微胶囊技术应用进展

本文综述了微胶囊制备技术及其在医药、食品、农药、肥料、饲料、纺织、涂料等方面的应用现状。随着制备技术的发展 ,微胶囊的应用前景十分广阔     

黏结剂和纤维对石蜡微胶囊保温砂浆抗裂性影响

采用黏结剂增强石蜡微胶囊保温砂浆内部微粒间的结合力,分析了黏结剂类型和掺量对石蜡微胶囊保温砂浆抗折强度、黏结强度和韧性的影响;采用纤维增韧技术提高保温砂浆的抗裂能力,分析了纤维类型和掺量对石蜡微胶囊保温砂浆力学性能和抗裂性能的影响;确定了配制石蜡微胶囊保温砂浆使用乙烯—乙酸乙烯酯共聚乳胶粉黏结剂和聚丙烯纤维,其最佳掺量...     

微胶囊型自修复碳纤维增强复合材料性能研究

为了分析内嵌环氧树脂基微胶囊的碳纤维增强复合材料(CFRP)的力学性能,开展了材料在准静态载荷条件下力学性能试验研究,对比分析了有、无微胶囊时碳纤维增强复合材料的静态力学性能,详细探究了微胶囊的质量分数对碳纤维增强复合材料的力学性能和自修复性能的影响,分析了材料的拉伸强度,弹性模量,断裂伸长率以及自修复性能情况。在相同冲击能量下,采用落锤法对不同微胶囊含量的层合板进行冲击试验,研究其在冲击载荷作用下的动态力学响应。结果表明,微胶囊具有增韧效果和自修复能力。随着微胶囊质量分数的增加,自修复碳纤维增强复合材料的拉伸强度降低,弹性模量先略微升高后降低,断裂伸长率先降低后升高,但总体变化不大,修复效率随微胶囊含量的增加而升高。在相同冲击能量下,微胶囊含量越大,最大冲击力越小,材料的冲击力-位移曲线斜率越小,抗冲击性能越差。研究结果可以为推动自修复型CFRP材料的实际工程应用和理论研究提供相关参考。     

一步法制备石蜡微胶囊的中试研究及性能表征

采用一步法在100L反应釜内进行石蜡微胶囊制备的中试，表征了石蜡微胶囊的微胶囊化率、粒径和热性能，探讨了中试工艺对产品性能的影响。结果表明中试产品与实验室小试产品的性能基本接近。中试石蜡微胶囊的微胶囊化率为70％，平均粒径为54．0μm，相变范围为40～80℃，相变峰值和热焓分别为65℃，114J／g，分解温度达250℃。     

微胶囊化红磷及其应用

微胶囊化红磷是一种无卤、无毒、低烟、高效和普适的新型阻燃剂。本文讨论微胶囊化红磷的几种制备方法,分析该阻燃剂的优异性能及在橡胶、塑料等阻燃制品中的特殊作用。     

声场计算与分析技术

声场计算与分析技术是近代声学理论与应用发展中十分重要的手段和依据。随着计算数学和计算机技术的迅速发展,声场分析技术突飞猛进并日趋成熟和完善,文章就声场分析技术所涉及的主要方法、特点及其应用的进展进行了评述和讨论。     

蜜胺甲醛树脂壁材辣素微胶囊的表面分析与释放动力学

在乳液体系中,以蜜胺甲醛树脂为壁材,以原位聚合法制备了包裹辣素同系物——N-香草基壬酰胺的微胶囊．电镜确定了微胶囊的形成,通过红外光谱、比表面吸附和光电子能谱对壁材进行了表面分析,释放动力学显示囊心符合Huiguchi一维释放模式,与表面分析的假设一致。     

弱吸收物质与低浓度场的光声光谱研究

从光谱学基本原理出发,分析了一般吸收光谱和发射光谱技术在工程应用方面所存在的缺陷,介绍了一种具有较高灵敏度的光声光谱分析技术,并利用光声光谱技术对弱吸收物质的吸收特性及低浓度场中各组分浓度的监测进行了定性和定量的分析研究,给出了该技术在某些领域中的具体应用。     

低熔点石蜡微胶囊的中试及热性能

为寻找能适应环境温度的相变材料,选择低熔点石蜡作为芯材,制备微胶囊并进行中试生产。对同一样品进行了26次DSC热循环测试和TGA热失重测试,结果表明：中试产品的相变温度始终保持在25~60℃,相变极值和相变热焓均未发生明显变化,分别为42℃和72 J/g;产品能耐受150℃以内的高温而不分解,且在相变温度范围内基本无失重。证明低熔点石蜡微胶囊能在环境温度内发挥调节作用,同时具备较长的热循环寿命和较好的热稳定性,是一种具备良好应用前景的相变材料。     

