Vapor-phase decomposition of dimethyl methylphosphonate (DMMP), a sarin surrogate,in presence of metal oxides

Chemical warfare agents (CWA) are stockpiled in large quantities across the globe. Agents stored in inaccessible facilities need to be destroyed rapidly without dispersing the compounds to surrounding areas. Metal-based energetic formulations are used in such prompt defeat applications to rapidly decompose the CWA by generating a high temperature environment. An alternate, and possibly a more effective decomposition pathway could be provided by chemicidal action of aerosolized condensed combustion products, which typically consist of metal oxides. Toxic fumes that escape the high tem-perature blast zone can be neutralized by smoke generated during combustion, depending on the par-ticle size, surface characteristics, chemical properties, and concentration of this smoke. This review considers relevant experimental and modeling studies quantifying decomposition of CWA comprising organophosphorus compounds and their surrogates on the surface of various metal oxides. Dimethyl methylphosphonate (DMMP), a sarine surrogate, was used most commonly for such experiments. Many reported efforts focused on the mechanisms of adsorption of DMMP to various metal oxides and initial reaction steps cleaving various bonds from the chemisorbed molecules. For selected oxides, these ex-periments were supported by quantum-mechanical calculations. In other studies, the capacity of oxide surfaces to adsorb and decompose DMMP was quantified. In most cases, porous catalysts were used although limited experimental data are available for aerosolized nonporous oxide particles. The reported experimental data applicable to scenarios involving prompt decomposition of CWA are summarized. It is noted that information is lacking describing respective heterogeneous reaction kinetics. Preliminary estimates of aerosolized smoke particle concentrations required to destroy CWA are made considering gas phase diffusion rates and reported values of the oxide capacity to decompose CWA or their surrogates.     

一种适用于非合作源雷达的波束形成技术

非合作源雷达要完成对运动目标的检测,必须能够有效地抑制强烈的直达波信号。常规的波束形成方法在存在阵元误差的情况下,其性能将显著下降。提出的数值式波束形成算法既可以实现误差校正,又能在已知的干扰方向上形成较深的零陷,且能保持主瓣的形状和限制副瓣的响应。     

一种基于串联谐振型变换器的激光电源设计

激光器电源是激光器装置的重要组成部分,其泵浦方式分为光激励、放电激励、能量激励等,均必须配有相适应的供电电源。基于脉冲式固体激光器中负载是气体放电器件的激光电源,设计了一种带有预燃放电功能的半桥LCC串联谐振逆变电路,可实现每次点灯不必使用高压触发脉冲,避免触发高压的电磁辐射干扰。使得当灯处于低阻状态时,电容器上的能量能更有效地转换成光能。整体电源设计结构简单,可靠性高,可满足激光器对电源稳态工作的要求,在应用预燃电路后,激光输出能量可提高10%。     

考虑维修时间不确定性的维修任务选择模型

由于维修时间存在不确定性,如何在考虑维修时间不确定性的情况下确定任务间隔期的维修方案是一个值得探讨的问题.给出了一种考虑维修时间不确定性的维修任务选择模型及其求解算法,以在一定置信水平下获得最佳的维修方案.首先,给出了考虑维修时间不确定性的维修任务选择问题的假设条件,并建立了一种非线形的、离散的机会约束规划.其次,给出了一种基于随机模拟的粒子群求解算法,包括粒子的表示、适应度函数、更新公式、算法框架等.最后,给出了具体实例,证明了模型与算法的有效性.该模型非常适用于管理人员在维修时间存在不确定性的情况下作出合理的维修任务选择决策.     

基于关联离散度的目标类型识别方法

针对空中作战空中目标识别问题,在分析影响目标类别因素的基础上,提出了一种基于关联离散度的空中目标灰色识别方法。该方法采用灰色理论,通过应用定义的关联离散度作为识别测度,因而在无需对现役雷达作太多技术改进的情况下,就可以提高低分辨雷达对空中目标粗略分类的自动判别能力。给出了应用该方法的具体步骤,通过仿真实例证明该算法的有效性。     

磨合预处理对有机钼添加剂摩擦学性能的影响

采用MMW-1万能摩擦磨损试验机,考察了磨合预处理工况(时间、载荷)对两种有机钼添加剂在CF-4 15W-40柴油机油中抗磨减摩性能的影响。采用扫描电子显微镜和能谱仪分析了磨斑表面形貌和表面元素组成。结果表明,适当的磨合预处理可有效增强有机钼添加剂在柴油机油中的抗磨减摩性能,且经过磨合预处理的磨斑表面形貌较没有处理时平整,添加剂主要功能元素在摩擦表面的质量分数增加。     

一种改进的跳频信号频率估计算法

信号的信噪比较低时,旋转不变信号参数估计技术（Estimated Signal Parametersvia Rotational Invariance Technique,ESPRIT）算法的频率估计性能明显下降,针对这一问题,提出了一种基于ESPRIT的改进算法。该改进算法在基于ESPRIT的噪声抑制（Noise Suppressed based on ESPRIT,NS—ESPRIT）算法的基础上,利用DFT谱中的,个局部最大值点,缩小基于互相关矩阵迹模值曲线的ESPRIT算法中口的选择区域,在降低计算复杂度的同时,也有效地减弱了噪声对信号频率估计的影响。理论分析和仿真结果证明了该改进算法的可行性和有效性。     

基于STAGE平台的模型扩展方法

STAGE(Scenario Toolkit And Generation Environment)是用于开发想定战场环境和武器系统验证的仿真软件。用户可根据需求利用自己开发的仿真模型取代STAGE的内置仿真模型,也可以将开发的仿真模型与STAGE中现有模型进行集成。针对STAGE 6.0仿真开发平台,研究了STAGE模型扩展中的关键技术,实现了用户开发模型与STAGE仿真引擎的集成,从而为快速构建用户自定义战场环境提供了一种新途径。     

Modeling the operation of multireservoir systems using decomposition and stochastic dynamic programming

Stochastic dynamic programming models are attractive for multireservoir control problems because they allow non‐linear features to be incorporated and changes in hydrological conditions to be modeled as Markov processes. However, with the exception of the simplest cases, these models are computationally intractable because of the high dimension of the state and action spaces involved. This paper proposes a new method of determining an operating policy for a multireservoir control problem that uses stochastic dynamic programming, but is practical for systems with many reservoirs. Decomposition is first used to reduce the problem to a number of independent subproblems. Each subproblem is formulated as a low‐dimensional stochastic dynamic program and solved to determine the operating policy for one of the reservoirs in the system. © 2006 Wiley Periodicals, Inc. Naval Research Logistics, 2006     

巡航导弹强弱点分析及防御方法

巡航导弹具有突防能力强、命中精度高、灵活性强、技术上易于实现和造价低等优点而备受各个国家重视,已经发展成为现代战争的重要武器,是上世纪90年代以后的主要空中作战目标之一.对巡航导弹的强点与弱点进行了分析,并研究了防御巡航导弹的可行方法.