聚合物材料热危险性分析

聚合物材料具有的易燃性或可燃性使其在实际应用中具有潜在的火灾危险性,正确分析评价聚合物材料的火灾危险性,对材料的安全使用和火灾预防与控制具有重要的作用。在综述文献的基础上,根据火灾危害的特征,对聚合物材料的引燃、热释放和火焰传播等热危险性进行了分析和总结,并提出了相应的预防对策。     

Polymer composite for antistatic application in aerospace

The phenomenon of static electricity is unpredictable, particularly when an aircraft flying at high altitude that causes the accumulation of static charges beyond a threshold value leading to the failure of its parts and systems including severe explosion and radio communication failure. The accumulation of static charges on aircraft is generated by the virtue of interaction between the outer surface of aircraft and the external environmental attributes encompasses air particles, ice, hail, dust, volcanic ash in addition to its triboelectric charging. In the recent years, advanced polymer-based composites or nanocomposites are preferred structural constituents for aircrafts due to their light weight and comparable mechanical properties, but such composite systems do not render low impedance path for charge flow and are subsequently vulnerable to effect of lightning strike and precipitation static. In this context, it is essential to develop conductive composite systems from non-conductive polymer matrix by nanofiller embodiments. The advent of carbon-based nanocomposite/nanomaterials have adequately addressed such issues related to the nonconductive polymer matrix and further turned into an avant-garde genre of materials. The current review envisioned to illustrate the detailed exploitation of various polymer nanocomposites in addition to especially mentioned epoxy composites based on carbon fillers like carbon black, carbon nanotube (single walled carbon nanotube and multi walled carbon nanotube) and graphene the development of antistatic application in aircraft in addition to the static charge phenomenon and condition for its prevalence in avionic systems.     

Experimental investigations on wear properties of Palm kernel reinforced composites for brake pad applications

The use of asbestos material is being avoided to manufacture the brake pads as it is harmful and toxic in nature. Further it leads to various health issues like asbestosis, mesothelioma and lung cancers. These brake pads can be replaced by natural fibers like Palm kernel (0–50%), Nile roses (0–15%) and Wheat (0–10%) with additives like aluminum oxide (5%–20%) and graphite powder (10%–35%). Phenolic resin of 35% is utilized as a binder. Particulated Nile roses are used to increase the friction coefficient and wheat powder is used to reduce the wear rate. Aluminum oxide and graphite are abrasive in nature. This helps to make brake pads with high friction co-efficient and less wear rate with low noise pollution. The wear of the proposed composites have been investigated at different speeds. Various tests like wear on pin-on-disc apparatus, hardness on the Rockwell hardness apparatus and oil absorption test have been conducted. Phenolic resin produces good bonding nature to fiber. Thus, Fibers found to have performed palatably among all commercial brake pads. The objective of the research indicates that Palm kernal shell could be a conceivable alternative for asbestos in friction coating materials.     

基于步进应力加速老化和改进Arrhenius模型的橡胶贮存寿命预测

为准确、快速地预测橡胶的贮存寿命,在步进高温应力加速老化试验的基础上,对不同加速温度下的加速系数进行计算,获得加速因子和绝对温度倒数的曲线,发现橡胶老化过程表现出非Arrhenius特性。针对非Arrhenius特性,引入幂指数因子,采用一种改进的Arrhenius模型对加速系数进行拟合。由对数反应速率与绝对温度倒数曲线的斜率,计算了改进Arrhenius模型在不同温度下的等效线性活化能,结果表明低温下活化能减小。建立低温下的老化寿命模型,对胶料在10℃,20℃和30℃下的老化寿命进行评估。评估结果表明,该模型可为相关高分子材料腐蚀过程中呈现的非Arrhenius特性的分析及寿命预测提供参考。     

压电材料中的共线非等长多裂纹问题

建立了横观各向同性压电材料中的共线非等长多裂纹模型。将裂纹模拟为连续分布的广义位错,推导了单点广义位错的格林函数,并基于此得到了共线非等长多裂纹的奇异积分方程组,最后由数值计算给出了裂纹尖端的能量释放率。对奇异积分方程组的退化分析和对称条件下的数值结果的讨论,验证了本文结果的正确性。研究表明:当共线裂纹间距小于裂纹长度时,裂纹尖端场存在显著的干涉效应;裂纹越长,干涉效应越显著;电载荷系数越大,能量释放率也越大;相对于外侧尖端而言,共线裂纹内侧尖端对电载荷系数更为敏感。     

压电界面电极的应力强度因子

建立了压电界面电极的力学模型，利用有限傅里叶变换方法将相应的力电耦合问题描述为奇异积分方程，并得到了界面应力及其强度因子的解析解。讨论了结构几何参数对应力强度因子的影响。基于强度设计的观点得到两方面的结论：一是界面中心电极优于偏置电极；二是界面长度的最优值为中心电极长度的2倍。     

B4C/Al复合板中应力波行为分析（Ⅰ）

依据7.62mm穿甲燃烧弹与B4C,Al板的物理和力学特性,提出弹、板的力学模型;在此基础上,给出弹板碰撞后B4C/Al复合板的弹性动力学方程,建立应力波的传播模型,讨论了应力波传播时复合板的力学行为,最后确定了复合板承受的初始冲击应力。理论分析表明：一维应变条件的B4C和Al板的弹性极限高于一维应力条件下的值;弹、板间的作用力服从指数衰减规律;B4C板的初始应力高于430MPa时,应力波的作用使Al板在卸载过程中发生反向屈服。     

对央视新址北配楼火灾的思考

从央视新址北配楼火灾着手，通过分析火灾的特点，从加强烟花爆竹安全管理及宣传教育、建筑外部装修消防安全、改进对建筑工程及施工现场的消防监督工作和对高层建筑限高、加强“六熟悉”方面提出了防止类似高层建筑火灾发生的措施。     

剪切变形对夹芯复合材料悬臂箱梁挠度的影响

为了分析剪切变形对夹芯复合材料悬臂箱梁挠度的影响,推导了夹芯复合材料薄壁箱梁的等效弯曲刚度和剪切刚度,将夹芯复合材料悬臂箱梁等效为具有等跨度等刚度的均质箱梁;利用初等梁理论得到了考虑剪切变形的夹芯复合材料悬臂箱梁的挠曲线方程;分析了剪切变形对夹芯复合材料薄壁箱梁挠度的影响,为复合材料薄壁箱梁的设计提供了理论参考.     

Ni-Co-P／导电聚苯胺复合材料电磁和红外性能

采用化学镀对高氯酸掺杂聚苯胺（PANI/HClO4）粉体进行Ni-Co-P合金化改性,改性材料磁损耗因子得到提高。进行红外光谱分析,PANI/HClO4在3-5μm和8-14μm 2个大气窗口没有强吸收峰,具有雷达红外隐身兼容特性。