An experimental investigation of wire electrical discharge machining of hot-pressed boron carbide

The present work discusses the experimental study on wire-cut electric discharge machining of hot-pressed boron carbide.The effects of machining parameters,such as pulse on time(TON),peak current(IP),flushing pressure(FP) and spark voltage on material removal rate(MRR)and surface roughness(R_a) of the material,have been evaluated.These parameters are found to have an effect on the surface integrity of boron carbide machined samples.Wear rate of brass wire increases with rise in input energy in machining of hot-pressed boron carbide.The surfaces of machined samples were examined using scanning electron microscopy(SEM).The influence of machining parameters on mechanism of MRR and R_a was described.It was demonstrated that higher TON and peak current deteriorate the surface finish of boron carbide samples and result in the formation of large craters,debris and micro cracks.The generation of spherical particles was noticed and it was attributed to surface tension of molten material.Macro-ridges were also observed on the surface due to protrusion of molten material at higher discharge energy levels.     

卫星柔性热控薄膜材料充放电效应试验

针对柔性热控薄膜材料导电/绝缘多层复合、微纳尺寸厚度的结构特点,采用10～70 KeV电子辐照的方法开展了kapton基二次表面镜薄膜材料充放电特性的测试试验,获得了表面充电电位、静电放电频次等关键参数,并采用蒙特卡罗方法研究了辐照电子在多层薄膜材料内的输运规律。研究结果表明由于kapton基二次表面镜薄膜结构的特殊性,当辐照电子能量为10 KeV时未发生静电放电现象,随着电子能量不断增加,薄膜材料的表面充电电位幅值与静电放电频次呈先上升后下降的变化规律,且在电子能量为25 KeV时空间充放电效应最为显著。     

Effect of nano powder (Al2O3-CaO) addition on the mechanical properties of the polymer blend matrix composite

This work describes the preparation and study of the properties of composite nanoparticles prepared by the sol-gel method which consists of two materials (Al₂O₃-CaO), and study the effect of these nanoparticles on the mechanical behavior of a polymer blend (EP 4% + 96% UPE). The powder was evaluated by X-ray diffraction analysis, scanning electron microscopy analysis (SEM), particle size analysis, and energy dispersive X-ray analysis (EDX). The mechanical behavior of the composite material was assessed by tensile test, bending test and hardness test. The evaluation results of the composite nanoparticles showed good distribution of the chemical composition between aluminum oxide and calcium oxide, smoothness in particles' size at calcination in high and low temperatures, formation of different shapes of nanoparticles and different (kappa and gamma) phases of the Al₂O₃ particles. The results of mechanical behavior tests showed marked improvement in the mechanical properties of the resulted composite material, especially at 1.5%, compared with polymer blend material without nano powder addition. The tensile properties improved about (24 and 14.9) % and bending resistance about (23.5 and 16.8) % and hardness by (25 and 22) % when adding particles of size (63.8 and 68.6) respectively. Therefore, this reflects the efficiency of the proposed method to manufacture the nanocomposite powder and the possibility of using this powder as a strengthening material for the composite materials and using these composite materials in bio applications, especially in the fabrication of artificial limbs.     

PSpice模型用于电爆炸丝的数值模拟

根据细铜丝通过大电流时发生爆炸而导致电阻率的急剧变化的实验数据,建立了其PSpcie电路模型。然后将这个模型应用于一个含电爆炸丝断路开关的电感储能脉冲功率电路,以探讨电爆炸丝的参数选择对脉冲功率调制系统的影响。研究表明电爆炸丝长度主要控制电流切断的效果,而电爆炸丝的根数或截面积主要控制电爆炸丝切断的时刻,并且初始电压愈大,切断愈迅速,在负载上获得更高的电压。这些结论可以较好地解释实验结果。     

电晕放电辐射场若干特性分析

为了研究电晕放电辐射场若干特性,首先进行了电晕放电时电晕电流的理论分析,研究了电晕电流的波形随电压变化情况。然后在采用针-板电极物理实验模型的基础上进行了电晕放电实验研究,分析了放电针上的充电电压对脉冲电流的影响,并确定了辐射场随传播距离的变化规律以及放电重复率随电压的变化情况。实验结果发现,当针为负极性时先发生放电,但正极性下先发生火花放电;电晕放电辐射场与距离成反比关系;放电重复率随着电压的增大而增大。     

