碳纳米管对MWCNTs/EP复合材料力学性能的影响

采用超声波分散法制备多壁碳纳米管增强树脂基复合材料,研究了多壁碳纳米管质量分数对树脂基复合材料力学性能的影响规律.结果表明:多壁碳纳米管的加入可有效地改善树脂基复合材料的韧性和强度,当多壁碳纳米管质量分数为0.7％时,树脂基复合材料的力学性能最佳.加人多壁碳纳米管后,树脂基复合材料的玻璃化转变温度降低,且相容性良好.     

侧面封边对玻璃纤维增强环氧树脂基复合材料吸湿规律的影响

采用称量法和排水法联合,研究了侧面封边和未封边单向玻璃纤维增强环氧树脂基复合材料层合板试件的吸湿量和体积变化率与浸泡时间的关系,结果显示,复合材料侧面吸湿的速度远大于表面吸湿速度;侧面封边复合材料试件的饱和吸湿量为1.30％,而未封边试件的为2.26％,即与侧面封边试件相比,未封边试件的饱和吸湿量(质量比)增加了73....     

双酚A环氧树脂改性二氧化双环戊二烯体系固化动力学分析及其性能研究

二氧化双环戊二烯(CDR -0122)环氧树脂固化物的耐热性较好,但脆性大.采用不同质量分数的环氧(E -51)改性CDR -0122.对不同的改性体系进行DSC分析,确定其活化能、反应级数和最佳固化工艺.对改性的CDR - 0122环氧树脂固化物进行力学性能和耐温性能测试.结果表明:当加入E-51的质量分数为30％时,CDR -0122的树脂体系的综合性能最优.相比改性前,改性后的树脂体系活化能略有下降,并且其拉伸强度和弯曲强度分别提高了52.38％和54.77％,但玻璃化转变温度略有下降.     

聚氨酯/环氧树脂SIN中的增塑作用初探

本文通过测量聚醚氨酯(PU)/环氧树脂(EP)SIN系列的玻璃化转变温度(Tg);并对该数据进行分析及用DiBenedetto理论式对该Tg数据进行了处理,发现PU/EP SIN中,EP对PU链段存在着较强的增塑作用,这个增塑作用与PU与EP网间的互穿作用并存,它主要受PU/EP组成配比等因素的影响。     

纳米SiO_2增韧改性环氧乙烯基酯树脂的性能研究

为了对环氧乙烯基酯树脂(EVER)进行增韧改性,采用KH570硅烷偶联剂对纳米SiO2进行表面处理,考察了纳米SiO2表面改性及其质量分数对EVER力学性能的影响。经过偶联剂处理的纳米SiO2复合材料在树脂基体中具备更好的分散性和相容性,力学性能明显优于纯EVER材料和未经偶联剂处理的复合材料。纳米SiO2质量分数为3%时,纳米SiO2复合材料的拉伸强度、断裂伸长率、冲击强度分别比纯EVER材料提高了42.10%,43.38%和91.91%;纳米SiO2质量分数为4%时,纳米SiO2复合材料的拉伸模量比纯EVER材料提高了34.57%。通过观察冲击断面的SEM照片,分析了纳米SiO2增韧改性的作用机理。结果表明:纳米SiO2增韧改性的关键在于诱发基体产生银纹,使其对裂纹扩展起到钝化、阻碍的作用。     

基于纤维方向的C/SiC复合材料端面磨削实验研究

采用小直径金刚石砂轮对气相渗硅反应烧结工艺(Gaseous Si Infiltration,GSI)方法制备的C/Si C复合材料进行了端面磨削实验研究,探究了不同纤维方向的磨削性能,讨论了磨削用量对磨削力和磨削表面粗糙度的影响规律,采用扫描电子显微镜(Scanning Electron Microscope,SEM)对磨削表面形貌进行观测,分析了磨削损伤和磨削加工机理。结果表明:C/Si C复合材料不同纤维方向磨削性能不同,正常纤维方向磨削力最大,粗糙度最小;纵向纤维方向磨削力最小,粗糙度最大。材料以脆性断裂形式去除,磨削面损伤主要为纤维断裂、分层,Si C基体微裂纹,界面层失粘。通过理论分析推测碳纤维层主要作用是减弱微裂纹扩展程度和改变微裂纹扩展方向。     

