列车用复合材料阻燃性能研究

不同类别的阻燃剂配合使用能产生协效作用,大大提高阻燃效果。在甲基丙烯酸类不饱和聚酯树脂9001基体中,添加微囊化红磷/氢氧化铝/三氧化二锑/甲基膦酸二甲酯(MRP/Al(OH)3/Sb2O3/DMMP)阻燃剂体系,对其树脂体系固化物及玻璃纤维织物复合材料的力学性能和阻燃性能进行了实验研究,提出了一种有望用于列车复合材料大尺寸构件制造的性能优异、价格低廉的新体系。结果表明,当质量添加比例分别为12%MRP、50%Al(OH)3、2%Sb2O3时,树脂体系室温粘度100mPa.s左右,凝胶时间超过80min,适用于RTM和VIMP等大尺寸构件成型工艺;复合材料拉伸强度215.4MPa,弯曲强度177.15MPa,拉伸模量13.85GPa,弯曲模量13.36GPa,氧指数39.7。     

烧结助剂对碳纳米管增强氮化铝陶瓷结构与性能的影响

采用热压烧结工艺制备了碳纳米管增强氮化铝陶瓷,研究了烧结助剂种类、含量对碳纳米管增强氮化铝陶瓷性能及结构的影响.利用XRD、SEM和TEM等分析测试手段对其相组成,断口形貌和微观结构进行了分析.结果表明,烧结助剂Y2O3+CaF2较YE3+CaF2更能促进碳纳米管增强氮化铝陶瓷致密化,但随烧结助剂Y2O3+CaF2含量的增加,碳纳米管增强氮化铝陶瓷致密度提高,而力学、导热性能下降.     

Ni-Zn铁氧体粉末的溶胶-凝胶合成及微波性能

以硝酸铁、硝酸镍、硝酸锌、柠檬酸和氨水为原料,用溶胶-凝胶法合成了不同组成的Ni-Zn铁氧体粉末。利用热分析、X射线衍射等手段研究了干凝胶热分解行为。利用网络分析仪对铁氧体粉末的电磁性能进行了表征,考察了铁氧体的组成与其电磁性能之间的关系。结果表明,溶胶-凝胶法合成的铁氧体粉末的μ″值随测试频率的提高和Ni-Zn铁氧体中锌含量的增加而减小。     

Evaluation of infrared camouflage effectiveness via a multi-fractal method

This paper reports an alternative approach to the evaluation of infrared camouflage effectiveness via a multi-fractal method. By calculating multi-fractal spectra of the target region and the background re-gions in an infrared image, the spectrum shape features and the discrete Fréchet distances among these spectra were used to analyze the camouflage effectiveness of the target qualitatively and quantitatively, and the correlation coefficients of the spectra were further used as the index of camouflage effectiveness. It was found that the camouflaged target had better camouflage effectiveness than the target without camouflage in the same one background, and the same one camouflaged target had different camouflage effectiveness in different backgrounds. On the whole, the target matching well with its background had high camouflage effectiveness value. This approach can expand the application of multi-fractal theory in infrared camouflage technology, which should be useful for the research of infrared camouflage mate-rials, the design of camouflage patterns as well as the deployment of military equipment in battlefield.     

Preparation and characterization of HMX/NH2-GO composite with enhanced thermal safety and desensitization

To improve the safety of HMX, HMX/NH₂-GO composite was prepared with aqueous ammonia functionalized graphene oxide (NH₂-GO). The composite was characterized by SEM, Zeta potential, XPS, Raman spectrum, XRD, HPLC, DSC and BAM sensitivity test. The results indicated that the functionalization with aqueous ammonia can enhance the interaction between GO and HMX, and more efficiently desensitize the explosive. The optimal impact sensitivity of the HMX/NH₂-GO composite can be not less than 40 J, which is also the most insensitivity compared to the previous reports prepared by coating desensitization with non-energetic desensitized material. Moreover, the potential reason for the different impact and friction sensitivity was also discussed, which may bring a novel perspective to achieve the desensitization of energetic material.     

Influence of Al2O3 particles on the microstructure and mechanical properties of copper surface composites fabricated by friction stir processing

The influence of three factors, such as volume percentage of reinforcement particles (i.e. Al₂O₃), tool tilt angle and concave angle of shoulder, on the mechanical properties of Cu–Al₂O₃ surface composites fabricated via friction stir processing was studied. Taguchi method was used to optimize these factors for maximizing the mechanical properties of surface composites. The fabricated surface composites were examined by optical microscope for dispersion of reinforcement particles. It was found that Al₂O₃ particles are uniformly dispersed in the stir zone. The tensile properties of the surface composites increased with the increase in the volume percentage of the Al₂O₃ reinforcement particles. This is due to the addition of the reinforcement particles which increases the temperature of recrystallization by pinning the grain boundaries of the copper matrix and blocking the movement of the dislocations. The observed mechanical properties are correlated with microstructure and fracture features.     

