Tuning the reactivity of Al–Ni by fine coating of halogen-containing energetic composites

In this paper, various core-shell structured Al–Ni@ECs composites have been prepared by a spray-drying technique. The involved ECs refer to the energetic composites (ECs) of ammonium perchlorate/nitrocellulose (AP/NC, NA) and polyvinylidene fluoride/hexanitrohexaazaisowurtzitane (PVDF/CL-20, PC). Two Al–Ni mixtures were prepared at atomic ratios of 1:1 and 1:3 and named as Al/Ni and Al/3Ni, respectively. The thermal reactivity and combustion behaviors of Al–Ni@ECs composites have been comprehensively investigated. Results showed that the reactivity and combustion performance of Al–Ni could be enhanced by introducing both NA and PC energetic composites. Among which the Al/Ni@NA composite exhibited higher reactivity and improved combustion performance. The measured flame propagation rate (v = 20.6 mm/s), average combustion wave temperature (T_max = 1567.0 °C) and maximum temperature rise rate (γ_t = 1633.6 °C/s) of Al/Ni@NA are higher than that of the Al/Ni (v = 15.8 mm/s, T_max = 858.0 °C, and γ_t = 143.5 °C/s). The enhancement in combustion properties could be due to presence of the acidic gaseous products from ECs, which could etch the Al₂O₃ shell on the surface of Al particles, and make the inner active Al to be easier transported, so that an intimate and faster intermetallic reaction between Al and Ni would be realized. Furthermore, the morphologies and chemical compositions of the condensed combustion products (CCPs) of Al–Ni@ECs composites were found to be different depending on the types of ECs. The compositions of CCPs are dominated with the Al–Ni intermetallics, combining with a trace amount of Al₅O₆N and Al₂O₃.     

The non-isothermal gravimetric method for study the thermal decomposition kinetic of HNBB and HNS explosives

The hexanitrostilben (HNS) is a thermally stable explosive that can be prepared from hexanitrobibenzyl (HNBB). Therefore, the investigation of thermal stability of HNBB can be important in the yield of preparation of HNS. The decomposition kinetic of HNBB and HNS are studied by non-isothermal gravimetric method. The TG/DTG curves in non-isothermal method are obtained in range of 25°C–400 °C at heating rates of 3 °C/min, 5 °C/min, 8 °C/min, 10 °C/min and 12 °C/min. The data of weight-temperature are used for calculation of activation energy (E_a) of thermal decomposition reactions by methods of Ozawa, Kissinger, Ozawa-Flynn-Wall (OFW) and Kissinger-Akahira-Sunose (KAS) as model-free methods and Strink's equation as model-fitting method. The compensation effect is used for prediction of mechanism and determination of pre-exponential factor (lnA) of the decomposition reaction. A reduction 60 kj/mol for the average of activation energy of thermal decomposition reaction of HNBB is obtained versus HNS. This result shows the lower thermal stability of HNBB in comparison to HNS. The Avrami equation (A_3/2) with function f(α) = 3/2(1-α)[-ln(1-α)]^1/3 indicates the predicted mechanism for thermal decomposition reaction both explosives.     

Preparation of ammonium nitrate-based solid composite propellants supplemented with polyurethane/nitrocellulose blends binder and their thermal decomposition behavior

To improve the performance of solid composite propellants (SCPs) supplemented with ammonium nitrate (AN) as an oxidizer, the incorporation of energetic ingredients such as explosives, energetic binders or catalysts is a common effective approach. For this purpose, polyurethane (PU), a typical inert binder, was mixed with nitrocellulose (NC) as an energetic polymer. Numerous composite solid propellant compositions based on AN and NC-modified polyurethane binder with different NC ratios were prepared. The prepared formulations were characterized using Fourier transform infrared spectroscopy (FTIR), RAMAN spectroscopy, X-ray diffraction (XRD), electron densimetry, thermogravimetric (TG) analysis, and differential scanning calorimetry (DSC). A kinetic study was then performed using the iterative Kissinger-Akahira-Sunose (It-KAS), Flynn-Wall-Ozawa (It-FWO), and non-linear Vyazovkin integral with compensation effect (VYA/CE) methods. The theoretical performances, such as theoretical specific impulse, adiabatic flame temperature, and ideal exhaust gaseous species, were also determined using the NASA Lewis Code, Chemical Equilibrium with Application (CEA). Spectroscopic examinations revealed the existence of NC and full polymerization of PU in the prepared propellants. According to density tests, the density of the propellant increases as the nitrocellulose component increases. According to the thermal analysis and kinetics study, the increase in NC content catalyzed the thermal decomposition of the AN-based composite solid propellants. Based on the theoretical study, increasing the amount of NC in the propellant increased the specific impulse and, as a result, the overall performance.     

