树脂浸渍裂解对气相硅反应渗透C/SiC的影响

粘胶基碳纤维毡经过CVD工艺进行沉积碳增密处理后,采用酚醛树脂浸渍—裂解对C/C素坯的密度进行调节,通过气相硅渗透反应工艺制备了C/SiC复合材料。研究了树脂浸渍—裂解对C/C素坯密度和气孔率的影响规律,分析了树脂裂解碳对C/SiC显微形貌和力学性能的影响。结果表明:随着树脂浸渍—裂解循环次数的增加,素坯密度增加,孔隙率降低;裂解碳含量为27wt%时,C/SiC复合材料的强度和模量达到最大,分别为231MPa和209GPa。通过控制裂解碳含量,可以实现对C/SiC复合材料力学性能和微观结构的裁剪。     

Effect of nano powder (Al2O3-CaO) addition on the mechanical properties of the polymer blend matrix composite

This work describes the preparation and study of the properties of composite nanoparticles prepared by the sol-gel method which consists of two materials (Al₂O₃-CaO), and study the effect of these nanoparticles on the mechanical behavior of a polymer blend (EP 4% + 96% UPE). The powder was evaluated by X-ray diffraction analysis, scanning electron microscopy analysis (SEM), particle size analysis, and energy dispersive X-ray analysis (EDX). The mechanical behavior of the composite material was assessed by tensile test, bending test and hardness test. The evaluation results of the composite nanoparticles showed good distribution of the chemical composition between aluminum oxide and calcium oxide, smoothness in particles' size at calcination in high and low temperatures, formation of different shapes of nanoparticles and different (kappa and gamma) phases of the Al₂O₃ particles. The results of mechanical behavior tests showed marked improvement in the mechanical properties of the resulted composite material, especially at 1.5%, compared with polymer blend material without nano powder addition. The tensile properties improved about (24 and 14.9) % and bending resistance about (23.5 and 16.8) % and hardness by (25 and 22) % when adding particles of size (63.8 and 68.6) respectively. Therefore, this reflects the efficiency of the proposed method to manufacture the nanocomposite powder and the possibility of using this powder as a strengthening material for the composite materials and using these composite materials in bio applications, especially in the fabrication of artificial limbs.     

The effect of sintering and cooling process on geometry distortion and mechanical properties transition of PTFE/Al reactive materials

In this research, the effect of the sintering and cooling process on geometry distortion and mechanical properties of PTFE/Al reactive material is investigated. Six particularly selected sintering temperatures, three different cooling modes (annealing cooling, normalizing cooling and rapid cooling), three different initial cooling temperatures, as well as six different final cooling temperatures were designed to compare the effects of sintering temperature, cooling rate, initial cooling temperature and final cooling temperature on the properties of reactive materials. Geometry distortion was quantitatively analyzed by a statistic on the dimensional changes of the specimens and microscopic morphology. A mechanical response properties transition from brittle to ductile was found and analyzed. By combining the thermodynamic properties of PTFE and unsteady heat conduction theory, mechanisms of cooling induced morphology change, temperature induced distortion and strength decrease were obtained. The results showed that the cooling rate has the most significant effect on the morphology transformation, while initial cooling temperature has more significant effect on the dimensional distortion than final cooling temperature. As to the mechanical properties transition from brittle to plastic, a more prominent effect of initial cooling temperature than cooling rate and final temperature was revealed.     

复合固体推进剂等效力学性能VCFEM细观预示方法

根据固体推进剂的细观结构特征,采用等圆最优装载方式生成代表性体积单元(Representative Volume Element,RVE)模型,并结合Voronoi单元有限元方法(Voronoi Cell Finite Element Method,VCFEM)和均匀化方法,发展了一种可预示固体推进剂等效力学性能的数值分析方法,从而得到体分比和组分材料对等效模量和等效泊松比的影响规律。为证明该方法的有效性,设计一个对称数值模型,通过对该方法和传统有限元方法的节点位移结果的比较,发现两者之间的相对误差小于5%,且VCFEM用少量单元就完成了分析,提高了计算效率。通过对不同细观结构下推进剂RVE模型的计算,发现随着夹杂体分比的增大,夹杂的颗粒增强效应越明显,基体材料的变化比夹杂材料对等效力学性能有着更加显著的影响。     