超导技术让武器装备突破物理极限

军事活动作为人类社会生活的特殊需要,般来说总是最先吸纳人类社会最新的科技成果,而这些最新技术的应用直接导致了军事技术革命和一大批高新技术武器装备的出现。由于超导材料在军事上的应用有着极为广阔的前景,各先进国家都在竞相研究,随着超导技术的发展和应用,必然对军事技术产生重大影响。 一、超导技术及其发展 所谓超导体,是指电阻为零的物质。1911年,     

Dynamic impact protective body armour: A comprehensive appraisal on panel engineering design and its prospective materials

Personal body armour is one of the most important pieces of equipment to protect human beings from various critical and fatal injuries. In today’s modern world, various organizations including law enforcement and security service have made it mandatory for their personnel to wear personal protection system while on field duty. However, the systems should comprise an improved ballistic performance, light-weighted, flexible as well as comfortable panel not only to be accepted with a wider range but also for effective performances of the consumer. Generally, the overall performances of the protective body armour could be affected by various parameters including armour design techniques, type of materials used and finishing of the panels. The current paper aims to critically review state-of-art for armour panel design techniques and the different perspective body armour materials. The paper starts by discussing the different body armour and its category. Later, the different states of technology for armour panel design (mostly for women), its problems and the possible solutions will be cited. Later, the commonly used different polymeric fibrous and the future possible advanced materials including carbon nanotube (CNT), Graphene CNT and shear thickening fluids (STFs) treated materials for developing the reinforced body armour panel will be discussed. The authors believe that this paper will enlighten useful guidelines and procedures about the different panel design techniques and current and promising future materials for researchers, designers, engineers and manufacturers working on the impact resistance body armour field.     

化学在消防中的基础地位探析

阐述化学在消防实践中的基础地位 ,表明消防技术的发展与完善离不开化学的不断发展和新的化学技术手段与材料的出现 ,另一方面 ,消防实践中出现的新问题又会促进化学的发展 ,同时也对化学提出了新的要求。     

Experimental and numerical study of the fragmentation of expanding warhead casings by using different numerical codes and solution techniques

There has been increasing interest in numerical simulations of fragmentation of expanding warheads in 3D. Accordingly there is a pressure on developers of leading commercial codes, such as LS-DYNA, AUTODYN and IMPETUS Afea, to implement the reliable fracture models and the efficient solution techniques. The applicability of the Johnson–Cook strength and fracture model is evaluated by comparing the fracture behaviour of an expanding steel casing of a warhead with experiments. The numerical codes and different numerical solution techniques, such as Eulerian, Lagrangian, Smooth particle hydrodynamics (SPH), and the corpuscular models recently implemented in IMPETUS Afea are compared. For the same solution techniques and material models we find that the codes give similar results. The SPH technique and the corpuscular technique are superior to the Eulerian technique and the Lagrangian technique (with erosion) when it is applied to materials that have fluid like behaviour such as the explosive and the tracer. The Eulerian technique gives much larger calculation time and both the Lagrangian and Eulerian techniques seem to give less agreement with our measurements. To more correctly simulate the fracture behaviours of the expanding steel casing, we applied that ductility decreases with strain rate. The phenomena may be explained by the realization of adiabatic shear bands. An implemented node splitting algorithm in IMPETUS Afea seems very promising.     

An efficient SPH methodology for modelling mechanical characteristics of particulate composites

Particulate composites are one of the widely used materials in producing numerous state-of-the-art components in biomedical, automobile, aerospace including defence technology. Variety of modelling techniques have been adopted in the past to model mechanical behaviour of particulate composites. Due to their favourable properties, particle-based methods provide a convenient platform to model failure or fracture of these composites. Smooth particle hydrodynamics (SPH) is one of such methods which demonstrate excellent potential for modelling failure or fracture of particulate composites in a Lagrangian setting. One of the major challenges in using SPH method for modelling composite materials depends on accurate and efficient way to treat interface and boundary conditions. In this paper, a master-slave method based multi-freedom constraints is proposed to impose essential boundary conditions and interfacial displacement constraints in modelling mechanical behaviour of composite materials using SPH method. The proposed methodology enforces the above constraints more accurately and requires only smaller condition number for system stiffness matrix than the procedures based on typical penalty function approach. A minimum cut-off value-based error criteria is employed to improve the compu-tational efficiency of the proposed methodology. In addition, the proposed method is further enhanced by adopting a modified numerical interpolation scheme along the boundary to increase the accuracy and computational efficiency. The numerical examples demonstrate that the proposed master-slave approach yields better accuracy in enforcing displacement constraints and requires approximately the same computational time as that of penalty method.     

