FOX-7/HMX混合体系热性能研究

为研究FOX-7及其与HMX混合体系的热性能,采用差示扫描量热仪(DSC)、热常数分析仪等手段,对HMX与FOX-7等质量比共混物、以及具有不同HMX与FOX-7比例的炸药配方的热分解行为、导热性质等开展了研究。结果表明：在FOX-7/HMX混合体系中,HMX与FOX-7的分解放热以及晶型转变吸热过程可相互影响：HMX在247.3℃处已有部分分解,282.5℃出现的放热峰对应于HMX的分解放热峰和FOX-7的第2步分解峰的叠加;而FOX-7的β到γ晶型转变以及HMX的β到δ晶型转变吸热峰相较于单质颗粒,分别延迟了8.5℃、9.5℃。配方中HMX与FOX-7的相对含量决定了两者的分解峰温,这可能与两者热效应的相互影响及粘结剂对炸药颗粒包覆完整度有关：随着配方中HMX含量由25%增加至60%,其熔融吸热峰由276.6℃提前至252.5℃;随着配方中FOX-7含量由25%增加至60%,其第1步分解峰和HMX的熔融分解过程相互影响,导致只出现一个分解放热峰,FOX-7第1步分解反应放热将导致其更早发生熔融分解。FOX-7颗粒的热导率、热扩散系数、比热容都高于HMX。在总含量不变的情况下,随着F...     

聚甲基丙烯酰亚胺的制备研究

以甲基丙烯腈(MAN)、甲基丙烯酸(MAA)和甲基丙烯酰胺(MAM)为主要单体原料,过氧化物引发共聚制得甲基丙烯腈-甲基丙烯酸-甲基丙烯酰胺(MAN-MAA-MAM)共聚物.详细研究了所制备共聚物的高温环化反应,以及所生成的聚甲基丙烯酰亚胺(PMI)的耐热性能.结果表明,MAN-MAA-MAM 共聚物的环化温度为160℃,所制备的聚甲基丙烯酰亚胺(PMI)在空气中可耐280℃的高温.     

PPQ-b-PEG刚柔嵌段共聚物的合成及热稳定性

以聚乙二醇单甲醚、丁二酸酐、4-氨基苯乙酮、5-乙酰基-2-氨基二苯甲酮为原料合成了以聚苯基喹啉(PPQ)为硬段、聚乙二醇(PEG)为软段的"刚棒—线团"两嵌段共聚物PPQ b PEG,通过IR、1HNMR对其结构进行了表征,并对PPQ b PEG嵌段共聚物的热稳定性进行研究,结果表明:PPQ b PEG(d)的热稳定性高,PPQ b PEG起始的分解温度为250℃,在250～400℃失重很少,其失重率小于5%,在400～600℃才迅速失重,到620℃时彻底分解。     

聚氨酯的合成及水声性能

用甲苯-2,4-二异氰酸酯(2,4-TDI)、聚丙二醇(PPG)等原料合成了聚氨酯预聚体,以3,3-二氯-4,4-二氨基二苯甲烷(MOCA)、三羟甲基丙烷(TMP)为扩链剂合成了聚氨酯,在脉冲声管中测试了合成试样的声压反射系数和吸声系数,研究了不同扩链剂及不同含量的2,6-二叔丁基-4-甲基苯酚(BHT)对其水下声学性能的影响。测试结果表明:TDI-PPG-MOCA合成型聚氨酯是一种良好的水下透声材料,TDI-PPG-TMP合成型聚氨酯是一种良好的水下吸声材料;BHT的加入对TDI-PPG-TMP合成型聚氨酯的水下吸声性能有显著提高,因此合理地设计实验工艺参数,可以得到水下声学性能更佳的聚氨酯。     

j不变量等于1728的GLS椭圆曲线上四维

为了实现椭圆曲线的快速倍乘,Gallant-Lamber-Vanstone( GLV)方法被推广到四维的一般情形.文章中回答了Galbraith,Lin和Scott(J.Cryptol.DOI:10.1007/s00145 - 010 - 9065-y)提出的一个公开问题:研究Fp2上j不变量等于1728的GLS椭圆曲线上的四维GLV方法,并给出时间周期.尤其指出GLV的四维分解能够在很大的概率上实现,给出了一些结果和例子.特别指出在同一类曲线上,四维GLV方法的时间周期大概是二维GLV方法的70％～ 73％.     