Structure design and property adjustment of new cage rich-nitrogen pentazolyltetraazacubanes as potential high energy density compounds

In this study, based on two attractive energetic compounds pentazole (PZ) and tetraazacubane (TAC), a new family of high energy and high nitrogen compounds pentazolyltetraazacubanes were designed. Then, a different number of NH₂ or NO₂ groups were introduced into the system to further adjust the property. The structures, properties, and the structure-property relationship of designed molecules were investigated theoretically. The results showed that all nine designed compounds have extremely high heat of formation (HOF, 1226-2734 kJ/mol), good density (1.73–1.88 g/cm³), high detonation velocity (8.30–9.35 km/s), high detonation pressure (29.8–39.7 GPa) and acceptable sensitivity (ΔV: 41-87 ų). These properties could be effectively positive adjusted by replacing one or two PZ rings by NH₂ or/and NO₂ groups, especially for the energy and sensitivity performance, which were increased and decreased obviously, respectively. As a result, two designed pentazolyltetraazacubanes were predicted to have higher energy and lower sensitivity than the famous high energy compound in use 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane, while two others have better combination property than 1,3,5-Trinitro-1,3,5-triazacyclohexane. In all, four new pentazolyltetraazacubanes with good combination performance were successfully designed by combining PZ with TAC, and the further property adjustment strategy of introducing a suitable amount of NH₂/NO₂ groups into the system. This work may help develop new cage energetic compounds.     

Inventory policies for a make‐to‐order system with a perishable component and fixed ordering cost

We consider a make‐to‐order production system where two major components, one nonperishable (referred to as part 1) and one perishable (part 2), are needed to fulfill a customer order. In each period, replenishment decisions for both parts need to be made jointly before demand is realized and a fixed ordering cost is incurred for the nonperishable part. We show that a simple (s_n,S,S) policy is optimal. Under this policy, S along with the number of backorders at the beginning of a period if any and the availability of the nonperishable part (part 1) determines the optimal order quantity of the perishable part (part 2), while (s_n,S) guide when and how much of part 1 to order at each state. Numerical study demonstrates that the benefits of using the joint replenishment policy can be substantial, especially when the unit costs are high and/or the profit margin is low. © 2009 Wiley Periodicals, Inc. Naval Research Logistics, 2009     

添加SiC微粉对硅树脂先驱体转化3D Cf/Si-O-C材料性能的影响

以三维碳纤维织物和廉价的硅树脂为原料,采用先驱体转化工艺制备3D G/Si-O-C材料,考察了浸渍液中添加SiC填料对材料微观结构、力学性能和抗氧化性能影响.结果表明:添加适量的SiC填料有助于减少基体孔隙,改善界面结合,从而提高材料的力学性能;而SiC含量过高时,容易在材料内部形成闭孔,从而导致材料力学性能下降.当SiC微粉含量为18.2%时,材料具有最好的力学性能,弯曲强度和断裂韧度分别为421.3MPa和13.0 MPa·m1/2;而材料的抗氧化性能随着SiC微粉含量的增加而增加,当SiC微粉含量为25.0%时,材料的弯曲强度保留率最高,达到了89.5%.     

Preservation of unimodality under shock models

A number of results pertaining to preservation of aging properties (IFR, IFRA etc.) under various shock models are available in the literature. Our aim in this paper is to examine in the same spirit, the preservation of unimodality under various shock models. For example, it is proved that in a non-homogeneous Poisson shock model if {p_k}_K≥0, the sequence of probabilities with which the device fails on the kth shock, is unimodal then under some suitable conditions on the mean value function Λ (t), the corresponding survival function is also unimodal. The other shock models under which the preservation of unimodality is considered in this paper are pure birth shock model and a more general shock model in which shocks occur according to a general counting process. © 1999 John Wiley & Sons, Inc. Naval Research Logistics 46: 952–957, 1999     

