La掺杂纳米TiO2光催化降解TNT的动力学

以掺杂La的纳米TiO2作光催化剂，研究了光催化降解TNT的动力学规律，考察了TNT初始质量浓度、催化剂用量、初始pH、通氧速率及光照强度等因素对TNT光催化降解的影响。试验结果表明：在不同初始质量浓度、初始pH、通氧速率、光照强度及催化剂用量为0．3～2．0g／L的条件下，TNT光催化降解反应遵循拟一级动力学规律，且可用Langmuir-Hinshelwood动力学模型描述；当催化剂用量为0．1g／L时，该反应可认为是震缀反应．     

基于高压脉冲等离子体技术的TNT废水处理研究

针对报废弹药处理过程中产生的TNT废水毒性大、处理难的特点,分析TNT废水的特性和当前处理方法现状,提出基于高压脉冲等离子体技术的TNT废水处理方法;分析脉冲等离子体对废水的处理降解机理,给出双向窄脉冲电源和气液固三相反应器的设计方案．研究表明,利用脉冲放电等离子体技术可提高TNT废水的处理效率,有效解决报废弹药TNT废水处理难题．     

重庆缙云山典型紫色土吸附TNT动力学研究

采用振荡平衡法对缙云山典型紫色土吸附TNT过程进行研究,探讨供试土壤对TNT吸附的动力学特征。结果表明,TNT在供试土壤上的吸附可分为快速吸附和慢速吸附2个过程,快速吸附过程主要发生在初始的15 min内,并且在吸附8 h后基本达到平衡。对动力学数据采用准一级动力学模型、准二级动力学模型、Elovich动力学模型以及颗粒内扩散模型进行拟合,拟合结果排序为准二级动力学模型Elovich动力学模型准一级动力学模型颗粒内扩散模型,说明供试土壤对TNT的吸附过程具体可分为液膜扩散、表面吸附以及内扩散3个阶段。     

La掺杂纳米TiO2的制备及其光催化性能

采用溶胶-凝胶法制备了镧掺杂TiO2粉体材料，利用DSC—TG和XRD进行了结构表征，以TNT为目标降解物研究了其光催化性能。结果表明，La掺杂抑制了TiO2的晶粒增长和晶型的转变，适量的La掺杂提高了TiO2的光催化活性，La掺杂量（摩尔分数）为2％时光催化活性最佳，La掺杂过量会降低其光催化活性。     

TNT生物代谢的可能途径

因具有毒性和三致作用,污染环境介质中TNT去除倍受关注。为了能更有效地去除TNT,在总结大量文献的基础上,主要从TNT反应性质方面探讨其生物代谢途径。TNT的结构决定了TNT难于生物氧化、易于生物还原。TNT还原以硝基基团的序批式还原为主,一些中间代谢产物还会相互作用生成聚合物,产物TAT需在严格厌氧条件下生成;TNT的芳烃环也可实现加氢脱硝还原,以利于下一步反应的进行;此外,TNT可同时发生硝基还原和芳烃环还原,两条途径的中间产物还会相互作用生成一些聚合物。TNT的氧化以间接氧化为主,直接氧化很少。由于TNT本身结构的复杂性、反应条件或介质的不同、中间产物的多样性,使得TNT代谢途径还具有很大的不确定性,故仍需进行深入研究。     

Response of masonry systems against blast loading

In this paper eight successive experimental blast tests with an increasing TNT equivalent charge weights ranging from 0.56 kg to 17.78 kg were conducted on unreinforced, ferrocemented overlay masonry and confined masonry walls. The pressure-time history caused by the blast was recorded by pressure sensors installed on the test specimen. The resulting damage pattern was observed during each test. Weak zones in the three systems of masonry were identified. Scaled distances for different damage levels in the three masonry systems were experimentally obtained. The results provide a basis for determining the response of each masonry system against blast loading. Consequently, efficiency of ferrocemented overlay ma-sonry and confined masonry was found established in mitigation against blast loads.     

Formation and characterization of core-shell CL-20/TNT composite prepared by spray-drying technique

The core-shell 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane/2,4,6-Trinitrotoluene (CL-20/TNT) composite was prepared by spray-drying method in which sensitive high energy explosive (CL-20) was coated with insensitive explosive (TNT). The structure and properties of different formulations of CL-20/TNT composite and CL-20/TNT mixture were characterized by scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Laser particle size analyzer, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), differential scanning calorimetry (DSC), impact sensitivity test and detonation performance. The results of SEM, TEM, XPS and XRD show that ϵ-CL-20 particles are coated by TNT. When the ratio of CL-20/TNT is 75/25, core-shell structure is well formed, and thickness of the shell is about 20–30 nm. And the analysis of heat and impact show that with the increase of TNT content, the TNT coating on the core-shell composite material can not only catalyze the thermal decomposition of core material (CL-20), but also greatly reduce the impact sensitivity. Compared with the CL-20/TNT mixture (75/25) at the same ratio, the characteristic drop height of core-shell CL-20/TNT composite (75/25) increased by 47.6% and the TNT coating can accelerate the nuclear decomposition in the CL-20/TNT composites. Therefore, the preparation of the core-shell composites can be regarded as a unique means, by which the composites are characterized by controllable decomposition rate, high energy and excellent mechanical sensitivity and could be applied to propellants and other fields.     

Mitigation of the blast load effects on a building structure using newly composite structural configurations

In this study, a nonlinear three-dimensional hydrocode numerical simulation was carried out using AUTODYN-3D to investigate the effect of blasting of a high explosive material (TNT) against several configurations of the composite structure. Several numerical models were carried out to study the effect of varying the thickness of the walls and the effect of adding an air layer or aluminum foam layer inside two layers of concrete in mitigating the effect of blast waves on the structure walls. The results showed that increasing the thickness of walls has a good effect on mitigating the effect of blast waves. When a layer of air was added, the effect of blast waves was exaggerated, while when a layer of aluminum foam was added the blast wave effects were mitigated with a reasonable percentage.     

火炮模拟终端对目标毁伤定量计算研究

计算火炮毁伤半径及对目标毁伤程度是实兵对抗训练系统的重要研究内容之一,对实兵对抗训练中火力毁伤建模具有重要意义。根据实际项目应用情况,提出一种火炮对目标毁伤定量计算方法,该方法通过计算炮弹爆炸时产生的冲击波超压,进而计算火炮毁伤半径及对目标产生的毁伤程度,提高了模拟火力打击的可信度和科学性,能较准确地体现火炮模拟终端在实兵对抗训练中火力打击的作用,贴近实战。     

温度对梯恩梯感度的影响

本文用落锤法测得了温度对TNT炸药撞击感度的影响。实验表明,TNT的撞击感度随着温度的升高而增加,当温度为75℃时,其感度比钝感的黑索金高,因此在高温下使用TNT时应采取必要的安全措施。此外,本文还从理论上分析了温度对撞击感度的影响原因。