Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

An interface shear damage model of chromium coating/steel substrate under thermal erosion load

The Cr-plated coating inside a gun barrel can effectively improve the barrel's erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gun-powder,micro-element damage tends to occur within the Cr coating/steel substrate interface,leading to a gradual deterioration in macro-mechanical properties for the material in the related region.In order to mimic this cyclic thermal load and,thereby,study the thermal erosion behavior of the Cr coating on the barrel's inner wall,a laser emitter is utilized in the current study.With the help of in-situ tensile test and finite element simulation results,a shear stress distribution law of the Cr coating/steel substrate and a change law of the interface ultimate shear strength are identified.Studies have shown that the Cr coating/steel substrate interface's ultimate shear strength has a significant weakening effect due to increasing temperature.In this study,the interfacial ultimate shear strength decreases from 2.57 GPa(no erosion)to 1.02 GPa(laser power is 160 W).The data from this experiment is employed to establish a Cr coating/steel substrate interface shear damage model.And this model is used to predict the flaking process of Cr coating by finite element method.The simulation results show that the increase of coating crack spacing and coating thickness will increase the service life of gun barrel.     

基于RTP协议H．264视频流传输QoS保证的研究

提出一个Linux环境下基于RTP/RTCP的H.264视频流传输的方案,在Linux中调用V4L(VideofourLinux)的API函数采集视频流,经X264压缩,RTP/RTCP协议打包进行传输。并通过RTCP的RR(接收方报告)包反馈信息和吞吐量公式来计算近似带宽,以起始帧量化参数start-qp为视频编码的调节参数,由近似带宽来控制视频编码的参数调整,达到控制输出码率的目的,实现对视频传输的QoS(QualityofService)保证。     

基于到达时差法的目标定位系统

运用声被动定位理论探索空中目标的定位问题。建立了一种平面波声被动定位模型,利用简易被动声传感器阵列,分析并设计了定位系统的总体结构。提出了一种简易的计算到达时差电路设计方案,此电路利于目标的实时定位。在利用这种系统定位远距离目标时,可消除有效声速的影响。最后给出了几组实验结果,证明了此系统的可行性,但对近距离目标的定位结果较差,模型需进一步研究。     

弹道导弹打击航空母舰末制导有效区的确定与评估

在地地弹道式导弹与航空母舰攻防对抗中,需要研究航母是否在导弹进攻的有效区内。针对具有末制导的弹道式导弹具有再入机动变轨特性,建立了导弹再入机动飞行模型,提出了导弹在不同的再入条件下,对其飞行弹道及机动能力进行仿真计算的方法,通过仿真确定出了导弹打击航空母舰的有效区域。在此基础上,探讨了导弹在以不同的再入姿态、不同的再入飞行高度实施末制导时,导弹落点的有效区域、边界外形及有效区的变化范围。从所得结果来看,所建模型及仿真方法正确可行,在一定程度上解决了弹道导弹打击航空母舰战斗群作战保障急需解决的一些问题。     

三坐标雷达目标真实高度估计算法研究

在目标跟踪领域,通过三坐标雷达的测量值(斜距、仰角及方位角)来估算目标的真实高度一直是个难点。目前主要有两类处理方法:坐标转换法和等效地球半径法。前者把与雷达天线相关的三坐标测量值转换到大地坐标系统来计算目标高度;后者充分考虑地球曲率以及大气折射的特性,通过增加地球半径来估算目标的高度。最后对上述的两类方法进行总结、比较与分析。     

一种基于SOAP安全的网络中心发布/订阅机制

针对网络中心发布/订阅系统异步、松散耦合和多对多通信等特点,采用了SOAP消息传递机制对信息进行了封装,从而屏蔽了信息的异构性。考虑到信息传输的可靠性,采用XML-Encryption机制构造SOAP消息,为消息交换和数据传输提供一种安全的保证。实际应用表明该系统在网络中心战中有较好的应用前景。     

聚硅氧烷先驱体转化制备2D Cf/Si-O-C材料

以二维碳纤维布和廉价的聚硅氧烷为原料,采用先驱体转化工艺制备2D Cf/Si-O-C材料,对其力学性能进行了考察,并与以聚碳硅烷为先驱体制备的2D Cf/SiC材料在价格和性能方面进行了对比。实验表明,2D Cf/Si-O-C材料力学性能较2D Cf/SiC材料有所下降,但成本大大降低。2D Cf/Si-O-C材料弯曲强度达到157.9 MPa,断裂韧性达到8.4MPa.m1/2,剪切强度达到23.4MPa,并且在1400℃下能较好保持材料的力学性能。     

Emergency transshipment in decentralized dealer networks: When to send and accept transshipment requests

While there has been significant previous literature on inventory transshipment, most research has focused on the dealers' demand filling decision (when to fill transshipment requests from other dealers), ignoring the requesting decision (when to send transshipment requests to other dealers). In this paper we develop optimal inventory transshipment policies that incorporate both types of decisions. We consider a decentralized system in which the dealers are independent of the manufacturer and of each other. We first study a network consisting of a very large number of dealers. We prove that the optimal inventory and transshipment decisions for an individual dealer are controlled by threshold rationing and requesting levels. Then, in order to study the impact of transshipment among independent dealers in a smaller dealer network, we consider a decentralized two‐dealer network and use a game theoretic approach to characterize the equilibrium inventory strategies of the individual dealers. An extensive numerical study highlights the impact of the requesting decision on the dealers' equilibrium behavior in a decentralized setting. © 2006 Wiley Periodicals, Inc. Naval Research Logistics, 2006     

近程反导中拦阻射击模式和多重命中体制研究

在近程反导中,片面强调提高高炮随动系统的跟踪瞄准速度,已经不现实,通过对拦阻射击模式的研究,探讨了采用多重命中体制弥补随动系统缺陷的可行性。