Formation and characterization of core-shell CL-20/TNT composite prepared by spray-drying technique

The core-shell 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane/2,4,6-Trinitrotoluene (CL-20/TNT) composite was prepared by spray-drying method in which sensitive high energy explosive (CL-20) was coated with insensitive explosive (TNT). The structure and properties of different formulations of CL-20/TNT composite and CL-20/TNT mixture were characterized by scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Laser particle size analyzer, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), differential scanning calorimetry (DSC), impact sensitivity test and detonation performance. The results of SEM, TEM, XPS and XRD show that ϵ-CL-20 particles are coated by TNT. When the ratio of CL-20/TNT is 75/25, core-shell structure is well formed, and thickness of the shell is about 20–30 nm. And the analysis of heat and impact show that with the increase of TNT content, the TNT coating on the core-shell composite material can not only catalyze the thermal decomposition of core material (CL-20), but also greatly reduce the impact sensitivity. Compared with the CL-20/TNT mixture (75/25) at the same ratio, the characteristic drop height of core-shell CL-20/TNT composite (75/25) increased by 47.6% and the TNT coating can accelerate the nuclear decomposition in the CL-20/TNT composites. Therefore, the preparation of the core-shell composites can be regarded as a unique means, by which the composites are characterized by controllable decomposition rate, high energy and excellent mechanical sensitivity and could be applied to propellants and other fields.     

LaB6空心阴极中毒特性研究

LaB6阴极与其他类型阴极相比具有电子发射电流密度大等优点，已广泛用于电推进、高发射密度电子枪等产品。为了研究LaB6空心阴极中毒特性，识别LaB6空心阴极主要失效模式，分别对LaB6空心阴极暴露大气后性能变化特征和引起性能变化的原因进行了研究。结果表明：LaB6空心阴极在暴露大气后表面吸附大量中毒气体，出现了发射体表面逸出功增加，发射体出现短期中毒现象。此时空心阴极的放电电压和阴极顶温度均有所上升，经过短期工作后放电电压和阴极顶温度均恢复初始状态。但LaB6空心阴极严重中毒后，并且不能通过加热和离子轰击方式去除表面生成的氧化物。因此，可以在实验过程中通过监测空心阴极的阴极顶温度和阳极电压变化间接表征空心阴极发射体状态。     

飞机静电起电放电机理及带电极性的相关研究

飞机上的静电来源主要包括：沉积颗粒的摩擦起电、发动机引擎燃烧产生的等离子气体起电、穿越带电云层时的感应起电、对流起电和雨滴等粒子的破裂起电等。当机体上电压达到周围介质的放电电压阈值时就会放电，这些放电产生的电磁噪声对导航和通讯都会造成干扰。飞机放电机理主要包括电晕放电、绝缘材料与金属之间的流柱放电和相邻未焊接金属间的火花放电。在实验室内通过对不同物质进行摩擦起电试验和发动机尾气喷射起电实验，得出不同起电方式的带电极性。     

火箭弹防静电作用研究

针对电发火弹药静电放电问题,以某型130 mm火箭弹为例,采用真实静电感度测试系统测试了电火工品在有、无绝缘层时50%的静电点火能量,并在试验程序及数据处理中使用真实静电感度数据处理方法统计了50%静电发火能量的估计值。通过比较发现二者的差值在误差范围内,这表明静电放电研究中可以将弹体所接受的能量视作全部作用于火工品上,绝缘层不吸收静电放电的能量。在电发火弹药的防护中,必须采用静电防护措施杜绝电发火弹药的意外发火。     

LaB6空心阴极中毒特性

LaB_6阴极与其他类型阴极相比具有电子发射电流密度大等优点,已广泛用于电推进、高发射密度电子枪等产品。为了研究LaB_6空心阴极中毒特性、识别LaB_6空心阴极主要失效模式,分别对LaB_6空心阴极暴露大气后性能变化特征和引起性能变化的原因进行了研究。结果表明:LaB_6空心阴极在暴露大气后表面吸附大量中毒气体,出现了发射体表面逸出功增加、发射体短期中毒现象。此时空心阴极的放电电压和阴极顶温度均有所上升,经过短期工作后放电电压和阴极顶温度均恢复初始状态。但LaB_6空心阴极严重中毒后,并不能通过加热和离子轰击方式去除表面生成的氧化物。因此,可以在实验过程中通过监测空心阴极的阴极顶温度和阳极电压变化间接表征空心阴极发射体状态。     