Reaction characteristic of PTFE/Al/Cu/Pb composites and application in shaped charge liner

In this paper, the reaction characteristic and its application in shaped charge warhead of a novel reactive material, which introduced copper (Cu) and plumbum (Pb) into traditional polytetrafluoroethylene/aluminum (PTFE/Al), are studied. The thermal analysis and chemical reaction behavior of the PTFE/Al/Cu/Pb mixture are investigated by Differential Scanning Calorimetry (DSC),Thermo-gravimetry (TG), and X-ray Diffraction (XRD) techniques. Then, the shaped charge liners with PTFE/Al/Cu/Pb reactive materials are fabricated, and the X-ray experiments show that they could form reactive jets with excellent performance under the detonation effects of the shaped charge. Based on that, the penetration experiments of shaped charge with PTFE/Al/Cu/Pb reactive liner against steel plates are carried out, and the results demonstrate that the PTFE/Al/Cu/Pb reactive jets could produce a deeper penetration depth compared to the traditional PTFE/Al reactive jets. Meanwhile, the PTFE/Al/Cu/Pb reactive jets also show significant inner-blast effects, leading to dramatically cracking or fragmentation behavior of the penetrated steel plates. This new PTFE/Al/Cu/Pb reactive liner shaped charge presents enhanced penetration behavior for steel targets that incorporates the penetration capability of a high-density and ductility jet, and the chemical energy release of PTFE-matrix reactive materials.     

油料装备战场应急维修技术体系研究

从信息化战争对油料装备战场抢修快捷、有效和适时的要求出发,建立了油料装备战场应急维修技术体系,该体系由智能自修复维修技术、战场原位应急维修技术、伴随应急维修技术、定点应急维修技术和远程可视化应急维修技术五个层次组成,其关键技术是智能自修复技术和原位应急维修技术。采用新材料、新工艺、新技术实现维修敏捷化、精确化、信息化是油料装备战场应急维修技术的发展方向。     

虚拟环境中坦克射击训练仿真系统

在作战仿真系统中,坦克是一种重要的武器仿真实体,其火力模拟常成为研究的重点.结合科研实践,采用计算机仿真技术和部分坦克实装相结合的方式,对坦克炮长在虚拟环境中的射击训练进行仿真,着重从系统设计原理、系统软件和硬件的设计与实现等方面进行系列研究.实践证明,单片机技术和汇编编程的组合运用,不仅使系统数据的采集和传输更加实时准确,而且大大提高了系统的效能比,取得较高的军事效益和经济效益.     

Direct ink writing of 3D-Honeycombed CL-20 structures with low critical size

3D-Honeycombed CL-20 structures with low critical size of detonation have been fabricated successfully for intelligent weapon systems using a micro-flow direct ink writing (DIW) technology. The CL-20-based explosive ink for DIW technology was prepared by a two-component adhesive system with waterborne polyurethane (WPU) and ethyl cellulose (EC). Not only the preparation of the explosive ink but also the principle of DIW process have been investigated systematically. The explosive ink displayed strong shear-thinning behavior that permitted layer-by-layer deposition from a fine nozzle onto a substrate to produce complex shapes. The EC content was varied to alter the pore structure distribution and rheological behavior of ink samples after curing. The deposited explosive composite materials are of a honeycombed structure with high porosity, and the pore size distribution increases with the increase of EC content. No phase change was observed during the preparation process. Both WPU and EC show good compatibility with CL-20 particles. Apparently high activation energy was realized in the CL-20-based composite ink compared with that of the refined CL-20 due to the presence of non-energetic but stable WPU. The detonation performance of the composite materials can be precisely controlled by an adjustment in the content of binders. The 3D honeycombed CL-20 structures, which are fabricated by DIW technology, have a very small critical detonation size of less than 69 μm, as demonstrated by wedge shaped charge test. The ink can be used to create 3D structures with complex geometries not possible with traditional manufacturing techniques, which presents a bright future for the development of intelligent weapon systems.     

红外发射率可变材料在航天器热控技术中的应用

基于热致变色和电致变色的可变发射率涂层或器件由于其重量轻、体积小、能耗少、调控灵活等优点在航天器热控技术中具有极大的应用前景.红外发射率可变材料是可变发射率涂层或器件的核心,主要有电致变发射率材料和热致变发射率材料两类.分析了红外发射率可变材料在航天器热控中应用的原理,重点介绍了钙钛矿型复合氧化物(A1-xBxMO3)、二氧化钒(VO2)、三氧化钨(WO3)、导电高分子(CPs)等四类典型红外发射率可变材料应用于航天器热控的研究进展.根据航天器总体和热控技术的发展需求,指出了未来航天器热控用红外发射率可变材料的发展趋势.     

元胞法模拟非线性弹性层合材料中的应力波

元胞法 (MethodofCell)是在有效刚度理论的基础上发展起来的新方法 ,可以用来构造具有周期性结构单元的材料的本构 ,也可以用来模拟应力波在材料中的传播问题 ,尤其是具有分层结构的材料。本文中给出两种常见的初值条件 ,并利用该方法模拟了非线性弹性材料的动态响应 ,研究了波在该层合材料中的振荡现象