桥丝式电火工品静电感度测试方法研究

本文对目前静电感度试验的现状进行了分析。在理论分析的基础上解决了JGY-50型静电火花感度仪的串联电阻和真空开关所带来的问题。提出了桥丝式电火工品的静电感度测试新方法,通过一个高压线性采样装置直接测量试样在试验过程中的电压、电流曲线,求得试样实际消耗的能量,以此统计试样的静电感度。采用这种方法,测试了JD-11电点火具的50％发火能与放电时间常数的关系,得到了呈单调规律变化的曲线。     

火箭弹防静电作用研究

针对电发火弹药静电放电问题,以某型130 mm火箭弹为例,采用真实静电感度测试系统测试了电火工品在有、无绝缘层时50%的静电点火能量,并在试验程序及数据处理中使用真实静电感度数据处理方法统计了50%静电发火能量的估计值。通过比较发现二者的差值在误差范围内,这表明静电放电研究中可以将弹体所接受的能量视作全部作用于火工品上,绝缘层不吸收静电放电的能量。在电发火弹药的防护中,必须采用静电防护措施杜绝电发火弹药的意外发火。     

电磁辐射对桥丝式电火工品性能影响研究

利用传导方法研究射频对桥丝式电火工品的桥丝电阻、烤爆、迟发火以及瞎火等性能影响。研究结果表明,在10％发火功率和0．4MHz的敏感频率条件下,所研究的3种电火工品在照射1～5min后,电阻增加1.2％～7．4％,并且17．3％的试样在照射的过程中出现了烤爆;在对经过照射后的试样进行正常的发火感度试验中,发火时间显著增加,出现了不同程度的迟发火,16．9％的试样瞎火。     

火炸药静电起爆最小发火能量测试方法研究

分析研究了测量火炸药静电起爆最小发火能量的三种方法,并进行了大量的对比试验,提出了首先进行OSTR法试验,然后进行逐步降压法试验,从而得出火炸药静电起爆的最小发火能量。     

关于提高枪弹发火感度的研究

提高枪弹发火感度的方法,通过调整枪弹底火内击发药组分及弹壳内火台高度提高枪弹发火感度。经过试验数据对比分析,证明方法合理可行。     

电桥材料和结构对发火感度影响分析

电桥材料和结构可影响电火工品的发火感度,依据电火工品发火能量平衡方程,对几种常用材料不同电桥形状对电火工品(EED)感度的影响进行了分析,结果表明通过改变电桥材料和电桥结构能够降低EED的发火感度,为EED改进提供了依据。     

ESD对电点火管安全性的影响研究

简述了真实静电感度测试方法及其数据处理方法,报道了利用该方法测试的两种电点火管DD—4.5、DD—17的静电感度测试结果。确定了其最小静电点火能分别为834μJ和188μJ。依据不同的ESD(静电放电)模型,讨论了不同静电危害源对电点火管直接放电时的最高安全电压值。     

定性测量与定量测量火炸药静电感度的对比分析

采用先进测试系统,对氮化铅、硝化棉、梯恩梯和黑索金火炸药静电感度分别进行了定性测量和定量测量,得出了相对静电感度值和实际静电感度值,并对其进行了对比分析。     

引信军标委2000年工作计划

引信军标委2000年工作计划包括:①根据原科工委下达的科研计划,《引信外场性能试验方法》国军标要在2000年上半年完成送审报批。该系列标准包括引信零部件强度试验、发射安全性试验、大着角发火性试验、对钢甲发火性试验、钝感度试验、灵敏度试验、对目标发火性试验、自毁时间试验、炸高试验、远距离接电试验以及保险距离和解除保险距离试验等方法。②引     

钝感电火工品静电敏感度试验研究

钝感电火工品具有一定的稳定性和抗静电能力。采用真实静电感度试验方法测试其静电敏感度,能够为产品设计和鉴定试验时进行定量的静电安全性评估、确定钝感电火工品对各种有害使用环境的抵抗能力以及为产品制定安全技术标准和采取防护措施提供科学依据。     

Hazard evaluation of ignition sensitivity and explosion severity for three typical MH2 (M＝Mg,Ti, Zr) of energetic materials