Estimation of the kinetic parameters for thermal decomposition of HNIW and its adiabatic time-to-explosion by Kooij formula

A differential/integral method to estimate the kinetic parameters (apparent activation energy E_a and pre-exponential factor A) for thermal decomposition reaction of energetic materials based on Kooij formula are applied to study the nonisothermal decomposition reaction kinetics of hexanitrohexaazaisowurtzitane (HNIW) by analyzing nonisothermal DSC curve data. The apparent activation energy (E_a) obtained by the integral isoconversional non-isothermal method based on Kooij formula is used to check the constancy and validity of apparent activation energy by the differential/integral method based on Kooij formula. The most probable mechanism function of thermal decomposition reaction of HNIW is determined by a logical choice method. The equations for calculating the critical temperatures of thermal explosion (T_b) and adiabatic time-to-explosion (t_TIad) based on Kooij formula are used to calculate the values of T_b and t_TIad to evaluate the thermal safety and heat-resistant ability of HNIW. All the original data needed for analyzing the kinetic parameters are from nonisothermal DSC curves. The results show that the kinetic model function in differential form and the values of E_a and A of decomposition reaction of HNIW are 3(1 − α)[−ln(1 − α)]^2/3, 152.73 kJ mol⁻¹ and 10^11.97 s⁻¹, respectively, and the values of self-accelerating decomposition temperature (T_SADT), T_b and t_TIad are 486.55 K, 493.11 K and 52.01 s, respectively.     

Noise and vibration measurements in a Viking military vehicle

Noise and whole-body vibration measurements were made in a Viking military vehicle to determine the variation that should be expected during repeat measures, the effect of speed (up to 60 km/h in 5 km/h increments), and during travel over different types of terrain (comprising concrete road, gravel track and rough cross-country). Measurements were made at various crew positions (including the driver and commander) in both the front and the rear cabs in the vehicles. Three translational axes of vibration were measured in each seat. Two speeds were investigated over road (35 km/h and 55–60 km/h) and gravel (20 km/h and 35 km/h) surfaces. The effect of varying speed of the vehicle on the measured noise and vibration magnitudes was also investigated. The highest sound pressure level (L_Aeq) of 104 dB(A) was measured at the commander’s standing position during travel over concrete road at 55 km/h. Higher noise levels occurred for a standing commander compared with when sitting on the seat. A maximum single axis frequency-weighted vibration magnitude of 1.0 m/s² r.m.s. was measured on the driver’s seat during travel over track at 35 km/h. Higher vibration magnitudes occurred during travel over track compared with travel over road. Both noise and vibration exposure of crew within the Viking vehicle increased with increasing speed of the vehicle.     

Covariance of weibull order statistics

Let X₁ < X₂ <… < X_n denote an ordered sample of size n from a Weibull population with cdf F(x) = 1 - exp (?x^p), x > 0. Formulae for computing Cov (X_i, X_j) are well known, but they are difficult to use in practice. A simple approximation to Cov(X_i, X_j) is presented here, and its accuracy is discussed.     

Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging

In order to study the cross-linking density and aging constitutive relationship of HTPB coating during storage, the thermal accelerated aging tests at 0%, 3%, 6% and 9% prestrains were carried out. The cross-linking density of HTPB coating at different aging stages were tested using low-field ¹H NMR and the variation of cross-linking density was analyzed. The aging model of cross-linking density considering the chemical aging and the physical stretching factors was established. The uniaxial tensile tests were carried out on HTPB coating at different aging stages and the cross-linking density was introduced into Ogden hyperelastic constitutive model as a characterization parameter of correction coefficient. Combined with uniaxial tensile test results, a prestrain aging constitutive model of HTPB coating was established. The results show that the cross-linking density of HTPB coating increases rapidly at first and then slowly with the increase of thermal accelerated aging time without prestrain. Under prestrain conditions, the cross-linking density of HTPB coating decreases at the early stage, and increases rapidly at first and then slowly at the middle and late stages of thermal accelerated aging. The correlation coefficients of aging model of cross-linking density and aging constitutive model with test results are R > 0.9500 and R > 0.9900 respectively, which can be used to accurately describe the cross-linking density and aging constitutive relationship of HTPB coating under prestrain accelerated thermal aging conditions.     

A minmax search for the critical level of a system: The asymmetric case

We consider a system composed of k components, each of which is subject to failure if temperature is above a critical level. The failure of one component causes the failure of the system as a whole (a serially connected system). If z_i is the critical temperature of the ith component then z^* = min{z_i: i = 1,2,…, k} is the critical level of the system. The components may be tested individually at different temperature levels, if the temperature is below the critical level the cost is $1, otherwise the test is destructive and the cost is m > 1 dollars. The purpose of this article is to construct, under a budgetary constraint, an efficient (in a minmax sense) testing procedure which will locate the critical level of the system with maximal accuracy.     

Structure design and property adjustment of new cage rich-nitrogen pentazolyltetraazacubanes as potential high energy density compounds

In this study, based on two attractive energetic compounds pentazole (PZ) and tetraazacubane (TAC), a new family of high energy and high nitrogen compounds pentazolyltetraazacubanes were designed. Then, a different number of NH₂ or NO₂ groups were introduced into the system to further adjust the property. The structures, properties, and the structure-property relationship of designed molecules were investigated theoretically. The results showed that all nine designed compounds have extremely high heat of formation (HOF, 1226-2734 kJ/mol), good density (1.73–1.88 g/cm³), high detonation velocity (8.30–9.35 km/s), high detonation pressure (29.8–39.7 GPa) and acceptable sensitivity (ΔV: 41-87 ų). These properties could be effectively positive adjusted by replacing one or two PZ rings by NH₂ or/and NO₂ groups, especially for the energy and sensitivity performance, which were increased and decreased obviously, respectively. As a result, two designed pentazolyltetraazacubanes were predicted to have higher energy and lower sensitivity than the famous high energy compound in use 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane, while two others have better combination property than 1,3,5-Trinitro-1,3,5-triazacyclohexane. In all, four new pentazolyltetraazacubanes with good combination performance were successfully designed by combining PZ with TAC, and the further property adjustment strategy of introducing a suitable amount of NH₂/NO₂ groups into the system. This work may help develop new cage energetic compounds.     

Studies on the flame propagation characteristic and thermal hazard of the premixed N2O/fuel mixtures

An experimental study was carried out to investigate the flame propagation and thermal hazard of the premixed N₂O/fuel mixtures, including NH₃, C₃H₈ and C₂H₄. The study provided the high speed video images and data about the flame locations, propagation patterns, overpressures and the quenching diameters during the course of combustion in different channels to elucidate the dynamics of various combustion processes. The onset decomposition temperature was determined using high-performance adiabatic calorimetry. It was shown that the order of the flame acceleration rate and thermal hazard was N₂O/C₂H₄>N₂O/C₃H₈>N₂O/NH₃.     

1.25cm 体效应振荡器研制

文中讨论了一种1.25cm波段的波导型体效应振荡器。其主腔采用可调节的同轴减高波导座结构,使电路与二极管实现良好匹配。文中着重讨论了主腔各部尺寸对振荡器特性的影响。稳频腔采用高Q值的H_(011)模式圆柱腔,并采用线胀系数不同的金属材料进行温度补偿,提高了频率稳定度。利用WT55型体效应管,在23-25GH_2频带内,功率输出大于30mw,频率稳定度为5×10~(-5)。     

Problem of the reference height of the projectile trajectory as a reduced meteo-ballistic weighting factor

This paper deals with the issue of preparation of the aiming angles with the use of tabular firing tables and needed determination of the ballistic elements μ_B (ballistic wind w_B, w_xB, w_ZB, ballistic (virtual) temperature τ_B, ballistic density ρ_B) from the standardized met messages. The weighting factors are used for the calculation of ballistic elements μ_B that are incorporated into the trajectory calculations characteristics of weapon and ammunition. Two different methodologies practically used in the praxis are analysed and compared. For the comparison of the two methodologies the reference height of trajectory determined from the weighting factor functions is employed. On the basis of the analyses conducted, the potential for further increase in accuracy of these aiming angles preparation methods is pointed out.     