基于四阶累积量的相干信号二维波达方向估计算法

提出了一种基于四阶累积量的相干信号二维波达方向(DOA)估计的算法--CSS算法.该算法利用双平行线阵的接收数据以及平滑技术构造了一个平滑的渡达方向矩阵,通过对其进行特征分解估计出空间相干信号的二维到达角.在色噪声环境下,该算法能够精确地估计空间相干信号的二维到达角,无需谱峰搜索,并且信号的二维参数能够自动配对.计算机仿真结果验证了算法的有效性.     

酚醛-石英混杂纤维增强苯并噁嗪复合材料高温失效特征

通过模压工艺制备了酚醛-石英混织纤维增强苯并噁嗪复合材料(P-Q/BZ)试样,考察了其力学性能、烧蚀性能和耐冲刷性能,分析了该试样在高温环境中的主要失效特征,研究其在高温环境中的适用性。结果表明,未经热处理的P-Q/BZ试样平均弯曲强度、弯曲模量和层间剪切强度分别为283 MPa、10.8 GPa和22.6 MPa;经300℃,N_2处理15 min后,试样均匀膨胀,厚度增加22%,弯曲强度、弯曲模量和层间剪切强度分别下降58%、41%和58%;在氧乙炔焰的平均质量烧蚀率和线烧蚀率分别为0.048 4 g/s和-0.081 mm/s,烧蚀后试样宏观不分层,表面炭层微观分层严重,酚醛纤维热解炭、树脂基体热解炭、熔融石英纤维以及碳硅氧化产物相互分离;该试样耐冲刷能力差,在发动机尾焰烧蚀平台模拟的热-力耦合环境中的质量损失率高达59%。P-Q/BZ复合材料需要解决热解膨胀问题,进一步提高抗冲刷性能。     

An Unlikely Alliance: Portuguese and South African Airpower in Angola, 1968–1974

The war that Portugal was obliged to fight in Africa began in 1961 and immediately stretched the resources of its armed forces. Nowhere was this thinness more apparent than in policing the vast territory of Angola. The east and southeast of Angola were particularly vulnerable, as the area was a vast, sparsely populated region characterised by enormous featureless plains or chanas covered in tall grass and broken by an extensive river system and mountainous forests. The only military solution to policing these immense spaces was aviation and specifically the helicopter that could carry troops into battle, protect them with a gunship and bring them home when the operation was concluded. The immediate problem for the Portuguese Air Force (Força Aérea Portuguesa or FAP) in Angola and elsewhere was a scarcity of helicopters. The solution was an alliance with South Africa, which had a strong inventory of Alouette IIIs, to help in policing the east. This move was likewise in the interest of South Africa, as its threat came from Zambia through south-eastern Angola. This article examines the strategic and tactical development of this unusual, cross-cultural alliance and the symbiotic relationship that resulted in destruction of the enemies of both in Angola.     

Helping hands: civil–military cooperation and Italy's military operation abroad

In the Post-Bipolar Era the growing complexity of the military operations requires a new approach for the resolution of international crises. Since the end of the Cold War, peace support operations (PSO) have become the mainstay and principal occupation of most Western armies. At the same time, Italy has been one of the most important actors in such an area. The article focuses on the cooperation between military and civil components (a process called CIMIC) as a key variable in the Italian PSOs. We will analyse in detail the main lessons learned from past military interventions as well as the general context in which new tendencies are taking place. The maintaining of a minimum security frame becomes essential to fulfil activities ‘collateral’ to the mission: reconstructing services and infrastructure, food distribution, water and medication, law and order, de-mining, training of local forces, and supporting local institutions. These are the main tasks to obtain thrust and support from the population.     