吸湿环境对石英纤维增强环氧树脂面板/PMI泡沫夹层结构复合材料吸湿行为的影响

研究了不同温度、湿度环境下,夹层结构石英纤维增强环氧树脂面板/PMI泡沫夹层结构复合材料及其芯材和面板的吸湿规律。将石英纤维增强环氧树脂面板、PMI泡沫、复合材料面板/PMI泡沫夹层结构试样在不同吸湿环境中进行吸湿处理后,对其吸湿行为进行分析。结果表明:浸水环境下面板、PMI泡沫、PMI泡沫夹层结构复合材料都表现出更为严重的吸湿行为;在潮湿环境中,50℃至70℃范围内,温度越高,试样在吸湿过程中的质量损失越多,最终的饱和吸湿率越小;在60℃以内的潮湿环境中,PMI泡沫夹层结构复合材料的饱和吸湿率可以通过相同环境下面板复合材料和PMI泡沫的吸湿率进行预测。     

界面热阻对金刚石/银复合材料导热率的影响

研究了金刚石／银复合材料的导热率与金刚石的含量、粒度等之间的关系,着重讨论了界面热阻对复合材料导热率的影响。并阐述了金刚石表面镀钛,能有效改善金刚石对银的润湿性,降低界面热阻,从而提高金刚石／银复合材料的导热率。     

碳纤维增强聚合物基复合材料频率选择表面的电磁传输特性

为了避免采用金属频率选择表面制备的天线罩中存在的热残余应力和弱黏接界面等问题,采用与聚合物基复合材料罩壁结构相容性好的碳纤维增强聚合物基复合材料制备频率选择表面,利用自由空间法对试样的电磁传输性能进行测试,并采用数值分析模型对碳纤维复合材料频率选择表面的电磁传输机制和电磁传输影响因子进行分析。结果表明:碳纤维复合材料频率选择表面具有频率选择功能,但谐振频率处的电磁传输损耗较大;通过改变复合材料频率选择表面的单元缝隙率、厚度、电导率以及介电常数可以实现对其电磁传输性能的调节。     

低速冲击下玻璃钢/钢复合结构损伤特性实验研究

考虑基体材料的不同增韧特性,针对两种不同的玻纤织物增强复合材料/钢复合结构进行低速冲击实验,采用超声波探伤仪对玻璃钢损伤区域进行了探测.结果表明,采用增韧基体的玻璃钢/钢复合结构在低速冲击下玻璃钢层的抗冲击能力更强,相同能量冲击下的损伤面积更小;损伤面积近似呈正方形分布,正方形对角线与纤维方向一致.     

添加SiC微粉对硅树脂先驱体转化3D Cf/Si-O-C材料性能的影响

以三维碳纤维织物和廉价的硅树脂为原料,采用先驱体转化工艺制备3D G/Si-O-C材料,考察了浸渍液中添加SiC填料对材料微观结构、力学性能和抗氧化性能影响.结果表明:添加适量的SiC填料有助于减少基体孔隙,改善界面结合,从而提高材料的力学性能;而SiC含量过高时,容易在材料内部形成闭孔,从而导致材料力学性能下降.当SiC微粉含量为18.2%时,材料具有最好的力学性能,弯曲强度和断裂韧度分别为421.3MPa和13.0 MPa·m1/2;而材料的抗氧化性能随着SiC微粉含量的增加而增加,当SiC微粉含量为25.0%时,材料的弯曲强度保留率最高,达到了89.5%.     