Numerical modelling of non-ideal detonation in ANFO explosives applying Wood-Kirkwood theory coupled with EXPLO5 thermochemical code

Ammonium nitrate and fuel oil (ANFO) based explosive is a classic example of non-ideal high explosives. Its detonation is characterized by a strong dependence of detonation parameters on explosive charge diameter, presence and characteristics of confinement, as well as incomplete consumption of explosive at the sonic point.In this work we propose a detonation model based on the Wood-Kirkwood (WK) theory coupled with the thermochemical code EXPLO5 and supplemented with reaction rate models. Our objective is to analyze the validity of the model for highly non-ideal ANFO explosives, with emphasis on effect of reaction rate models.It was found that both single-step and two-step pressure-based models can be calibrated to reproduce experimental detonation velocity-charge radius data of ANFO at radii significantly above the failure radius (i.e. for D/D_id > ∼0.6). Single-step pressure-based model, with the pressure exponent equal to 1.4, proved to be the most accurate, even in the vicinity of the failure radius. The impact of the rate models is most evident on temporal (and spatial) distribution of flow parameters in detonation driving zone, especially when it comes to the conversion and width of detonation driving zone.     

A new look on the electric spark sensitivity of nitramines

Electric spark energy, E_ES, for a 50% probability of initiation of the 14 nitramines was determined using a measuring instrument in which the electrodes are in direct contact with the sample. Indirectly proportional relationships were established between the logarithm of the E_ES values and the length of the longest N–N bond in the nitramine molecule. This finding is compatible with the mechanism of the first step in the electro-reduction of the nitramine grouping. Directly proportional relationships were found to exist between the E_ES values and the crystal lattice free volumes, ΔV (i.e. an increase in the ΔV values increases the nitramine's resistance to electric sparks) but there were several nitramines with the opposite course of this relationship. Also a semilogarithic relationships between the E_ES values and a ratio of intrinsic volumes of molecule, V_int, to the ΔV values were described as well as ambiguous linear dependence between these energies and a sum of the positive and negative extremes of the molecular surface electrostatic potentials, V_S,Σ. Several nitramines studied (always the same ones) display roughly the same distribution in the coordinate systems of relationships with lengths of the longest N–N bonds, the V_int/ΔV ratio and the sum V_S,Σ as the independent variables. It was found that, typically, such relationships start from a single identical point, in effect a point corresponding to data for a structural unit from which the studied nitramines can be hypothetically generated, and/or are converging on another point, often the one corresponding to the data for HNIW. All the findings point to a fundamental influence of the intermolecular forces on reactivity of nitramines exposed to electric sparks.     

Analysis on the resistive force in penetration of a rigid projectile

According to the dimensionless formulae of DOP (depth of penetration) of a rigid projectile into different targets, the resistive force which a target exerts on the projectile during the penetration of rigid projectile is theoretically analyzed. In particular, the threshold V_c of impact velocity applicable for the assumption of constant resistive force is formulated through impulse analysis. The various values of V_c corresponding to different pairs of projectile-target are calculated, and the consistency of the relative test data and numerical results is observed.     

