大气中二氧化碳分离技术的研究与现状

本文概要介绍了潜艇和载人航天器舱内二氧化碳分离去除的４种主要方法：碱吸收法、吸附法、电化学法和膜法,并就该技术领域的历史与现状、各种方法的优缺点和具体的应用情况,以及今后国内外的发展趋势进行了分析与评述。     

单晶硅反射镜激光能量吸收系数与衬底表面质量的关联

高能激光系统中,单晶硅基底反射镜的能量吸收系数是影响系统性能的关键指标。衬底加工质量对镀膜后元件激光能量吸收系数影响显著。通过测试不同衬底粗糙度、划痕密度的单晶硅反射元件,分析衬底表面典型加工特征(粗糙度、划痕)对激光能量吸收系数的影响规律,认为粗糙度与吸收系数正相关,粗糙度均方根从0.668nm降低至0.345nm会使吸收系数降低28.0%。少量划痕对吸收系数的直接影响并不明显,吸收系数均值变化在3.1%以内。但表面划痕会诱发激光损伤,划痕密度较大时会引起后续能量吸收持续增大,辐照400s后,吸收系数较辐照100s时增大18.3%。     

碱性焊条 Al 和V对焊缝金属扩散氢的影响

通过实验和理论分析,研究了Ａｌ、Ｖ加入碱性焊条药皮对其吸湿性和焊缝金属扩散氢ＨＤ的影响．结果表明：Ａｌ、Ｖ对焊条药皮吸湿性均无影响,Ｖ能一定程度降低而Ａｌ却提高ＨＤ．     

夹杂物对有机涂层下碳钢腐蚀初期过程的影响

选择两种具有典型夹杂物的碳钢,通过浸泡试验,研究有机涂层下碳钢的腐蚀初期过程,并和裸钢的腐蚀过程进行对比．结果表明：涂层试样和裸钢试样腐蚀发展的初期过程都是点蚀;涂层试样点蚀诱发孕育期大大长于裸钢试样;点蚀的主要诱发源是钢中的硫化物和硅酸盐;硫化物夹杂物诱发点蚀及点蚀的扩展主要沿夹杂物与基体间的相界进行．     

吸收光谱法测量COIL水含量的实验研究

介绍了吸收光谱测量水蒸汽绝对浓度的方法,标定了实验环境下水蒸汽的吸收系数,并在氧碘化学激光器(COIL)上进行了初步的实验研究.测量结果显示,在常规工作条件下由于BHP温度变化所引起的水汽百分含量变化可以忽略,气体流速是引起水汽含量变化的主要原因.     

Mechanical properties and thermal conductivity of pristine andfunctionalized carbon nanotube reinforced metallic glass composites:A molecular dynamics approach

This work uses the molecular dynamics approach to study the effects of functionalization of carbon nanotubes (CNTs) on the mechanical properties of Cu64Zr36 metallic glass (MG). Three types of functional groups, carboxylic, vinyl and ester were used. The effect of CNT volume fraction (Vf) and the number of functional groups attached to CNT, on the mechanical properties and thermal conductivity of CNT-MG composites was analysed using Biovia Materials Studio. At lower values of Vf (from 0 to 5％), the per-centage increase in Young's modulus was approximately 66％. As the value of Vf was increased further (from 5 to 12％), the rate of increase in Young's modulus was reduced to 16％. The thermal conductivity was found to increase from 1.52 W/mK at Vf=0％to 5.88 W/mK at Vf=12％, thus giving an increase of approximately 286％. Functionalization of SWCNT reduced the thermal conductivity of the SWCNT-MG composites.     

Effect of organo-modified montmorillonite nanoclay on mechanical,thermal and ablation behavior of carbon fiber/phenolic resin composites

The mechanical, thermal and ablation properties of carbon phenolic (C-Ph) composites (Type-I) rein-forced with different weight percentages of organo-modified montmorillonite (o-MMT) nanoclay have been studied experimentally. Ball milling was used to disperse different weight (wt) percentages (0, 1,2,4,6 wt.％) of nanoclay into phenolic resin. Viscosity changes to resin due to nanoclay was studied. On the other hand, nanoclay added phenolic matrix composites (Type-II) were prepared to study the dispersion of nanoclay in phenolic matrix by small angle X-ray scattering and thermal stability changes to the matrix by thermogravimetric analyser (TGA). This data was used to understand the mechanical, thermal and ablation properties of Type-I composites. Inter laminar shear strength (ILSS), flexural strength and flexural modulus of Type I composites increased by about 29％, 12％and 7％respectively at 2 wt.％ addition of nanoclay beyond which these properties decreased. This was attributed to reduced fiber volume fraction (％Vf) of Type-I composites due to nanoclay addition at such high loadings. Mass ablation rate of Type-I composites was evaluated using oxy acetylene torch test at low heat flux (125 W/cm2) and high heat flux levels (500 W/cm2). Mass ablation rates have increased at both flux levels marginally up to 2 wt.％ addition of nanoclay beyond which it has increased significantly. This is in contrast to increased thermal stability observed for Type-I and Type-Ⅱ composites up to 2 wt.％addition of nanoclay. Increased ablation rates due to nanoclay addition was attributed to higher insulation effi-ciency of nanolcay, which accumulates more heat energy in limited area behind the ablation front and self-propagating ablation mechanisms triggered by thermal decomposition of organic part of nanoclay.     