Mechanical properties and thermal conductivity of pristine andfunctionalized carbon nanotube reinforced metallic glass composites:A molecular dynamics approach

This work uses the molecular dynamics approach to study the effects of functionalization of carbon nanotubes (CNTs) on the mechanical properties of Cu64Zr36 metallic glass (MG). Three types of functional groups, carboxylic, vinyl and ester were used. The effect of CNT volume fraction (Vf) and the number of functional groups attached to CNT, on the mechanical properties and thermal conductivity of CNT-MG composites was analysed using Biovia Materials Studio. At lower values of Vf (from 0 to 5％), the per-centage increase in Young's modulus was approximately 66％. As the value of Vf was increased further (from 5 to 12％), the rate of increase in Young's modulus was reduced to 16％. The thermal conductivity was found to increase from 1.52 W/mK at Vf=0％to 5.88 W/mK at Vf=12％, thus giving an increase of approximately 286％. Functionalization of SWCNT reduced the thermal conductivity of the SWCNT-MG composites.     

烧结助剂对碳纳米管增强氮化铝陶瓷结构与性能的影响

采用热压烧结工艺制备了碳纳米管增强氮化铝陶瓷,研究了烧结助剂种类、含量对碳纳米管增强氮化铝陶瓷性能及结构的影响.利用XRD、SEM和TEM等分析测试手段对其相组成,断口形貌和微观结构进行了分析.结果表明,烧结助剂Y2O3+CaF2较YE3+CaF2更能促进碳纳米管增强氮化铝陶瓷致密化,但随烧结助剂Y2O3+CaF2含量的增加,碳纳米管增强氮化铝陶瓷致密度提高,而力学、导热性能下降.     

Synergistic effect of hybrid Himalayan Nettle/Bauhinia-vahlii fibers on physico-mechanical and sliding wear properties of epoxy composites

The cellulosic bast fibers are recognized as a justifiable and biodegradable substitute for producing moderate strength polymer composite materials because of their characteristics of renewability, eco-friendliness, and higher specific strength. Hence the aim of this research work is to fabricate Himalayan bast fibers (Nettle fiber (NF)/bauhinia vahlii fiber (BF)) based mono/hybrid epoxy composites at varying weight percentage of 2–6 wt% and evaluate the physical (void fraction and water absorption), mechanical (tensile strength, flexural strength, hardness) and sliding wear properties of as-fabricated composites. The 6 wt% NBF reinforced composites exhibited higher mechanical properties as compared to NF and BF composites with tensile strength of 34.04 MPa, flexural strength of 42.45 MPa, and hardness of 37.01 H_v respectively. The influence of various control factors (sliding velocity, NF/BF/NBF contents, normal load and sliding distance) on specific sliding wear rate of composites was evaluated by Taguchi (three factors at three levels) experimental design and the percentage contribution of these selected parameters on sliding wear performance was examined by Analysis of variance (ANOVA). The sliding wear property of as-developed composites was found to be greatly influenced by sliding velocity and the wear resistance was observed to be improved with the NF/BF/NBF contents. The wear mechanism of the as-fabricated composites has been elucidated by scanning electron microscopy analysis. The research outcomes demonstrated that the hybridization of Bauhinia vahlii fiber with Nettle fiber led to improve the mechanical and wear properties of epoxy composites.     

列车用复合材料阻燃性能研究

不同类别的阻燃剂配合使用能产生协效作用,大大提高阻燃效果。在甲基丙烯酸类不饱和聚酯树脂9001基体中,添加微囊化红磷/氢氧化铝/三氧化二锑/甲基膦酸二甲酯(MRP/Al(OH)3/Sb2O3/DMMP)阻燃剂体系,对其树脂体系固化物及玻璃纤维织物复合材料的力学性能和阻燃性能进行了实验研究,提出了一种有望用于列车复合材料大尺寸构件制造的性能优异、价格低廉的新体系。结果表明,当质量添加比例分别为12%MRP、50%Al(OH)3、2%Sb2O3时,树脂体系室温粘度100mPa.s左右,凝胶时间超过80min,适用于RTM和VIMP等大尺寸构件成型工艺;复合材料拉伸强度215.4MPa,弯曲强度177.15MPa,拉伸模量13.85GPa,弯曲模量13.36GPa,氧指数39.7。     

