Influence of yttrium on microstructure and properties of Ni–Al alloy coatings prepared by laser cladding

Ni–Al alloy coatings with different Y additions are prepared on 45^# medium steel by laser cladding. The influence of Y contents on the microstructure and properties of Ni–Al alloy coatings is investigated using X-ray diffraction, scanning electron microscopy, electron probe microanalyzer, Vickers hardness tester, friction wear testing machine, and thermal analyzer. The results show that the cladding layers are mainly composed of NiAl dendrites, and the dendrites are gradually refined with the increase in Y additions. The purification effect of Y can effectively prevent Al₂O₃ oxide from forming. However, when the atomic percent of Y addition exceeds 1.5%, the extra Y addition will react with O to form Y₂O₃ oxide, even to form Al₅Y₃O₁₂ oxide, depending on the amount of Y added. The Y addition in a range of 1.5–3.5 at.% reduces the hardness and anti-attrition of cladding layer, but improves obviously its wear and oxidation resistances.     

Dynamic globularization prediction during cogging process of large size TC11 titanium alloy billet with lamellar structure

The flow behavior and dynamic globularization of TC11 titanium alloy during subtransus deformation are investigated through hot compression tests. A constitutive model is established based on physical-based hardening model and phenomenological softening model. And based on the recrystallization mechanisms of globularization, the Avrami type kinetics model is established for prediction of globularization fraction and globularized grain size under large strain subtransus deformation of TC11 alloy. As the preliminary application of the previous results, the cogging process of large size TC11 alloy billet is simulated. Based on subroutine development of the DEFORM software, the coupled simulation of one fire cogging process is developed. It shows that the predicted results are in good agreement with the experimental results in forging load and microstructure characteristic, which validates the reliability of the developed FEM subroutine models.     

Effect of post weld heat treatment on tensile properties and microstructure characteristics of friction stir welded armour grade AA7075-T651 aluminium alloy

This paper reports the effects of post weld heat treatments, namely artificial ageing and solution treatment followed by artificial ageing, on microstructure and mechanical properties of 12 mm thick friction stir welded joints of precipitation hardenable high strength armour grade AA7075-T651 aluminium alloy. The tensile properties, such as yield strength, tensile strength, elongation and notch tensile strength, are evaluated and correlated with the microhardness and microstructural features. The scanning electron microscope is used to characterie the fracture surfaces. The solution treatment followed by ageing heat treatment cycle is found to be marginally beneficial in improving the tensile properties of friction stir welds of AA7075-T651 aluminium alloy.     

基于模糊隶属函数的一类灰色关联度问题研究

针对系统特征序列与相关因素序列中数据不确定或存在区间取值的问题,基于模糊隶属函数提出了一种解决灰色关联分析中关联度确定的方法,并以实例说明了该方法的合理性.     

高速电弧喷涂FeCrBSiMnNbW非晶纳米晶涂层组织及性能

研究开发了一种FeCrBSiMnNbW新型喷涂粉芯丝材,并采用自动化高速电弧喷涂技术在镁合金基体上制备了FecrBsiMnNbw非晶纳米晶涂层。对Fe基非晶纳米晶涂层和传统的3Cr13涂层的组织结构、力学性能以及油润滑条件下的摩擦学性能进行了对比分析,结果表明：与3Cr13涂层相比,铁基非晶纳米晶涂层组织更加致密,孔隙率低,具有相对较高的硬度和拉伸结合强度;形成了非晶相和纳米晶相组成的复合结构,使得涂层具备更好的摩擦学性能。     

AZ91D镁合金表面纳米TiO_2复合微弧氧化层耐蚀性能研究

为了提高AZ91D镁合金微弧氧化陶瓷层的耐蚀能力,采用Na2SiO3电解液,添加入纳米TiO2,经微弧氧化,纳米TiO2颗粒复合入陶瓷层中,形成表面质量良好的纳米复合陶瓷质氧化膜。通过与普通微弧氧化陶瓷层比较,结果表明：纳米TiO2复合微弧氧化陶瓷层孔隙率降低,致密性提高,抗盐雾腐蚀性能提高1倍以上。     

外加电位条件下7A52铝合金应力腐蚀开裂敏感性研究

摘要：采用电化学极化手段和慢应变速率拉伸试验,结合扫描电镜观察合金断口形貌,研究了外加电位对7A52铝合金应力腐蚀开裂敏感性的影响。研究结果表明：合金在3．5％NaCl溶液中的应力腐蚀开裂敏感性与外加电位有强烈的相关性,开裂敏感性在外加电位为一0．95V时最低,外加电位起到阴极保护的作用;在外加电位为一1V时有所升高,但仍然低于开路电位条件下的敏感性;在一1．1V时最高,应力腐蚀过程以氢脆为主;在一1．2V时又有所降低,阴极析出的氢以气态逸出而降低应力腐蚀开裂敏感性。     

新型航空铝合金材料复杂形貌点蚀损伤应力集中效应分析

根据7B04铝合金材料试件模拟加速点蚀试验检测结果,并结合铝合金材料点蚀行为机制、微观结构特征与随机性过程本质,构建由多个微观椭球体合成的楔入型与合围型两种典型复杂形貌点蚀损伤模型。采用ANSYS有限元方法建模并基于线弹性断裂力学,对上述两种点蚀损伤模型的应力集中效应进行计算与分析。研究发现:两种复杂形貌特征的点蚀损伤模型产生的应力集中系数数值基本相当,各个微观椭球体蚀坑分别对应力分布产生影响并相互干涉与叠加,造成复杂形貌点蚀损伤模型的应力集中系数数值增大;两种复杂形貌点蚀损伤模型的应力主要集中在各个微观椭球体蚀坑交会的位置,大都位于宏观点蚀损伤的侧边;两种复杂形貌点蚀损伤模型的应力集中效应作用区域的尺寸与铝合金材料微观晶粒尺寸、点蚀萌生的短裂纹初期尺寸基本相当。     

基于马尔科夫链的一种评价方法

应用了数理统计与随机过程理论,从分析动态系统的状态以及状态转移情况给出了一种合理的评价方法,经过实例验证,该方法效果较好.     

磁性合金A1-xBx相图的理论计算

采用变分累积展开方法,研究了块体磁性合金的相图.利用随机键海森堡模型计算了面心立方、体心立方的居里点和耐尔点,给出了磁性合金临界点的计算公式,进而分别给出自旋1/2和3/2情况下Tc-x相图,并加以分析.