Experimental investigation for machinability aspects of graphene oxide/carbon fiber reinforced polymer nanocomposites and predictive modeling using hybrid approach

This article explores the drilling behavior of polymer nanocomposites reinforced by Graphene oxide/Carbon fiber using a hybrid method of Grey theory and Principal component analysis (GR-PCA). An online digital dynamometer was employed for the evaluation of Thrust Force and Torque. The image processing technique computes the delamination. Response surface methodology (RSM) considers the parameters, namely, drilling speed (S), feed rate (F), Graphene Oxide wt.% (G) in designing the experimentation array. Principal component analysis (PCA) was used to tackle the response priority weight during the combination of multiple functions. Analysis of variance (ANOVA) scrutinized the influence of parameters and intended the regression models to predict the response. GR-PCA evaluated the optimal parametric setting and remarked that feed rate acts as the most predominant factor. The higher feed rate and wt.% of G is responsible for surface damages like fiber pull-out, fiber fracture and cracks. A significant improvement in drilling responses has been obtained and also validates through confirmatory test and microstructure investigations.     

Investigation of the mechanical and ballistic properties of hybrid carbon/ aramid woven laminates

High-performance ballistic fibers, such as aramid fiber and ultra-high-molecular-weight polyethylene (UHMWPE), are commonly used in anti-ballistic structures due to their low density, high tensile strength and high specific modulus. However, their low modulus in the thickness direction and insufficient shear strength limits their application in certain ballistic structure. In contrast, carbon fiber reinforced epoxy resin matrix composites (CFRP) have the characteristics of high modulus in the thickness direction and high shear resistance. However, carbon fibers are rarely used and applied for protection purposes. A hybridization with aramid fiber reinforced epoxy resin matrix composites (AFRP) and CFRP has the potential to improve the stiffness and the ballistic property of the typical ballistic fiber composites. The hybrid effects on the flexural property and ballistic performance of the hybrid CFRP/AFRP laminates were investigated. Through conducting mechanical property tests and ballistic tests, two sets of reliable simulation parameters for AFRP and CFRP were established using LS-DYNA software, respectively. The experimental results suggested that by increasing the content of CFRP that the flexural properties of hybrid CFRP/AFRP laminates were enhanced. The ballistic tests’ results and the simulation illustrated that the specific energy absorption by the perforation method of CFRP achieved 77.7% of AFRP. When CFRP was on the striking face, the shear resistance of the laminates and the resistance force to the projectiles was promoted at the initial penetration stage. The proportion of fiber tensile failures in the AFRP layers was also enhanced with the addition of CFRP during the penetration process. These improvements resulted in the ballistic performance of hybrid CFRP/AFRP laminates was better than AFRP when the CFRP content was 20 wt% and 30 wt%.     

超声波辅助微波消解预处理测量污泥金属元素

以实验室污泥和污水厂污泥为研究对象,建立了超声波辅助微波消解预处理测量污泥金属元素的方法与程序。首先通过超声波分散污泥絮体,然后对污泥进行加热预处理和微波消除,最后采用火焰原子吸收法测量污泥中的金属元素。结果表明,150 W超声波作用于25 mL污泥3 min为超声波分散污泥的较优条件,能保证后续操作过程取样均匀。微波消解前适宜的加热预处理条件为90℃,20 min。实验室污泥微波消解的较优酸体系为2 mL双氧水＋4 mL反王水（或4 mL王水）;污水厂污泥微波消解的较优酸体系为1 mL氢氟酸＋2 mL双氧水＋4 mL王水,同时,第3阶段消解条件为压强2.0 MPa下消解20 min。超声波辅助微波消解预处理具有用酸量少、简易快捷、准确度和精密度高等优点,测量K,Ca,Mg,Fe的相对标准偏差≤2.75%,加标回收率为97.5%～102%。