基于敏感性分析和准稳态假设简化详细反应机理

发展了一套基于敏感性分析和准稳态假设来简化复杂化学动力学机理系统的方法。采用等压均相反应器燃烧模型和详细化学动力学机理计算特定工况下的自燃过程。通过对详细机理计算结果的敏感性分析后删除其中的冗余组分和冗余反应,简化得到基干反应模型。再找出基干机理中反应速率较快,浓度较低的组分假定为稳态组分,使用准稳态假设方法简化得到总包反应模型。最后以甲烷燃烧的GriMech1.2详细机理为例分析得到了简化机理并计算了着火延迟时间,与详细机理所得的结果进行比较验证,得到了较好的结果。     

温升热源条件油气热着火关键因素探究

通过对影响油气受热着火的关键因素进行研究,为发展主动防护技术提供理论依据。基于系统的实验和分析,探究了快速氧化现象、热源加热速度、热源面积与爆燃空间比例对热着火发生时临界浓度、着火概率和着火延迟期的影响,提出了温升热源条件受限空间能否发生热着火的综合判据。该判据认为：如果油气体积分数低于2.4％,受限空间体积与热源面积比值小于0．64m,那么即使温度达到873K,湿度降低到18％～21％,着火也不会发生。     

基于敏感性分析的贫燃甲烷氧化反应简化机理

以GRIMECH 3.0详细反应动力学机理为基础,计算了贫燃甲烷氧化时各个基元反应对关键中间组分的生产与消耗贡献,并利用敏感性分析的方法研究了甲烷氧化过程中各基元反应对整体反应速率的贡献程度。在确定主反应路径的前提下,构建了包含16种组分,31步反应的甲烷氧化的简化反应动力学机理并与详细机理做了比较。该简化机理主要适用于当量比0.2以下的极端贫燃工况。     

利用敏感性分析方法简化的贫燃甲烷氧化反应机理

以grimech 3.0详细反应动力学机理为基础,计算贫燃甲烷氧化时各个基元反应对关键中间组分的生产与消耗的贡献,并利用敏感性分析的方法研究甲烷氧化过程中各基元反应对整体反应速率的贡献程度。在确定主反应路径的前提下,构建包含16种组分、31步反应的甲烷氧化的简化反应动力学机理,并与详细机理做比较。该简化机理主要适用于当量比在0.2以下的极端贫燃工况。     

半封闭空间钨丝点燃油气特性研究

为研究钨丝点燃油气着火爆炸特性,建立了半封闭容器着火爆炸实验平台。通过高速摄影仪拍摄的火焰传播过程,研究不同油气体积分数下的着火模式。根据高频动态压力传感器采集的容器内压力变化情况,分析不同油气体积分数下的着火规律。结果表明,着火模式有燃烧、爆炸和爆燃后持续燃烧3种;爆炸和爆燃后持续燃烧都会形成"压力双峰"现象,而燃烧只产生1个压力峰值;不同着火模式的反应总时间、最大压力上升速率和下降速率均存在突变现象;油气着火爆炸过程中,火焰和压力波之间形成了强烈的耦合作用。     

液氧甲烷膨胀循环变推力发动机系统方案对比研究

当前对液氧甲烷膨胀循环变推力火箭发动机的研制难点和关键技术认识不够清楚,尤其是在大变比推力调节方案方面。基于整个发动机系统,采用理论计算方法,探讨甲烷膨胀做功能力以及变推力调节方案可行性。分别给出了单涡轮系统方案和双涡轮系统方案,首次给出了不同工况下详细的系统状态参数分布,进行了对比分析,并探讨了甲烷做功能力随室压的变化规律。研究结果表明,甲烷做功能力随着室压的减小呈现先减小后增大的趋势,单涡轮和双涡轮系统方案均能够实现大范围推力调节;相比单涡轮方案,双涡轮方案能够更好地保证混合比,且甲烷气体做功能力利用效率更高,氧涡轮和燃料涡轮功率变化范围较窄,涡轮所处环境较为缓和,因此双涡轮系统方案具备一定优势。     

F—K理论在堆积固体自燃火灾调查中的应用

堆积固体自燃火灾是常见多发火灾，由于其规模庞大、着火延迟期长等特点，难以进行全尺寸的模拟实验，为火灾预防和调查工作带来了一定的难度。基于F—K（Frank—Kamenetskii）理论，将小规模实验结果外推，从而预测或判断一定尺寸的堆积固体在一定的环境温度下自燃起火的危险性。     

热壁条件下油气热着火关键因素探究

设计了受限空间内高温热壁条件下的油气热着火的实验系统.基于系统的实验和分析,探究了受限空间环境温度、湿度、压力、热壁温度对油气热着火发生的影响.实验发现:油气热着火概率随着热壁温度和环境温度的升高、湿度的减小而增加;油气混合物在汽油自燃点附近开始快速化学反应,油气热着火的最低临界温度为783 K;油气热着火存在三角形的着火压力半岛,且着火压力下限随热壁温度升高而降低,着火压力上限随温度升高而提高.     

