Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

Some aspects in estimating warranty and post‐warranty repair demands

When customers buy a product, they are often eligible for free repairs for a certain warranty period. In this article, we study some important aspects, which are often overlooked in the literature but are of interest to the manufacturer, in estimating both warranty and post‐warranty repair demands. We consider that the installed base of the product (i.e., the number of units of the product actually in use) varies with time due to both new sales and units being taken out of service. When estimating warranty and post‐warranty repair demands, we explicitly address the fact that customers may not always request repairs for failed units. For the case where the product failure time distribution is exponential, we derive the closed‐form expressions for both types of repair demands of a single unit and of the time‐varying installed base. The insights into some risk‐related quantities are also presented. Furthermore, the proposed model is extended by considering delayed warranty claims that are frequently seen in practice. Numerical examples illustrate that understanding both types of repair demands and the related decision variables is important for managing the obligatory and profitable repair services. © 2013 Wiley Periodicals, Inc. Naval Research Logistics 60: 499–511, 2013     

火炸药静电起爆最小发火能量测试方法研究

分析研究了测量火炸药静电起爆最小发火能量的三种方法,并进行了大量的对比试验,提出了首先进行OSTR法试验,然后进行逐步降压法试验,从而得出火炸药静电起爆的最小发火能量。     

电子战条件下雷达接收信号模型

文中建立了电子战条件下雷达信号环境数学模型,包括雷达发射信号数学模型,目标回波信号数学模型,电子干扰（有源干扰和无源干扰）信号数学模型,杂波数学模型以及噪声数学模型     

系统与应用相结合 加强科学计算研究

科学计算是计算机学科和应用学科交叉融合的产物。文章阐述了科学计算的内涵和作用,论述了其科学基础和关键技术,及其对高性能计算机技术的挑战,提出了从科学计算应用基础研究和艾级计算机关键技术研究着手,加强科学计算交叉研究和复合型人才培养的思考。     

潜艇线式巡逻的最佳对策研究

本文先用面积法求出线式巡逻潜艇发现目标的概率,然后对潜艇发现目标距离作了分析。在此基础上,建立了潜艇线式巡逻的矩阵对策模型,并用计算机对此模型进行求解,得到了潜艇线式巡逻的最佳对策。最后,对最佳对策作了讨论。本文建立的矩阵对策模型和求得的结果以及求解方法可为组织潜艇进行线式巡逻提供决策的科学依据。     

加快政治工作信息的数字化改造

数字化是政治工作主动实现与计算机接轨的必然选择,是政治工作生存方式和知识表达方式的变革。政治工作数字化的技术路径包括文献研究、专家预测、改造重组、实验推演。要加强自主创新,努力突破政工知识表示与推理技术瓶颈,全面推进政治工作数字化。     

多杆多自由度连杆机构的分析与模拟

根据复杂平面连杆机构特点,提出对多杆多自由度连杆机构的运动分析策略和动态模拟方法,并以两种常见机构为例进行了分析、模拟。     

网络舆论战的心理学意义

从舆论战和网络舆论战的概念和特点出发,阐述了心理学在网络舆论战中的重要作用。综合心理学理论和舆论传播理论分析了网络舆论形成的心理机制,得出了网络舆论是通过个体心理和群体心理两个阶段而形成的结论。根据这个结论,提出了网络舆论引导的具体策略。即在个体层面上,通过操纵信息来影响人的认知;在群体层面上,通过塑造引导者主体的可信性和喜爱性,以及网络技术手段来增强舆论引导的效果。最后,指出了网络舆论战的发展前景在于充分考虑受众的心理,有针对性地进行舆论引导。