全文获取类型
收费全文 | 866篇 |
免费 | 206篇 |
国内免费 | 35篇 |
出版年
2024年 | 3篇 |
2023年 | 6篇 |
2022年 | 18篇 |
2021年 | 37篇 |
2020年 | 45篇 |
2019年 | 8篇 |
2018年 | 12篇 |
2017年 | 28篇 |
2016年 | 12篇 |
2015年 | 42篇 |
2014年 | 45篇 |
2013年 | 49篇 |
2012年 | 61篇 |
2011年 | 87篇 |
2010年 | 68篇 |
2009年 | 78篇 |
2008年 | 74篇 |
2007年 | 77篇 |
2006年 | 44篇 |
2005年 | 58篇 |
2004年 | 28篇 |
2003年 | 21篇 |
2002年 | 37篇 |
2001年 | 33篇 |
2000年 | 30篇 |
1999年 | 16篇 |
1998年 | 14篇 |
1997年 | 18篇 |
1996年 | 11篇 |
1995年 | 10篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有1107条查询结果,搜索用时 265 毫秒
151.
152.
To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C60 and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C60 compounds through Prato reaction. Their structures were characterized by UV–vis, 1H NMR, 13C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C60. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C60, which is consistent with the results of stabilization effect performance test. 相似文献
153.
Chain damage is a new phenomenon that occurs when a reactive jet impacts and penetrates multi-spaced plates.The reactive jet produces mechanical perforations on the spaced plates by its kinetic energy(KE),and then results in unusual chain rupturing effects and excessive structural damage on the spaced plates by its deflagration reaction.In the present study,the chain damage behavior is initially demonstrated by experiments.The reactive liners,composed of 26 wt%Al and 74 wt%PTFE,are fabricated through a pressing and sintering process.Three reactive liner thicknesses of 0.08 CD,0.10 CD and 0.12 CD(charge diameter)are chosen to carry out the chain damage experiments.The results show a chain rupturing phenomenon caused by reactive jet.The constant reaction delay time and the different penetration velocities of reactive jets from liners with different thicknesses result in the variation of the deflagration position,which consequently determines the number of ruptured plates behind the armor.Then,the finite-element code AUTODYN-3D has been used to simulate the kinetic energy only-induced rupturing effects on plates,based on the mechanism of behind armor debris(BAD).The significant discrepancies between simulations and experiments indicate that one enhanced damage mechanism,the behind armor blast(BAB),has acted on the ruptured plates.Finally,a theoretical model is used to consider the BAB-induced enhancement,and the analysis shows that the rupturing area on aluminum plates depends strongly upon the KE only-induced pre-perforations,the mass of reactive materials,and the thickness of plates. 相似文献
154.
新装备不经部队试用就批量生产交付部队使用,是导致新装备质量水平低、长期不能形成保障能力的重要原因之一。开展部队试用是提高新装备的质量与可靠性水平,促进新装备尽快形成作战、保障能力的重要途径之一。分析了开展新装备部队试用工作的必要性,探讨了新型装甲装备部队试用的基本任务,并对如何开展装甲新装备部队试用工作提出了几点建议。 相似文献
155.
三坐标雷达目标真实高度估计算法研究 总被引:1,自引:0,他引:1
在目标跟踪领域,通过三坐标雷达的测量值(斜距、仰角及方位角)来估算目标的真实高度一直是个难点。目前主要有两类处理方法:坐标转换法和等效地球半径法。前者把与雷达天线相关的三坐标测量值转换到大地坐标系统来计算目标高度;后者充分考虑地球曲率以及大气折射的特性,通过增加地球半径来估算目标的高度。最后对上述的两类方法进行总结、比较与分析。 相似文献
156.
集成电路方波脉冲注入损伤效应实验研究 总被引:3,自引:0,他引:3
为了得到各损伤参数随脉宽的变化规律,寻找建立评价复杂EMP波形对集成电路损伤模型的依据,对2种典型的集成电路器件进行了方波脉冲注入损伤实验。结果表明:RAM6264损伤电压、电流及功率均随脉宽增大而减小,损伤能量处于某一小范围之内,可能属于能量损伤型器件;BG305损伤电压、功率随脉宽增大而减小,损伤能量随脉宽增大而增大,损伤电流处于某一个小范围之内,可能属于电流损伤型器件。 相似文献
157.
避雷针保护范围的图形仿真与图解法分析 总被引:1,自引:0,他引:1
针对避雷针设计过程中计算公式过于复杂的问题,提出了利用平面几何作图求解避雷针联合保护范围的方法,给出了单支、双支和四支避雷针保护范围的作图解题步骤,并利用计算机图形仿真,给出了避雷针保护范围的空间结构图形。 相似文献
158.
159.
160.
粗糙集中不确定性测量的修正粗糙熵方法 总被引:1,自引:0,他引:1
分析了引起粗糙集中不确定性的因素,对已有的测量不确定性的粗糙度与粗糙熵方法进行了比较,提出了一种修正的粗糙熵方法,证明了此粗糙熵的性质,并将基于等价关系的修正粗糙熵拓展到基于一般二元关系下的广义修正粗糙熵,同时给出了广义修正粗糙熵的定义及性质.通过分析和实例可以看出,所提出的修正粗糙熵方法可以用来更合理、更精确地测量粗糙集中的不确定性. 相似文献