交叉激波湍流边界层干扰问题数值模拟

基于BANS方程,采用有限体积法离散计算区域,对流项使用Harten TVD格式进行流场求解,湍流部分应用Menter SST两方程湍流模型,建立了隐式LU-SGS方法的三维CFD计算程序,数值模拟了来流马赫数4.96条件下的18°×18°对称双楔产生的交叉激波/湍流边界层干扰问题,计算了不同剖面沿展向压强分布以及流场的详细结构,并将计算结果与相关文献的实验与计算结果进行了比较.     

提供有界延迟服务的网络结构

将来的计算机网络必须支持具有不同通信量和不同服务质量（ＱｏＳ）要求的应用，有界延迟服务保证所有应用包的延迟都不超过给定延迟上界。本文首先提出有界延迟实时服务网络的框架，详细说明了其关键部件的功能和工作原理，并阐述了分析它们性能的技术，最后讨论了设计有界延迟服务网络在性能与实现复杂性之间的折衷。     

The surface activation of boron to improve ignition and combustion characteristic

Boron is a very promising and highly attractive fuel because of high calorific value. However, the practical applications in explosives and propellants of boron have been limited by long ignition delay time and low combustion efficiency. Herein, nano-Al and graphene fluoride (GF) as surface activated materials are employed to coat boron (B) particles to improve ignition and combustion performance. The reaction heat of nano-Al coated B/KNO₃ and GF coated B/KNO₃ are 1116.83 J/g and 862.69 J/g, respectively, which are higher than that of pure B/KNO₃ (823.39 J/g). The ignition delay time of B/KNO₃ could be reduced through nano-Al coating. The shortest ignition delay time is only 75 ms for B coated with nano-Al of 8 wt%, which is much shorter than that of pure B/KNO₃ (109 ms). However, the ignition delay time of B/KNO₃ coated with GF has been increased from 109 to 187 ms. B coated with GF and nano-Al shown significantly influence on the pressure output and flame structure of B/KNO₃. Furthermore, the effects of B/O ratios on the pressure output and ignition delay time have been further fully studied. For B/KNO₃ coated with nano-Al and GF, the highest pressures are 88 KPa and 59 KPa for B/O ratio of 4:6, and the minimum ignition delay time are 94 ms and 148 ms for B/O ratio of 7:3. Based on the above results, the reaction process of boron coated with GF and nano-Al has been proposed to understand combustion mechanism.     

Research on 2D Model of Capillary Discharge Plasma

The physical process of capillary discharge in a PE tube utilized in electro-thermal-chemical(ETC)guns was investigated.ETC guns can enhance the ignition and combustion of propellant in order to reduce the ignition delay and increase muzzle velocity of the projectile.A key component in ETC gun is the capillary plasma source.In this paper,a 2D steady state model of discharge was built by using magnetic hydrodynamics method.It took the plasma energy balance,material ablation,mass and momentum conservations in a quasi-neutral plasma region into account.Also,the effect of different compositions and PE concentration distribution were considered.In order to evaluate the validation of this model,the simulation results are compared with former works.     

切向空气气流对激光辐照碳纤维复合材料的影响

实验研究了靶材表面存在和不存在切向空气气流时,975nm连续激光对碳纤维增强树脂基复合材料的辐照效应,发现切向气流的加载有利于激光对碳纤维复合材料的破坏.从理论上对激光辐照下碳纤维复合材料的破坏机理进行了初步分析,基于碳的氧化特性和氧化反应机理,推导了碳纤维的氧化速率方程.采用改进的光滑粒子方法,对激光辐照下复合材料树...     

A novel launch dynamics measurement system for multiple launch rocket system and comparative analysis with numerical simulations

In this paper,a novel launch dynamics measurement system based on the photoelectric sensor pair is built.The actual muzzle time(i.e.a time duration that originates from the initial movement to the rocket's departure from the muzzle)and the muzzle velocity are measured.Compared with the classical methods,the actual muzzle time is obtained by eliminating the ignition delay.The comparative analysis method is proposed with numerical simulations established by the transfer matrix method for multibody systems.The experiment results indicate that the proposed measurement system can effectively measure the actual muzzle time and reduce the error of classical methods,which match well with the simulation results showing the launch dynamics model is reliable and helpful for further analysis and design of the MLRS.     

Numerical and experimental study on the response characteristics of warhead in the fast cook-off process

The response characteristics of the warhead under thermal stimuli conditions are important to the safety improvement. The goal of this study is to obtain data on the warhead in the fast cook-off process. In this paper, a numerical calculation method is proposed, whose reliability is supported by comparison with experimental results. Through the numerical calculation, the temperature distribution, temperature change, and ignition time are acquired. The numerical results show that the ignition time is 76 s after the warhead started to burn and that the maximum temperature of the explosive's outer surface is 238.3 C at the ignition time. The fast cook-off experiment of the warhead is implemented so as to get the flame temperature and reaction grades that are not available through numerical calculation. The experimental results show that the overpressure fails to reach the preset minimum value which is equivalent to 6 kg of TNT and that the reaction grade is deflagration. The research results have reference value for the design of the warhead and the reduction of detonation risks.