2,6-diamino-3,5-dinitropyrazine-1-oxide

2,6-diamino-3,5-dinitropyrazine-1-oxide (ANPZO), as an insensitive high explosive, with a high yield and excellent purity has been prepared at pilot plant scale by an improved method. The synthesized ANPZO is characterized by IR, laser granularity measurement, SEM and HPLC. The particle analysis revealed that the improved method could offer desired product with average particle size of 40 μm and high purity (>98.45%). The experimental parameters exhibited that the detonation velocity of the formulation based on ANPZO was higher than that of the corresponding TATB formulation. The DSC curve showed that the exothermic decomposition of the product occurred at the temperature between 300.5 °C and 360.4 °C. Furthermore, the sensitivity test suggests its safe nature towards mechanical stimulus.     

Synthesis and properties of novel nitro-based thermally stable energetic compounds

This paper reviews the achievements in the field of synthesis of new thermally resistant explosive compounds in the years 2009 through 2019. The performance characteristics of these compounds (sensitivity, thermal decomposition parameters, and detonation parameters) were compared with those of 1,3,5-triamino-2,4,6-trinitrobenzene, which still seems to be an unrivalled model of a thermally resistant and generally low-sensitivity explosive material. New thermally stable explosives (TSEs) were found among macromolecular compounds with tri- and dinitrophenyl groups, nitro and amine-nitro derivatives of azoles, and polynitro derivatives of calixarenes. Some of them match TATB in terms of thermal resistance and additionally have higher detonation parameters.     

装备环境应力归纳技术研究

对实测振动数据通过随机性检验和谱分析进行编辑确认和分离性测量分析,得到实测功率谱密度曲线;采用Arrhenius和Manson-Coffin模型对实测温度数据的周期分量和随机分量进行等效平均和等效循环处理,得到实测温度应力剖面;采用基于修正容差上限技术对实测应力进行修正,实现剖面综合,得到综合环境试验剖面。     

4-羟甲基-2,6,7-三氧杂二环(2.2.2)辛烷的合成

介绍了双环原酸酯个4-羟甲基-2,6,7-二氧杂二环（2．2．2）辛烷的合成方法,并提供了一条简单可行的合成途径．