An interface shear damage model of chromium coating/steel substrate under thermal erosion load

The Cr-plated coating inside a gun barrel can effectively improve the barrel's erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gun-powder,micro-element damage tends to occur within the Cr coating/steel substrate interface,leading to a gradual deterioration in macro-mechanical properties for the material in the related region.In order to mimic this cyclic thermal load and,thereby,study the thermal erosion behavior of the Cr coating on the barrel's inner wall,a laser emitter is utilized in the current study.With the help of in-situ tensile test and finite element simulation results,a shear stress distribution law of the Cr coating/steel substrate and a change law of the interface ultimate shear strength are identified.Studies have shown that the Cr coating/steel substrate interface's ultimate shear strength has a significant weakening effect due to increasing temperature.In this study,the interfacial ultimate shear strength decreases from 2.57 GPa(no erosion)to 1.02 GPa(laser power is 160 W).The data from this experiment is employed to establish a Cr coating/steel substrate interface shear damage model.And this model is used to predict the flaking process of Cr coating by finite element method.The simulation results show that the increase of coating crack spacing and coating thickness will increase the service life of gun barrel.     

陶瓷/金属梯度热障涂层的制备及性能评价

为了评价陶瓷/金属梯度热障涂层的性能,设计了4种涂层方案和2种基体材料(1Cr18Ni9Ti和2Cr13).利用单枪单送粉器成功地制备了线性梯度涂层.通过观察涂层的微观结构、测量涂层的抗热震性能和热残余应力来评价涂层的性能.利用扫描电镜对各种陶瓷涂层的微观结构进行了观察和分析,利用X射线能谱分析得到了陶瓷梯度涂层试样中的不同区域的衍射图.热震试验表明,梯度涂层比非梯度涂层具有更好的抗热震性能.采用钻孔法对不同涂层方案进行了残余应力的测量,结果表明,压应力出现在1Cr18Ni9Ti基体材料上,而拉应力出现在2Cr13基体材料上.     

热障涂层厚度及其涂敷下材料内部缺陷的红外定量识别

针对热障涂层结构材料红外定量检测存在的不足,提出基于脉冲相位的LM(LevenbergMarquardt)识别算法。针对研究问题,建立了轴对称圆柱坐标下热障涂层结构材料的瞬态导热模型,利用有限体积法计算出检测表面的温度场,经快速傅里叶变换得到检测表面的相位分布,分析待检测参数对检测表面相位差的影响。以相位为识别条件,采用LM反演算法对热障涂层厚度及其涂敷下材料内部缺陷位置大小进行定量识别,并采用数值实验方法验证了基于相位的LM识别方法的有效性。     

铝合金表面涂覆隐身吸波涂层脱落原因分析

通过对某装备车体外脱落隐身吸波涂层样品的表面形貌、截面形貌、元素组成及含量分析,发现吸波涂层和Al2O3钝化层之间没有化学结合键,只存在物理吸附和机械结合,在外部环境的作用下,很容易引起隐身吸波涂层的脱落。     

SiC纤维表面CVD SiC涂层对其单丝强度的影响

采用化学气相沉积(CVD, Chemical Vapor Deposition)工艺在KD-I型SiC纤维表面制备了SiC涂层,选择2h、4h、6h和8h四个时间点研究了沉积时间对纤维性能的影响.结果表明:具有CVD SiC涂层的SiC纤维较无涂层的纤维来说强度有所下降;在所研究的沉积时间范围内,随着沉积时间的增加,涂层的厚度有所增加,涂层由不连续的岛状转变为连续层状,纤维的单丝强度出现了先升后降的趋势.     

自蔓延反应喷涂表面涂层技术进展

围绕自蔓延反应喷涂技术与工艺研究和自蔓延反应喷涂相关理论研究两个方面,介绍了这一技术领域的发展状况。SHS反应喷涂技术将燃烧合成与传统热喷涂相融合,将各类高化学能的反应型粉材、线材引入喷涂技术中制备高性能陶瓷和金属间化合物涂层,发展了SHS反应药芯线材电弧喷涂、SHS等离子喷涂、爆炸反应喷涂以及SHS反应火焰喷涂等技术手段。一方面,对其中的配系设计、控制参数、涂层性能和相关设备等方面开展了深入的实验研究;另一方面,围绕涂层形成过程、喷涂条件下的反应机理与模式,以及反应喷涂过程中的能量状态和粒子的物理状态等方面开展了初步的理论研究,正在构筑较完整的理论体系。     

铁红环氧酯涂层中缓蚀剂的研究

在有机涂层中加入缓蚀剂构成耐蚀涂层,可以进一步提高原涂层的耐蚀能力。本文研究了一种缓蚀剂HN(由H和N复配而成,H为杂环类,N为胺类),用在普通涂层—铁红环氧酯中试验。采用了四种方法:电化学交流阻抗法,盐雾箱试验法,人造海水浸泡,海上实船挂片,并分别与未加缓蚀剂的原涂层进行对比,对各涂层的耐蚀性能进行评定。结果表明:在铁红环氧酯中加入少量HN缓蚀剂后,在不改变原涂层附着力的情况下,明显提高了原涂层的耐蚀能力。     

聚氨酯防腐涂料综述

介绍了聚氨酯防腐涂料的种类、成分及其性能,并与现有的防腐涂料进行了比较。     

碳化硼涂覆的碳纤维的抗热氧化性研究

用自己合成的裂解能得到碳化硼的聚碳硼烷,对碳纤维进行涂层,并详细测试了涂层碳纤维的抗热氧化性能。     

Preparation and characterization of HMX/NH2-GO composite with enhanced thermal safety and desensitization

To improve the safety of HMX, HMX/NH₂-GO composite was prepared with aqueous ammonia functionalized graphene oxide (NH₂-GO). The composite was characterized by SEM, Zeta potential, XPS, Raman spectrum, XRD, HPLC, DSC and BAM sensitivity test. The results indicated that the functionalization with aqueous ammonia can enhance the interaction between GO and HMX, and more efficiently desensitize the explosive. The optimal impact sensitivity of the HMX/NH₂-GO composite can be not less than 40 J, which is also the most insensitivity compared to the previous reports prepared by coating desensitization with non-energetic desensitized material. Moreover, the potential reason for the different impact and friction sensitivity was also discussed, which may bring a novel perspective to achieve the desensitization of energetic material.