Study of nano-nitramine explosives: preparation,sensitivity and application

Nano-nitramine explosives (RDX, HMX, CL-20) are produced on a bi-directional grinding mill. The scanning electron microscope (SEM) observations show that the prepared particles are semi-spherical, and the narrow size distributions are characterized using the laser particle size analyzer. Compared with the micron-sized samples, the nano-products show obvious decrease in friction and impact sensitivities. In the case of shock sensitivities, nano-products have lower values by 59.9% (RDX), 56.4% (HMX), and 58.1% (CL-20), respectively. When nano-RDX and nano-HMX are used in plastic bonded explosives (PBX) as alternative materials of micron-sized particles, their shock sensitivities are significantly decreased by 24.5% (RDX) and 22.9% (HMX), and their detonation velocities are increased by about 1.7%. Therefore, it is expected to promote the application of nano-nitramine explosives in PBXs and composite modified double-based propellants (CMDBs) so that some of their properties would be improved.     

聚能射流形成过程的理论建模与分析

分析了聚能射流的形成过程,并对其中的各阶段进行了详细建模。在模型中考虑了炸药爆轰、金属的驱动、药型罩压垮以及射流和杵体的形成过程。采用该模型对某一聚能装药结构进行了计算,计算结果表明:药型罩顶部和底部微元的压垮速度较小,在射流头部形成反向速度梯度,与试验数据吻合较好。该模型对于多级侵彻战斗部的工程设计与侵彻参数的计算具有一定的参考价值。     

圆柱形容器爆炸焊接数值模拟与实验

针对深空探测采样容器的特殊要求,进行爆炸焊接严实密封技术研究。利用非线性动力学软件进行铝质柱形容器爆炸焊接数值模拟,得到各种焊接初始参数的影响规律,确定较佳焊接初始参数及容器结构尺寸,并进行实验验证。实验结果表明:外盖角度为7°时,1mm壁厚外盖配4mm壁厚内圆柱或2mm壁厚外盖配6mm壁厚内圆柱,配以较合适炸药厚度,密实焊接效果较理想。研究结果为深空探测采样容器结构设计提供了较好的参考。     

基于ANSYS／LS—DYNA的电子装备爆炸冲击振动损伤建模研究

针对电子装备爆炸冲击振动损伤问题,设计了损伤模拟的基本方案;采用ANSYS／LS—DYNA建立了二维“爆炸源-地面-弹性体-电子装备”模型;通过模型试验,获得了与实际爆炸冲击振动特性相吻合的加速度、位移和应力等数据。     

爆炸逻辑间隙零门实验研究

为了可靠实现爆炸逻辑间隙零门的原理功能,提出并验证了一种基于精细RDX和含能胶合剂的传爆药方案.通过实验探索了基于该传爆药的爆炸零门适用的间隙宽度范围,并设计了一种小尺寸爆炸逻辑间隙零门,为爆炸逻辑网络设计提供参考.     

煤层气加气站火灾爆炸危险性分析及消防对策

根据太原市煤层气加气站的具体情况,从设备安全、规范化安全管理等方面分析了CNG加气站的火灾爆炸危险性,探讨煤层气加气站消防安全的技术措施及对策。     

溶胶—凝胶法合成氧化铝—氧化硅纳米粉

以AlCl3*6H2O和(CH2)6N4为原料,用溶胶-凝胶法合成出比表面积为189.6m2/g的γ相氧化铝粉,平均粒径约为9nm.以铝溶胶和硅溶胶为原料,用溶胶-凝胶法合成出反应活性高的Al2O3-SiO2复合粉体.该粉体在1300℃煅烧后转变为莫来石.     

用溶胶-凝胶法制备碳纤维三维编织物增强氧化铝基复合材料的研究

本文研究了溶胶－凝胶（Ｓｏｌ－ｇｅｌ）法制备碳纤维三维编织物增强氧化铝（Ａｌ２Ｏ３）基复合材料的成型工艺及其力学性能，研究了两种主要起始物Ａｌ（ＮＯ３）３、ＡｌＣｌ３配制的氧化铝溶胶对复合材料成型工艺和力学性能的影响。分别以Ａｌ（ＮＯ３）３和ＡｌＣｌ３为起始物，制备得到Ⅰ＃、Ｉ＃复合材料。研究表明，以Ａｌ（ＮＯ３）３为起始物配制的溶胶粘度较小，利于材料的致密化。经过溶胶浸渍、凝胶、裂解１３个周期后，Ⅰ＃材料的密度和室温三点弯曲强度分别为１．８６ｇ／ｃｍ３和１４５．２ＭＰａ，而ＩＩ＃材料的密度和室温三点弯曲强度分别为１．６３ｇ／ｃｍ３和１０４．１ＭＰａ，材料均呈典型的韧性断裂模式。用扫描电子显微镜（ＳＥＭ）观察试样的断口形貌，发现断口表面有大量的纤维拔出，纤维表现了较好的增韧效果。     

单质炸药和样品混合炸药热分解反应动力学参数的研究

本文用差示扫描量热仪(DSC7)测得了几种单质炸药和样品混合炸药的非等温DSC曲线,对热分解反应速率方程进行了研究,编制了由一条非等温DSC曲线的信息计算炸药热分解反应动力学参数的程序,并证明DSC的线性升温速率对动力学参数没有明显影响。     

The investigation of NTO/HMX-based plastic-bonded explosives and its safety performance

3-nitro-1,2,4-triazol-5-one (NTO) is the main component of insensitive munitions (IM) formulation because of its outstanding insensitive properties.In this paper,a series of NTO/HMX-based composite explosives were prepared and characterized.The study focuses on the effect of NTO on the performance of the formulations,especially the safety performance.The results revealed that the mechanical sensi-tivity of formulations was associated with NTO content,as well as the thermal conductivity,specific heat capacity and Arrhenius parameters.Then,the high amount of NTO using in formulation was proved to be helpful for NTO/HMX-based formulation to exhibit good thermal safety.Besides,by accelerating rate calorimeter (ARC) and a modified cook-offequipment,the pressure and pressure rise rate were proved as the important indicator for judging the thermal safety performance in confined spaces.Finally,the numerical simulation was used as a credible method for predicting the respond temperature of cook-off experiment.