极性基团对环氧树脂基体力学性能及吸水特性的影响

研究了CYD- 128/THPA/DMP- 30 (CTD)、TDE- 85/THPA/DMP- 30(TTD)、CYD- 128/IPDA(CI)与TDE- 85/IPDA (TI)4种环氧树脂基体浇铸体的拉伸、弯曲和耐海水性能,分析了树脂、固化剂类型和分子结构对树脂基体性能的影响.结果表明,使用相同固化剂时,TDE...     

聚氨酯/环氧树脂(PU/EP)AB-交联聚合物的研究

用二胺同时固化聚醚氨酯预聚物及环氧树脂,制得了PU/EP AB-交联聚合物(AB-CP)。以动态粘弹仪对其进行了表征,结果表明:形成AB-CP后,PU与EP相之间的相互作用大大加强(强于PU/EF IPN中PU与EP之间的作用),使PU链运动受到限制,其Tg移向高温区并形成了一个单一的Tg峰;研究了物料比、环氧值等对其动态力学谱(DMS)的影响。预期该化合物是一类有前途的增韧环氧树脂材料。     

Influence of Al2O3 particles on the microstructure and mechanical properties of copper surface composites fabricated by friction stir processing

The influence of three factors, such as volume percentage of reinforcement particles (i.e. Al₂O₃), tool tilt angle and concave angle of shoulder, on the mechanical properties of Cu–Al₂O₃ surface composites fabricated via friction stir processing was studied. Taguchi method was used to optimize these factors for maximizing the mechanical properties of surface composites. The fabricated surface composites were examined by optical microscope for dispersion of reinforcement particles. It was found that Al₂O₃ particles are uniformly dispersed in the stir zone. The tensile properties of the surface composites increased with the increase in the volume percentage of the Al₂O₃ reinforcement particles. This is due to the addition of the reinforcement particles which increases the temperature of recrystallization by pinning the grain boundaries of the copper matrix and blocking the movement of the dislocations. The observed mechanical properties are correlated with microstructure and fracture features.     

Investigation of the mechanical and ballistic properties of hybrid carbon/ aramid woven laminates

High-performance ballistic fibers, such as aramid fiber and ultra-high-molecular-weight polyethylene (UHMWPE), are commonly used in anti-ballistic structures due to their low density, high tensile strength and high specific modulus. However, their low modulus in the thickness direction and insufficient shear strength limits their application in certain ballistic structure. In contrast, carbon fiber reinforced epoxy resin matrix composites (CFRP) have the characteristics of high modulus in the thickness direction and high shear resistance. However, carbon fibers are rarely used and applied for protection purposes. A hybridization with aramid fiber reinforced epoxy resin matrix composites (AFRP) and CFRP has the potential to improve the stiffness and the ballistic property of the typical ballistic fiber composites. The hybrid effects on the flexural property and ballistic performance of the hybrid CFRP/AFRP laminates were investigated. Through conducting mechanical property tests and ballistic tests, two sets of reliable simulation parameters for AFRP and CFRP were established using LS-DYNA software, respectively. The experimental results suggested that by increasing the content of CFRP that the flexural properties of hybrid CFRP/AFRP laminates were enhanced. The ballistic tests’ results and the simulation illustrated that the specific energy absorption by the perforation method of CFRP achieved 77.7% of AFRP. When CFRP was on the striking face, the shear resistance of the laminates and the resistance force to the projectiles was promoted at the initial penetration stage. The proportion of fiber tensile failures in the AFRP layers was also enhanced with the addition of CFRP during the penetration process. These improvements resulted in the ballistic performance of hybrid CFRP/AFRP laminates was better than AFRP when the CFRP content was 20 wt% and 30 wt%.     

Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.