MgH2, TiH2, and ZrH2 are three typical metal hydrides that have been gradually applied to composite explosives and propellants as additives in recent years. To evaluate ignition sensitivity and explosion severity, the Hartmann device and spherical pressure vessel were used to test ignition energy and ex-plosion pressure, respectively. The results showed that the ignition sensitivity of ZrH2, TiH2 and MgH2 gradually increased. When the concentration of MgH2 is 83.0 g/m3 in Hartmann device, the ignition energy attained a minimum of 10.0 mJ. The explosion pressure of MgH2 were 1.44 times and 1.76 times that of TiH2 and ZrH2, respectively, and the explosion pressure rising rate were 3.97 times and 9.96 times that of TiH2 and ZrH2, respectively, through the spherical pressure vessel. It indicated that the reaction reactivity and reaction rate of MgH2 were higher than that of TiH2 and ZrH2. In addition, to conduct in-depth theoretical analysis of ignition sensitivity and explosion severity, gas production and combus-tion heat per unit mass of ZrH2, TiH2 and MgH2 were tested by mercury manometer and oxygen bomb calorimetry. The experimental results revealed that MgH2 had a relatively high gas production per unit mass (5.15 mL/g), while TiH2 and ZrH2 both had a gas production of less than 2.0 mL/g. Their thermal stability gradually increased, leading to a gradual increase in ignition energy. Furthermore, compared with theoretical combustion heat, the combustion ratio of MgH2, TiH2 and ZrH2 was more than 96.0%, with combustion heat value of 29.96, 20.94 and 12.22 MJ/kg, respectively, which was consistent with the explosion pressure and explosion severity test results.     

Thermodynamics and performance of Al/CuO nanothermite with different storage time

The storage stability of energetic materials is important for its application. Here, the storage stability of Al/CuO nanothermite, which was prepared by electrospray method and stored with different storage time, was systematically researched. The activation energy of Al/CuO nanothermite was calculated by differential scanning calorimetry (DSC). The ignition temperature and the curve pressure history of Al/CuO nanothermite was measured using ignition temperature measuring device and constant-volume pressurization tests, respectively. Further, the thermites were characterized by X-ray Diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and Transmission electron microscopy (TEM). The results show that the morphology of the thermites did not change significantly. The activation energy was decreased from 254.1 kJ/mol to 181.8 kJ/mol after storage for 13 months. When stored for 0, 7 and 13 months, the peak pressures of Al/CuO nanothermite were 685.8 kPa, 626.3 kPa and 625.5 kPa, respectively. In addition to the ignition temperature, it was 775 ℃, 739 ℃ and 754 ℃, respectively. This result indicated that the ignition and combustion properties of Al/CuO nano-thermite are obviously reduced when stored for a long time, at room temperature.     

微小型固体火箭发动机点火特性试验

设计了一种适用于某微小型固体火箭发动机的点火器 ,对某微小型固体火箭发动机的点火特性进行了大量试验研究 ,引入了初始点火压强的概念 ,找出了影响点火延迟时间散布的主要规律 ,确定了能满足微小型固体火箭发动机点火性能的点火方案     

Controllable combustion behaviors of the laser-controlled solid propellant

Microsatellites have been widely applied in the fields of communication,remote sensing,navigation and science exploration due to its characteristics of low cost,flexible launch mode and short development period.However,conventional solid-propellant have difficulties in starting and interrupting combustion because combustion is autonomously sustained after ignition.Herein,we proposed a new type of solid-propellant named laser-controlled solid propellant,which is sensitive to laser irradiation and can be started or interrupted by switching on/off the continuous wave laser.To demonstrate the feasibility and investigate the controllable combustion behaviors under different laser on/off conditions,the combus-tion parameters including burning rate,ignition delay time and platform pressure were tested using pressure sensor,high-speed camera and thermographic camera.The results showed that the increase of laser-on or laser-off duration both will lead to the decrease of propellant combustion performance during re-ignition and re-combustion process.This is mainly attributed to the laser attenuation caused by the accumulation of combustion residue and the change of chamber ambient temperature.Simultaneously,the multiple ignition tests revealed that the increased chamber ambient temperature after combustion can make up for the energy loss of laser attenuation and expansion of chamber cavity.However,the laser-controlled combustion performance of solid propellant displayed a decrease trend with the addi-tion of ignition times.Nevertheless,the results still exhibited good laser-controlled agility of laser-controlled solid propellant and manifested its inspiring potential in many aspects of space missions.     