感烟火灾探测器响应模拟问题研究

通过介绍感烟火灾探测器响应模拟的不同方法,给出了感烟火灾探测器响应模拟所存在的问题及在设计安装过程中所需的性能参数,提出了解决这些问题的思路和方法。同时为进一步提高感烟火灾探测器对火灾信号的准确响应,指出了今后火灾中烟气性能参数的研究方向。     

安静型夹芯复合材料舵设计及其力学性能分析

通过对夹芯复合材料各层材料的选择,以及夹芯复合材料舵壳的结构设计,提出了夹芯复合材料舵的设计方案和制作工艺。并利用有限元方法计算了复合材料舵壳在流体压力作用下的应力和变形,以及在瞬态载荷作用下舵壳的振动响应。计算结果表明,夹芯复合材料舵壳满足结构的强度和刚度的要求,同时振动水平与钢舵比较有很大的改善。     

碳化硼涂覆的碳纤维的抗热氧化性研究

用自己合成的裂解能得到碳化硼的聚碳硼烷,对碳纤维进行涂层,并详细测试了涂层碳纤维的抗热氧化性能。     

UHMWPE纤维混凝土基本力学性能研究

研究了一种由超高分子量聚乙烯（UHMWPE）纤维增强的新型纤维混凝土基本力学性能。针对C70等级高强混凝土,设计了四种体积掺量纤维混凝土,通过立方体抗压、劈裂抗拉和四点弯曲抗折试验,分析了纤维掺量对混凝土力学性能的影响。结果表明：UHMWPE纤维对混凝土的抗压强度增强作用不明显,但较大提高了混凝土的抗拉强度和抗折强度,且对混凝土有很好的阻裂、增韧效果。在纤维体积掺量为0.3%~0.5%时,劈裂抗拉强度提高25%以上;掺量0.5%时,弯曲抗折强度提高率超过23%。     

纳米二氧化硅增强硬质聚氨酯泡沫塑料的制备

采用功率超声,将纳米二氧化硅颗粒分散到多次甲基多苯基多异氰酸酯体系内,然后与聚醚多元醇聚合制得了纳米二氧化硅增强的硬质聚氨酯泡沫塑料。SEM分析表明,纳米二氧化硅均匀分散在聚氨酯泡沫中。在较低添加量时,纳米二氧化硅使压缩强度和冲击强度有一定提高,但会引起多次甲基多苯基多异氰酸酯粘度迅速增加,从而导致发泡反应困难,当添加量为7wt%时,压缩强度和冲击强度开始下降。     

Mechanical behavior and failure mechanism of polyurea nanocomposites under quasi-static and dynamic compressive loading

Polyurea is an elastomeric material that can be applied to enhance the protection ability of structures under blast and impact loading.In order to study the compressive mechanical properties of SiC/polyurea nanocomposites under quasi-static and dynamic loading,a universal testing machine and split Hop-kinson pressure bar(SHPB)apparatus were used respectively.The stress-strain curves were obtained on polyurea and its composites at strain rates of 0.001-8000 s-1.The results of the experiment suggested that increase in the strain rates led to the rise of the flow stress,compressive strength,strain rate sensitivity and strain energy.This indicates that all of the presented materials were dependent on strain rate.Moreover,these mechanical characters were enhanced by incorporating a small amount of SiC into polyurea matrix.The relation between yield stress and strain rates were established using the power law functions.Finally,in order to investigate the fracture surfaces and inside information of failed specimens,scanning electron microscopy(SEM)and micro X-ray computed tomography(micro-CT)were used respectively.Multiple voids,crazes,micro-cracks and cracking were observed in fracture surfaces.On the other hand,the cracking propagation was found in the micro-CT slice images.It is essential to understand the deformation and failure mechanisms in all the polyurea materials.