集成电路ESD注入损伤效应及注入电压与能量间的关系

利用静电放电(ESD)模拟器对集成电路芯片进行电压注入损伤效应实验,通过存贮示波器记录的波形进行乘法和积分运算,得到对应注入电压下芯片上吸收的平均峰值功率和能量。对放电电压与平均峰值能量作散点图,采用曲线拟合的方法对离散点进行拟合,针对该曲线拟合的方法进行了分析,最终建立了ESD注入电压与平均峰值能量之间的数学模型。     

疏水性纳米TiO2制备及其在菜籽油中的摩擦磨损性能

以纳米TiO2为原料、硬脂酸为表面改性剂,通过超声反应制备了疏水性纳米TiO2（SA-TiO2）;采用扫描电子显微镜（SEM）、红外光谱仪及接触角测量仪对其微结构进行了表征。以SA-TiO2为润滑油添加剂,在四球试验机上考察了其在菜籽油中的摩擦磨损性能,并利用SEM观察钢球表面磨斑形貌,用能谱仪（EDS）和X射线光电子能谱仪（XPS）分析了钢球表面磨斑的化学成分。结果表明：SA-TiO2为疏水性单分散球状颗粒,其平均直径约为20 nm;SA-TiO2能够提高菜籽油的抗磨减摩性能,当SA-TiO2的质量分数为1%,菜籽油的抗磨减摩性能达到最佳;钢球表面磨斑的EDS和XPS分析表明,纳米微粒在钢球摩擦表面形成了一层含菜籽油和SA-TiO2的吸附膜,在摩擦剪切作用下,发生摩擦化学反应生成了一层含钛、铁氧化物的边界润滑膜,这种边界润滑膜起到了良好的润滑作用。     

Research on design and firing performance of Si-based detonator

For the chip integration of MEMS (micro-electromechanical system) safety and arming device, a miniature detonator needs to be developed to reduce the weight and volume of explosive train. A Si-based micro-detonator is designed and fabricated, which meets the requirement of MEMS safety and arming device. The firing sensitivity of micro-detonator is tested according to GJB/z377A-94 sensitivity test methods: Langlie. The function time of micro-detonator is measured using wire probe and photoelectric transducer. The result shows the average firing voltage is 6.4 V when the discharge capacitance of firing electro-circuit is 33 μF. And the average function time is 5.48 μs. The firing energy actually utilized by Si-based micro-detonator is explored.     

Thermodynamics and performance of Al/CuO nanothermite with different storage time

The storage stability of energetic materials is important for its application. Here, the storage stability of Al/CuO nanothermite, which was prepared by electrospray method and stored with different storage time, was systematically researched. The activation energy of Al/CuO nanothermite was calculated by differential scanning calorimetry (DSC). The ignition temperature and the curve pressure history of Al/CuO nanothermite was measured using ignition temperature measuring device and constant-volume pressurization tests, respectively. Further, the thermites were characterized by X-ray Diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and Transmission electron microscopy (TEM). The results show that the morphology of the thermites did not change significantly. The activation energy was decreased from 254.1 kJ/mol to 181.8 kJ/mol after storage for 13 months. When stored for 0, 7 and 13 months, the peak pressures of Al/CuO nanothermite were 685.8 kPa, 626.3 kPa and 625.5 kPa, respectively. In addition to the ignition temperature, it was 775 ℃, 739 ℃ and 754 ℃, respectively. This result indicated that the ignition and combustion properties of Al/CuO nano-thermite are obviously reduced when stored for a long time, at room temperature.     

铝导线短路熔珠对固体可燃物引燃能力实验研究

在模拟试验平台上进行了铝导线短路熔珠引燃棉布、聚氨酯泡沫塑料和纸张的试验，得到了不同材料的临界加栽电压值和引燃规律。初步分析了加栽电压与短路熔珠粒径及引燃能力的关系。结果表明，随着短路电压增大，导线熔珠的粒径逐渐增大，熔珠对固体材料的引燃能力逐渐增强，氧指数越低、表面粗糙、易蓄热的材料越容易被点燃。棉布、聚氨酯泡沫塑料和纸屑被引燃的短路临界电压分别为50V、35V和45V。     

