反应性事故中的瞬发加热效应

本文考虑了反应性事故中的瞬发加热效应和各种反应性反馈效应,导出了用于分析各类反应性事故的热工水力方程,其结果适用于运行监督现场的快速计算。     

THE MORAL PERMISSIBILITY OF AUTOMATED RESPONSES DURING CYBERWARFARE

Automated responses are an inevitable aspect of cyberwarfare, but there has not been a systematic treatment of the conditions in which they are morally permissible. We argue that there are three substantial barriers to the moral permissibility of an automated response: the attribution, chain reaction, and projection bias problems. Moreover, these three challenges together provide a set of operational tests that can be used to assess the moral permissibility of a particular automated response in a specific situation. Defensive automated responses will almost always pass all three challenges, while offensive automated responses typically face a substantial positive burden in order to overcome the chain reaction and projection bias challenges. Perhaps the most interesting cases arise in the middle ground between cyber-offense and cyber-defense, such as automated cyber-exploitation responses. In those situations, much depends on the finer details of the response, the context, and the adversary. Importantly, however, the operationalizations of the three challenges provide a clear guide for decision-makers to assess the moral permissibility of automated responses that could potentially be implemented.     

Vapor-phase decomposition of dimethyl methylphosphonate (DMMP), a sarin surrogate,in presence of metal oxides

Chemical warfare agents (CWA) are stockpiled in large quantities across the globe. Agents stored in inaccessible facilities need to be destroyed rapidly without dispersing the compounds to surrounding areas. Metal-based energetic formulations are used in such prompt defeat applications to rapidly decompose the CWA by generating a high temperature environment. An alternate, and possibly a more effective decomposition pathway could be provided by chemicidal action of aerosolized condensed combustion products, which typically consist of metal oxides. Toxic fumes that escape the high tem-perature blast zone can be neutralized by smoke generated during combustion, depending on the par-ticle size, surface characteristics, chemical properties, and concentration of this smoke. This review considers relevant experimental and modeling studies quantifying decomposition of CWA comprising organophosphorus compounds and their surrogates on the surface of various metal oxides. Dimethyl methylphosphonate (DMMP), a sarine surrogate, was used most commonly for such experiments. Many reported efforts focused on the mechanisms of adsorption of DMMP to various metal oxides and initial reaction steps cleaving various bonds from the chemisorbed molecules. For selected oxides, these ex-periments were supported by quantum-mechanical calculations. In other studies, the capacity of oxide surfaces to adsorb and decompose DMMP was quantified. In most cases, porous catalysts were used although limited experimental data are available for aerosolized nonporous oxide particles. The reported experimental data applicable to scenarios involving prompt decomposition of CWA are summarized. It is noted that information is lacking describing respective heterogeneous reaction kinetics. Preliminary estimates of aerosolized smoke particle concentrations required to destroy CWA are made considering gas phase diffusion rates and reported values of the oxide capacity to decompose CWA or their surrogates.