表面官能化对碳纳米管/环氧复合材料玻璃化转变温度及韧性的影响

通过碳纳米管的不同表面官能化,构造其与环氧树脂的不同界面。采用动态机械性能分析研究不同表面官能化碳纳米管对环氧树脂复合材料玻璃化转变温度的影响;采用摆锤冲击试验研究环氧树脂复合材料的韧性。结果表明:与纯环氧树脂相比,氨基化碳纳米管/环氧树脂复合材料的玻璃化转变温度升高,而羧基化碳纳米管/环氧树脂复合材料的玻璃化转变温度反而有所下降;碳纳米管/环氧树脂复合材料的冲击强度相比纯环氧树脂均提高了近一倍。复合材料性能的这些变化规律主要归因于不同表面官能化碳纳米管与环氧树脂基体间形成了不同的界面。     

Nitro-tetrazole based high performing explosives: Recent overview of synthesis and energetic properties

Heterocyclic skeleton (Azoles) and different energetic groups containing high performing explosives are highly emerged in recent years to meet the challenging requirements of energetic materials in both military and civilian applications with improved performance. For this purpose tetrazole (Azole) is identified as an attractive heterocyclic backbone with energetic functional groups nitro (-NO₂), nitrato (-ONO₂), nitrimino (-NNO₂), and nitramino (–NH–NO₂) to replace the traditionally used high performing explosives. The tetrazole based compounds having these energetic functional groups demonstrated advanced energetic performance (detonation velocity and pressure), densities, and heat of formation (HOF) and became a potential replacement of traditional energetic compounds such as RDX. This review presents a summary of the recently reported nitro-tetrazole energetic compounds containing poly-nitro, di/mono-nitro, nitrato/nitramino/nitrimino, bridged/bis/di tetrazole and nitro functional groups, describing their preparation methods, advance energetic properties, and further applications as high-performing explosives, especially those reported in the last decade. This review aims to provide a fresh concept for designing nitro-tetrazole based high performing explosives together with major challenges and perspectives.     

Flowshop/no-idle or no-wait scheduling to minimize the sum of completion times

This paper deals with flowshop/sum of completion times scheduling problems, working under a “no-idle” or a “no-wait” constraint, the former prescribes for the machines to work continuously without idle intervals and the latter for the jobs to be processed continuously without waiting times between consecutive machines. Under either of the constraints the problem is unary NP-Complete for two machines. We prove some properties of the optimal schedule for n/2/F, no-idle/σC_i. For n/m/P, no-idle/σC_i, and n/m/P, no-wait/σC_i, with an increasing or decreasing series of dominating machines, we prove theorems that are the basis for polynomial bounded algorithms. All theorems are demonstrated numerically.     

Hyperspectral imaging and remote trace detection of cis-1,3,4,6-tetranitrooctahydroimidazo-[4,5 d] imidazole (BCHMX) compared with traditional explosives using laser induced fluorescence

cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5 d] imidazole (BCHMX) is an advanced energetic compound that expected to spread worldwide in the near future. Since, no approved remote detection methods were reported in current literature for this material, we performed hyper-spectral imaging and laser induced fluorescence (LIF) to a BCHMX sample under low laser fluence for determining the optimum laser wavelength used in any future BCHMX-LIF based remote detection systems. For this purpose, an experimental setup consisted of a sun spectrum lamp and hyper-spectral camera was built to illuminate and image white powder samples of BCHMX in comparison with the traditional explosives, HMX (1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane), RDX (1,3,5-trinitro-1,3,5-triazacyclohexane), PETN (2,2-Bis[(nitroxy)methyl]propane-1,3-diyldinitrate). The imaging reveals strong BCHMX sample absorption contrast among other samples at wavelength ranging from 400 to 410 nm. When light source was replaced by a 405 nm laser diode illuminator, a strong BCHMX sample LIF at the spectral range from 425 to 700 nm was observed under low laser fluence condition of 0.1 mJ/cm². Finally, we demonstrated successfully the ability of the 405 nm LIF and the hyperspectral imaging technique to detect finger print traces of BCHMX on white cellulose fabric from a distance of 15 m and a detection limit of 1 μg/cm².     

植物叶片仿生伪装材料的设计与制备

设计和制备了一种新型的植物叶片仿生伪装材料,其由透明聚氯乙烯表层、叶绿素/聚乙烯醇薄膜、含水高阻隔袋和纸张四层组成.其中,透明聚氯乙烯表层提供防水性能,叶绿素封装于高隔氧材料聚乙烯醇中提高了其光稳定性,水封装于高隔水材料中降低了其蒸发散失速度,纸张提供了类植物叶片的疏松多孔结构.光谱测试结果表明,该仿生伪装材料在可见光...     