利用镁金属化学还原法制备多孔Si/Si-O-C负极材料机理研究

以二乙烯基苯和聚硅氧烷为原料经先驱体转化法制备了Si-O-C材料，利用镁金属在惰性气氛保护下高温还原制备了多孔的Si/Si-O-C负极材料。Si/Si-O-C负极材料的首次放电与充电容量分别为547.2和450.7mAh?g-1，第二次放电与充电容量分别为487.4和422.9mAh?g-1，库伦效率分别为82.3%、86.8%，材料具有较好的循环性能。利用X射线衍射(XRD)、能谱分析(EDX)、元素分析和场发射扫描电镜(FE-SEM)分析了多孔Si/Si-O-C负极材料的组成、结构、形貌，从而研究利用镁金属化学还原法制备多孔Si/Si-O-C负极材料的机理。结果表明，镁金属在还原过程中生成MgO和Mg2SiO4等产物，经HCl洗涤后可形成多孔的Si/Si-O-C负极材料。Si/Si-O-C材料中的单质硅分布于多孔的Si-O-C相中，一定程度上可缓解Si在循环过程中产生的体积效应。利用镁金属还原Si-O-C材料制备多孔Si/Si-O-C材料是一种可行的制备方法。     

Research on fuze microswitch based on corona discharge effect

Abnormal voltages such as electrostatic, constant current, and strong electromagnetic signals can erro-neously trigger operation of MEMS pyrotechnics and control systems in a fuze, which may result in casualties. This study designs a solid-state micro-scale switch by combining the corona gas discharge theory of asymmetric electric fields and Peek's Law. The MEMS switch can be transferred from "off" to"on" through the gas breakdown between the corona electrodes. In the model, one of the two electrodes is spherical and the other flat, so a non-uniform electric field is formed around the electrodes. The theoretical work is as follows. First, the relation among the radius of curvature of the spherical electrode, the discharge gap, and the air breakdown voltage is obtained; to meet the low voltage (30-60 V) required to drive the MEMS switch, the radius of curvature of the spherical electrode needs to be 10-50 μm and the discharge gap between the two electrodes needs to be 9-11 μm. Second, the optimal ratio ε is introduced to parameterize the model. Finally, the corona discharge structural parameters are determined by comparing the theoretical and electric field simulation results. The switch is then fabricated via MEMS processing. A hardware test platform is built and the performing chip tested. It is found that when the electrode gap is 9 μm, the electrostatic voltage is at least 37.3 V, with an error of 2.6% between the actual and theoretical air breakdown voltages. When the electrode gap is 11 μm, the electrostatic voltage is at least 42.3 V, with an error of 10.5% between the actual and theoretical air breakdown voltages. Both cases meet the design requirements.     

Combustion of B4C/KNO3 binary pyrotechnic system

Presented herein is an experimental study on the combustion of B4C/KNO3 binary pyrotechnic system.Combustion products were tested using X-ray diffraction(XRD),scanning electron microscopy(SEM),and energy dispersive spectrometer(EDS).According to the results of tests and CEA calculation,the combustion reaction equation was established.The flames and burning rates were recorded by a high speed camera and a spectrophotometer.The effect of B4C particle size on the thermal sensitivity of B4C/KNO3 was investigated by differential scanning calorimetry(DSC)techniques.In addition,a reliable method for calculating the flame temperature was proposed.Based on the results of experiments,the combustion reaction mechanism was briefly analyzed.The burning rate,flame temperature and thermal sensitivity of B4C/KNC3 increase with the decrease of B4C particle size.The mass ratio of B4C/KNO3 has a great effect on combustion properties.Oxidizer-rich compositions have low flame temperatures,low burning rates,and provide green light emission.The combustion reactions of fuel-rich compositions are vigorous,and the B4C/KNO3 with mass ratio of 25:75 has the highest burning rate and the highest flame temperature.     

某型火箭弹电点火系统雷电辐照效应研究

利用LSG-8015型雷电浪涌发生器与平行板传输线配合模拟雷电电磁脉冲辐射场,对整装状态下水平放置的某型火箭弹进行了辐照试验。比较了不同放电电压下某型火箭弹电点火系统的感应电压波形,试验了短路防护卡对雷电电磁脉冲的防护性能,提出了某型火箭弹雷电电磁脉冲防护的思路和方法。     

复合导线高电导性的实验及其应用前景

分析了铜包钢和铜导线内导体同轴电缆的电性能检测实验,从而证实复合导线的高电导特性,并指出该特性的应用前景和实用价值.