Influence of yttrium on microstructure and properties of Ni–Al alloy coatings prepared by laser cladding

Ni–Al alloy coatings with different Y additions are prepared on 45^# medium steel by laser cladding. The influence of Y contents on the microstructure and properties of Ni–Al alloy coatings is investigated using X-ray diffraction, scanning electron microscopy, electron probe microanalyzer, Vickers hardness tester, friction wear testing machine, and thermal analyzer. The results show that the cladding layers are mainly composed of NiAl dendrites, and the dendrites are gradually refined with the increase in Y additions. The purification effect of Y can effectively prevent Al₂O₃ oxide from forming. However, when the atomic percent of Y addition exceeds 1.5%, the extra Y addition will react with O to form Y₂O₃ oxide, even to form Al₅Y₃O₁₂ oxide, depending on the amount of Y added. The Y addition in a range of 1.5–3.5 at.% reduces the hardness and anti-attrition of cladding layer, but improves obviously its wear and oxidation resistances.     

Quantification of projection angle in fragment generator warhead

Tactical Ballistic Missile (TBM) class target neutralization by the fragment spray of a Fragment Generator Warhead (FGW) calls for quantification of fragment projection angle scatter to finalize the end game engagement logic. For conventional axi-symmetric warhead, dispersion is assumed to be normal with a standard deviation of 3⁰. However, such information is not available in case of FGW. Hence, a set of experiments are conducted to determine the dispersion of fragments. The experiments are conducted with a specific configuration of FGW in an identical arena to quantify the scatter and then verified its applicability to other configurations having a range of L/D and C/M ratios, and contoured fragmenting discs. From the experimental study, it is concluded that the scatter in projection angle follows normal distribution with a standard deviation of 0.75° at Chi-square significance level of 0.01(χ²_0.99).     

A solution for queues with instantaneous jockeying and other customer selection rules

This paper presents a general solution for the M/M/r queue with instantaneous jockeying and r > 1 servers. The solution is obtained in matrices in closed form without recourse to the generating function arguments usually used. The solution requires the inversion of two (Z^r?1) × (2^r?1) matrices. The method proposed is extended to allow different queue selection preferences of arriving customers, balking of arrivals, jockeying preference rules, and queue dependent selection along with jockeying. To illustrate the results, a problem previously published is studied to show how known results are obtained from the proposed general solution.     

Scheduling deteriorating jobs to minimize makespan

We consider a single-machine problem of scheduling n independent jobs to minimize makespan, in which the processing time of job J_j grows by w_j with each time unit its start is delayed beyond a given common critical date d. This processing time is p_j if J_j starts by d. We show that this problem is NP-hard, give a pseudopolynomial algorithm that runs in time and O(nd) space, and develop a branch-and-bound algorithm that solves instances with up to 100 jobs in a reasonable amount of time. We also introduce the case of bounded deterioration, where the processing time of a job grows no further if the job starts after a common maximum deterioration date D > d. For this case, we give two pseudopolynomial time algorithms: one runs in O(n²d(D − d) time and O(nd(D − d)) space, the other runs in p_j)²) time and p_j) space. © 1998 John Wiley & Sons, Inc. Naval Research Logistics 45: 511–523, 1998     

Readiness and the optimal redeployment of resources

This paper considers the problem of the optimal redeployment of a resource among different geographical locations. Initially, it is assumed that at each location i, i = 1,…, n, the level of availability of the resource is given by a₁ ≧ 0. At time t > 0, requirements R_f(t) ≧ 0 are imposed on each location which, in general, will differ from the a₁. The resource can be transported from any one location to any other in magnitudes which will depend on t and the distance between these locations. It is assumed that ΣR_j > Σa_t The objective function consideis, in addition to transportation costs incurred by reallocation, the degree to which the resource availabilities after redeployment differ from the requirements. We shall associate the unavailabilities at the locations with the unreadiness of the system and discuss the optimal redeployment in terms of the minimization of the following functional forms: \documentclass{article}\pagestyle{empty}\begin{document}$ \sum\limits_{j = 1}^n {kj(Rj - yj) + } $\end{document} transportation costs, Max \documentclass{article}\pagestyle{empty}\begin{document}$ \mathop {Max}\limits_j \,[kj(Rj - yj)] + $\end{document} transportation costs, and \documentclass{article}\pagestyle{empty}\begin{document}$ \sum\limits_{j = 1}^n {kj(Rj - yj)^2 + } $\end{document} transportation costs. The variables y_j represent the final amount of the resource available at location j. No benefits are assumed to accrue at any location if y_j > R_j. A numerical three location example is given and solved for the linear objective.