Liquid phase in-situ synthesis of LiF coated boron powder composite and performance study

Among practical metal additives, boron (B) has a high volumetric heating value, making it a promising choice as a fuel additive. Although B can theoretically yield a large amount of energy upon complete combustion, its combustion is retarded by the initial presence of B oxide, which coats the surfaces of B particle. To improve the ignition and combustion properties of B powder, LiOH and NH₄F were used as precursors to synthesize uniformly LiF-coated B composites (LiF-B) in situ. The LiF-B mixture was also prepared for comparison using a physical method. X-ray diffraction (XRD), Fourier-transform infrared (FTIR), scanning electron microscope (SEM), and energy-dispersive X-ray spectroscopy (EDS) were used to characterize the morphologies and compositions of the products. The thermal and combustion properties of the samples were characterized by thermal gravity-differential thermal gravity (TG-DTG), differential scanning calorimetry (DSC) and closed bomb experiment. The XRD, FTIR, SEM and EDS results demonstrated the successful preparation of the coated LiF-B sample. The TG-DTG and closed bomb experiment results indicated that the addition of LiF decreased the ignition temperature of B powder, and increasing its reaction efficiency. DSC results show that when LiF-B was added, the released heat of underwater explosive increased by 6727.2, 7280.4 and 3109.6 J/g at heating rates of 5, 10, and 15 °C/min, respectively. Moreover, LiF-B decreased the activation energy of secondary combustion reaction of explosive system as calculated through Kissinger's method by 28.9%, which indicated an excellent catalytic effect for the thermal decomposition of underwater explosive. The results reveal that LiF can improve the combustion efficiency of B powder, thereby increasing the total energy of explosives. The mechanical sensitivity increased slightly after adding LiF-B to the underwater explosive. Compared to the underwater explosive with added B, the mechanical sensitivity of the explosive with added LiF-B was significantly lower.     

Microcrack- and microvoid-related impact damage and ignition responses for HMX-based polymer-bonded explosives at high temperature

Investigating the damage and ignition behaviors of polymer-bonded explosive (PBX) under a coupled impact and high-temperature loading condition is required for the safe use of charged PBXs. An improved combined microcrack and microvoid model (CMM) was developed for better describing the thermal effects of deformation, damage, and ignition responses of PBXs. The main features of the model under typical dynamic loadings (i.e. uniaxial tension and compression, and lateral confinement) at different initial temperature were first studied. And then the effects of temperature on impact-shear sensitivity of HMX-based PBXs were investigated. The results showed that the ignition threshold velocity of shear-crack hotspots exhibits an increase from 260 to 270 to 315–325 m/s when initial temperature increases from 301 to 348 K; and then the threshold velocity decreases to 290–300 m/s with the initial temperature continually increasing to 378 K. The predicted ignition threshold velocity level of the explosives under coupled impact and high temperature loading conditions were consistent with the experimental data.     

Thermal and combustion behavior of Al-MnO2 nanothermite with poly(vinylidene fluoride -co- hexafluoropropylene) energetic binder

Fluoropolymers get increasing attention in energetic materials application due to the high fluorine content. To explore the effect of poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP)) on Al/MnO2 nanothermite, the samples with different contents are prepared and characterized by SEM, TG-DSC, XRD, and their ignition and combustion behavior are tested and recorded. The results show that P(VDF-HFP) as an energetic binder can combine the nanothermite components together, even exist in the gaps. The integrity of energetic materials has been improved. Thermal analysis shows that the addition of P(VDF-HFP) greatly changes the thermal reaction processes, and the exothermic peaks appear early, but the utilization of fuel and oxidizer is not efficient from the XRD results. Furthermore, the appropriate addition of P(VDF-HFP) can directly reduce the ignition energy threshold and increase the combustion time, which is necessary for the potential ignition charge application. The possible reasons for above phenomena are discussed and analyzed. This research provides a reference for improvement of thermite-based ignition charge formulation.