Terrorism,insurgency, kidnapping,and security in Africa's energy sector

Energy continues to serve as the bedrock of modern economies and the main driver of modern society. For Africa, the production and supply of energy resources such as crude oil, natural gas, uranium, coal, biomass, biofuels and other renewables are an important source of employment, rents, taxes, royalties and profits. This sector brings in several tens of billions of dollars of revenue annually. The production and delivery of such resources, however, depend on critical infrastructures such as pipelines, refineries, processing plants, terminals, rigs, electrical energy pylons, substations, pump stations, vessels, and tankers. These infrastructures have been attacked by terrorists, insurgents, vandals and saboteurs, all of whom see them as targets against which to register their grievances and extract concessions from the state. This paper is a chronological account of some of the documented incidents of terrorism, insurgency, kidnapping, destruction, sabotage, and human casualties suffered in the oil and gas sectors in Africa between 1999 and 2012. It is based on data extracted from the databases of the RAND Database of World Terrorism Incidents and the University of Maryland's Global Terrorism Database (GTD).     

国内外结构钢焊条研究的现状与发展

本文主要介绍了国外焊条的现状和发展趋势,包括焊条的高韧性、高效率、低尘低毒和耐吸潮性能,为国内的焊条研究提供了参考依据。     

A Sign of Victory?: ‘Scottish Swords’ and Other Weapons in the Possession of the ‘Auld Innemie’

Many late medieval documents, notably inventories of arms and armour, of Englishmen contain references to ‘Scottish swords’ and other weapons. What did the compilers of these documents mean when they described a weapon as ‘Scottish’? How did such weapons come to be in the possession of these men? This article will attempt to explain this phenomenon drawing on primary documentary sources and surviving material culture from Glasgow Museums’ collections and others, as well as artworks from the period.     

Tacit support for terrorism: The rapprochement between the USSR and Palestinian guerrilla organizations following the 1967 war

This article demonstrates the inconsistent and wavering Soviet attitude towards national liberation movements in general and the Palestinian organizations in particular. Until the late 1960s, the Soviets viewed these organizations with suspicion, hesitating to engage in political dialogue with them. However, in the 1970s, political and military events in the region, as well as modifications in the Kremlin's Cold War strategies, led to a general shift towards the Middle East in Soviet foreign policy. Soviet leaders showed increased willingness to provide certain Palestinian organizations with arms with which to conduct terrorist activities against Israeli, pro-Israeli, Jewish and Western targets. The article explores the complex relations between Palestinian organizations and the USSR in the field of international terror. The study also exposes and analyzes the nature and content of Soviet–Palestinian arms dialogues and transactions. It provides clear evidence that Soviet policymakers and other luminaries were fully informed of, and sometimes directly involved in, these transactions and dialogues at the highest levels.     

A1 Qaeda and the radical Islamic challenge to western strategy

The September 11 global crisis prompted by the attacks on the World Trade Center and the Pentagon raises major questions concerning the nature and trajectory of terrorism in the post-Cold War global order. Hitherto, terrorism has been largely debated by analysts at the level of nation states. Terrorist and insurgent movements have also been largely anchored in nationalist and ethnic power bases even when they have sought to mobilise a transnational ideological appeal on religious or class grounds. There have been a few exceptions to this pattern such as the alliance between the German Baader-Meinhof group and the Japanese Red Army Faction, but even such international alliances as this did not, until at least the 1980s, presage anything like a global terrorist network necessitating a global strategic response. This study examines terrorism and global strategic responses.     

Helping hands: external support for the KNU insurgency in Burma

This article analyses to what extent the Burmese KNU insurgency made use of external support from states, refugees, and diasporas. Based on extensive fieldwork it is concluded that support from neighbouring states and refugees has for years kept the Karen rebellion alive. Western countries perceived forms of resistance to the illegitimate Burmese regime as just and have therefore played a crucial role in the continuation of conflict in Karen State. It is important that policymakers and donors as well as executing organizations continue to reflect critically on the way they exercise their work.