Cell structure of microcellular combustible object foamed by supercritical carbon dioxide

In order to solve the issue that the combustible objects for cased telescoped ammunition (CTA) didn't burn completely during the combustion process, the microcellular combustible objects were foamed with numerous cells in the micron order to improve the combustion performance by the supercritical carbon dioxide (SCCO₂) foaming technology. As the cell structure determined the combustion properties of microcellular combustible objects, the solubility of SCCO₂ dissolved into the combustible objects was obtained from the gravimetric method, and scanning electron microscope (SEM) was applied to characterize the cell structure under various process conditions of solubility, foaming temperature and foaming time. SEM images indicate that the cell diameter of microcellular combustible objects is in the level of 1 μm and the cell density is about 10¹¹ cell⋅cm⁻³. The microcellular combustible objects fabricated by the SCCO₂ foaming technology are smooth and uniform, and the high specific surface area of cell structure can lead to the significant combustion performance of microcellular combustible object for CTA in the future.     

Burning rate and other characteristics of strontium titanate (SrTiO3) supplemented AP/HTPB/Al composite propellants

In a quest of search for a new burning rate modifier for composite propellant, strontium titanate (SrTiO₃), a perovskite oxide has been chosen for evaluation in a composite propellant formulation based on its other catalytic applications. Initially, SrTiO₃ was characterized for particle size, morphology and material/phase identification (using XRD). By varying SrTiO₃ content in a standard composite propellant, different compositions were prepared and their performance and processing parameters like the end of mix (EOM) viscosity, mechanical properties, density, burning rate, pressure exponent (n-value), etc. were measured. The results reveal that 2% SrTiO₃ causes more than 12% enhancement in propellant burning rate (at 70 ksc pressure) in comparison to the standard propellant composition. The pressure exponent also increases to 0.46, whereas the standard composition was having its value as 0.35.     

合成孔径雷达成像及工程伪装发展趋势

介绍了星载、机载合成孔径雷达(SAR)成像的发展概况,系统分析了合成孔径雷达的成像特点:图像接近光学水平,低频SAR具有穿透簇叶和识别伪装功能,可大范围战场实时监视及工程目标自动识别等。结合工程伪装材料、技术、实践及谋略,提出了研制仿地物工程伪装材料及防SAR伪装网(布),开发口部伪装技术及防复合SAR探测伪装技术,长远规划、系统实践工程伪装,建立大伪装理论框架,加强伪装谋略研究等途径与方法,指出了工程伪装的发展趋势。     

Theoretical study of an energetic material di-1H-1,3,4-triazole derivatives

Computations by density functional theory (DFT) method are performed on a series of di-1H-1,3,4-triazole derivatives with different substituents and linkages. The heat of formation (HOF) is predicted by the designed isodesmic reactions. The predicted results reveal that –N₃ and –NN– groups are effective structural units for increasing the HOF values of the di-1H-1,3,4-triazole derivatives. The HOMO–LUMO gap is affected by the substituents and linkage groups. Detonation performance is evaluated using the Kamlet–Jacobs approach based on the calculated density and HOF. The results indicate that –NO₂, –NF₂, –NH–, –NH–NH– and –NN– groups are helpful for enhancing the detonation properties of di-1H-1,3,4-triazole derivatives. The bond dissociation energy and bond order of the weakest bonds are analyzed to investigate their stability. It is observed that the –CH₂–, –CH₂–CH₂– and –CHCH– groups are effective structural units for improving the stabilities of these derivatives. Considering the detonation performance and the stability, five compounds are screened as the potential candidates for high energy density materials.     

Special materials in pyrotechnics VII: Pyrotechnics used in thermal batteries

Thermal batteries are unique direct current (DC) electrical power sources with long shelf live, high reliability and higher power density than classical alkaline batteries. This paper gives a brief overview into the working principle of thermal batteries and reviews the properties of zirconium/barium chromate (Zr/BaCrO₄) pyrolant previously used as first fire and iron/potassium perchlorate (Fe/KClO₄) pyrolant (Heat), commonly applied as heating pellet in thermal batteries and its hazard properties. The review gives 64 references to the public domain. CAS-Nos. Zr: [7440-67-7], BaCrO₄: [10294-40-3], Fe: [7439-89-6], KClO₄: [7778-74-7], Viton: [9011-17-0].CAS-Nos. Zr: [7440-67-7], BaCrO₄: [10294-40-3], Fe: [7439-89-6], KClO₄: [7778-74-7], Viton: [9011-17-0].